The new vanadyl complex [VO（o-van）2（H2O）]（o-van=o-vanillin）was synthesized and characterized by IR,elemental analysis,and X-ray diffraction analysis.In the complex,the vanadium atom was coordinated to six oxygen...The new vanadyl complex [VO（o-van）2（H2O）]（o-van=o-vanillin）was synthesized and characterized by IR,elemental analysis,and X-ray diffraction analysis.In the complex,the vanadium atom was coordinated to six oxygen atoms and formed a distorted octahedral structure.The crystal belongs to monoclinic system with space group P21/n,a=0.9414（4）nm,b=1.6103（6） nm,c=1.1710（4）nm,β=111.493（6）°,V=1.6518（10）nm3,Z=4,DC=1.557 g·cm-3,F（000）=796,R1=0.0424,wR2=0.0842.展开更多
文摘The new vanadyl complex [VO（o-van）2（H2O）]（o-van=o-vanillin）was synthesized and characterized by IR,elemental analysis,and X-ray diffraction analysis.In the complex,the vanadium atom was coordinated to six oxygen atoms and formed a distorted octahedral structure.The crystal belongs to monoclinic system with space group P21/n,a=0.9414（4）nm,b=1.6103（6） nm,c=1.1710（4）nm,β=111.493（6）°,V=1.6518（10）nm3,Z=4,DC=1.557 g·cm-3,F（000）=796,R1=0.0424,wR2=0.0842.
