Based on the molecular interaction volume model （MIVM）, the activities of components of Pb Sn Sb ternary alloy were predicted. The vapo^liquid phase equilibrium of Pb-Sn-Sb alloy system was calculated using the acti...Based on the molecular interaction volume model （MIVM）, the activities of components of Pb Sn Sb ternary alloy were predicted. The vapo^liquid phase equilibrium of Pb-Sn-Sb alloy system was calculated using the activity coefficients of Pb Sn-Sb alloy system in the process of vacuum distillation. The calculated results show that the content of Sn in vapor phase increases with the increasing distillation temperature and content of Sn in liquid phase. However, the content of Sn in vapor phase is only 0.45% （mass fraction） while 97% in liquid phase at 1100 ℃, which shows that the separating effect is very well. Experimental investigations on the separation of Pb-Sn-Sb ternary alloy were carried out in the distillation temperature range of 1100-1300 ℃ under vacuum condition. It is found that the Sn content in vapor phase is 0.54% while 97% in liquid phase at 1100 ℃. Finally, the predicted data were compared with the experimental results showing good agreement with each other.展开更多
Batch extractive distillation(BED)is a special method used in the distillation process by adding a solvent into the batch distillation column to alter the relative volatility of the components and improve the separati...Batch extractive distillation(BED)is a special method used in the distillation process by adding a solvent into the batch distillation column to alter the relative volatility of the components and improve the separation. A comprehensive design and simulation method is required due to the complexity of BED.In this study,a quasi-steady-state model for BED is proposed,the derivation and solution of the model are presented.This shortcut model can be used to simulate the composition and temperature of the reboiler,the top and other plates of the column in a batch extractive distillation operation.The calculated values are in good agreement with the experimental data.The results show that the quasi-steady-state model is a practical method because of some advantages such as high precision and fast calculation.展开更多
The modeling and optimization of an industrial-scale crude distillation unit （CDU） are addressed. The main spec- ifications and base conditions of CDU are taken from a crude oil refinery in Wuhan, China. For modelin...The modeling and optimization of an industrial-scale crude distillation unit （CDU） are addressed. The main spec- ifications and base conditions of CDU are taken from a crude oil refinery in Wuhan, China. For modeling of a com- plicated CDU, an improved wavelet neural network （WNN） is presented to model the complicated CDU, in which novel parametric updating laws are developed to precisely capture the characteristics of CDU. To address CDU in an economically optimal manner, an economic optimization algorithm under prescribed constraints is presented. By using a combination of WNN-based optimization model and line-up competition algorithm （LCA）, the supe- rior performance of the proposed approach is verified. Compared with the base operating condition, it is validat- ed that the increments of products including kerosene and diesel are up to 20% at least by increasing less than 5% duties of intermediate coolers such as second pump-around （PA2） and third Dump-around （PA3）.展开更多
Two types of equilibrium and non-equilibrium stage models are generally used to simulate the mass transfer of packed distillation column. Using non-equilibrium model requires the calculation of mass transfer coefficie...Two types of equilibrium and non-equilibrium stage models are generally used to simulate the mass transfer of packed distillation column. Using non-equilibrium model requires the calculation of mass transfer coefficients, thus, usually equilibrium-based methods are preferred to be used for simulations of distillation columns. In this paper, packed column distillation of production of Mono Ethylene Glycol in FARSA SHIMI Company （Assaluyeh-Iran）＇s Ethylene Glycol portion has been simulated through using the equilibrium model and solving the related equations. The simulation has been carried out in the MATLAB environment. The column also has been simulated in the Aspen Hysys and Aspen Plus ver. 2006.5 environments. Then, the output has been compared with software results, designing and operating data of the underlying columns which demonstrate good consistency with the model. Having the model validated, the effect of some operating parameters has been analyzed through the model.展开更多
This study aimed to model the kinetic of hydro-distillation of Aquilaria malaccensis leaves oil in order to understand and optimize the extraction process. In addition, this study, for the first time, aimed to identif...This study aimed to model the kinetic of hydro-distillation of Aquilaria malaccensis leaves oil in order to understand and optimize the extraction process. In addition, this study, for the first time, aimed to identify the chemical compositions of the A. rnalaccensis leave-oil. By assessing both first-order kinetic model and the model of simultaneous washing and diffusion, the result indicated that the model of simultaneous washing and diffusion better describes the hydro-distillation mechanism of the essential oil from A. rnalaccensis leaves. The optimum time, solid to liquid ratio, and the heating power for extracting the highest amount of essential oil were found to be around 3 h, 1：10 （g. ml-1）, and 300 W respectively. Yellow essential oil with a strong smell and a yield of 0.05 v/w was extracted by hydro-distillation Clevenger apparatus. Chemical compounds of the essential oil were analyzed using gas chromatography-mass spectroscopy （GC/MS）, which resulted in identification of 42 compounds that constitute 93% of essential oil. Among the identified components, Pentadecanal （32.082%）, 9-Octadecenal, （Z） （15.894%）, and Tetradecanal （6.927%） were the major compounds. Considering the fact that all the identified major components possess pesticidal properties, A. malaccensis leaves can be regarded as a promising natural source for producing pesticides.展开更多
基金Project(2012CB722803) supported by the National Basic Research Program of ChinaProject(2011FA008) supported by the Key Projectof Science and Technology Program of Yunnan Province,China
文摘Based on the molecular interaction volume model （MIVM）, the activities of components of Pb Sn Sb ternary alloy were predicted. The vapo^liquid phase equilibrium of Pb-Sn-Sb alloy system was calculated using the activity coefficients of Pb Sn-Sb alloy system in the process of vacuum distillation. The calculated results show that the content of Sn in vapor phase increases with the increasing distillation temperature and content of Sn in liquid phase. However, the content of Sn in vapor phase is only 0.45% （mass fraction） while 97% in liquid phase at 1100 ℃, which shows that the separating effect is very well. Experimental investigations on the separation of Pb-Sn-Sb ternary alloy were carried out in the distillation temperature range of 1100-1300 ℃ under vacuum condition. It is found that the Sn content in vapor phase is 0.54% while 97% in liquid phase at 1100 ℃. Finally, the predicted data were compared with the experimental results showing good agreement with each other.
基金Supported by the Natural Science Foundation of Hebei Province（B2006000018）
文摘Batch extractive distillation(BED)is a special method used in the distillation process by adding a solvent into the batch distillation column to alter the relative volatility of the components and improve the separation. A comprehensive design and simulation method is required due to the complexity of BED.In this study,a quasi-steady-state model for BED is proposed,the derivation and solution of the model are presented.This shortcut model can be used to simulate the composition and temperature of the reboiler,the top and other plates of the column in a batch extractive distillation operation.The calculated values are in good agreement with the experimental data.The results show that the quasi-steady-state model is a practical method because of some advantages such as high precision and fast calculation.
基金Supported by the National Natural Science Foundation of China(No.21376185)
文摘The modeling and optimization of an industrial-scale crude distillation unit （CDU） are addressed. The main spec- ifications and base conditions of CDU are taken from a crude oil refinery in Wuhan, China. For modeling of a com- plicated CDU, an improved wavelet neural network （WNN） is presented to model the complicated CDU, in which novel parametric updating laws are developed to precisely capture the characteristics of CDU. To address CDU in an economically optimal manner, an economic optimization algorithm under prescribed constraints is presented. By using a combination of WNN-based optimization model and line-up competition algorithm （LCA）, the supe- rior performance of the proposed approach is verified. Compared with the base operating condition, it is validat- ed that the increments of products including kerosene and diesel are up to 20% at least by increasing less than 5% duties of intermediate coolers such as second pump-around （PA2） and third Dump-around （PA3）.
文摘Two types of equilibrium and non-equilibrium stage models are generally used to simulate the mass transfer of packed distillation column. Using non-equilibrium model requires the calculation of mass transfer coefficients, thus, usually equilibrium-based methods are preferred to be used for simulations of distillation columns. In this paper, packed column distillation of production of Mono Ethylene Glycol in FARSA SHIMI Company （Assaluyeh-Iran）＇s Ethylene Glycol portion has been simulated through using the equilibrium model and solving the related equations. The simulation has been carried out in the MATLAB environment. The column also has been simulated in the Aspen Hysys and Aspen Plus ver. 2006.5 environments. Then, the output has been compared with software results, designing and operating data of the underlying columns which demonstrate good consistency with the model. Having the model validated, the effect of some operating parameters has been analyzed through the model.
文摘This study aimed to model the kinetic of hydro-distillation of Aquilaria malaccensis leaves oil in order to understand and optimize the extraction process. In addition, this study, for the first time, aimed to identify the chemical compositions of the A. rnalaccensis leave-oil. By assessing both first-order kinetic model and the model of simultaneous washing and diffusion, the result indicated that the model of simultaneous washing and diffusion better describes the hydro-distillation mechanism of the essential oil from A. rnalaccensis leaves. The optimum time, solid to liquid ratio, and the heating power for extracting the highest amount of essential oil were found to be around 3 h, 1：10 （g. ml-1）, and 300 W respectively. Yellow essential oil with a strong smell and a yield of 0.05 v/w was extracted by hydro-distillation Clevenger apparatus. Chemical compounds of the essential oil were analyzed using gas chromatography-mass spectroscopy （GC/MS）, which resulted in identification of 42 compounds that constitute 93% of essential oil. Among the identified components, Pentadecanal （32.082%）, 9-Octadecenal, （Z） （15.894%）, and Tetradecanal （6.927%） were the major compounds. Considering the fact that all the identified major components possess pesticidal properties, A. malaccensis leaves can be regarded as a promising natural source for producing pesticides.
