The iron-loaded organic phase of naphthenic acid-isooctyl alcohol-kerosene was prepared, and the process kinetics of hydrothermal stripping of iron from the phase was studied. Several factors affecting hydrothermal st...The iron-loaded organic phase of naphthenic acid-isooctyl alcohol-kerosene was prepared, and the process kinetics of hydrothermal stripping of iron from the phase was studied. Several factors affecting hydrothermal stripping, such as the polymer of naphthenic acid, initial concentrations of iron and naphthenic acid, temperature and agitation time, were investigated, and based on experimental results and theoretical analysis, two kinetic models were established.The stripping rate equation suggests that the hydrothermal stripping process activation energy is 96.4 kJ·mol-1 and the stripping is controlled by hydrolysis of naphthenic complex of iron. The values calculated by the stripping fraction equation comparatively accord with the experimental data.展开更多
Elovicb, two-constant, parabolic diffusion, exponential, second-order, first-order and zero-order equations were used to describe the kinetic characteristics of potassium desorption from six paddy soils df Zhejiang Pr...Elovicb, two-constant, parabolic diffusion, exponential, second-order, first-order and zero-order equations were used to describe the kinetic characteristics of potassium desorption from six paddy soils df Zhejiang Province in a constant electric field (44.4 V/ cm) of EUF. Results showed that the second-order and Elovich equations could describe the potassium desorption kinetics best, as evidenced by the highest correlation coefficients (r) and the lowest standard errors (SE). The first-order, two-constant and parabolic diffusion equations also described the K desorption kinetics well, as showed by the relatively high correlation coefficients and relatively low standard errors. The zero-order equation did not describe the K desorption satisfactorily with a relatively low correlation coefficient and relatively high standard error. However, the exponential equation could not be used to describe the K desorption kinetics, due to the lowest correlation coefficient and the highest standard error.展开更多
Non-consistency of stress results is of ten observed during field measurements. In some cases, even the rneasurernents are made at the same location in a massive rockrnass, the results can vary widely. In order to sol...Non-consistency of stress results is of ten observed during field measurements. In some cases, even the rneasurernents are made at the same location in a massive rockrnass, the results can vary widely. In order to solve the problem, extensive research has been carried out to study the major factors wh1ch rnay affect stress deterrnlnation. They include the rock behaviour and the stress state. For rocks showing non-isotropic behaviour, the values of Young’s modulus and Poisson ratio vary with the orientation of loading and measurement. Stress condition in the rock affects the rock behaviour. Furtherrnore, the loading condition on rock samples durlng laboratory tests is different from in the field and therefore the determined e1astic constants may not represent the field condi tion. In general , the Young’s modulus may depend on the orientation, the loading path, the stress magnitude and the stress ratio. This paper examines in detail the effects of those factors, especially for rocks showing transversely isotropic behaviour. It is found that the discrepancy of stress results from field measurernents in this type of rock is mainly due to over simplification of the rock behavior and inadequate use of elastic constants of the rock during stress calculation. A case study is given,which indicates the significance of these factors and demonstrates the proper procedure for stress calculation from measurements.展开更多
In this note, we provide a consistant thin layer theory for power law and Bingham incompressible fluids flowing down an inclined plane under the effect of gravity. The derivation of such equations is based on formal a...In this note, we provide a consistant thin layer theory for power law and Bingham incompressible fluids flowing down an inclined plane under the effect of gravity. The derivation of such equations is based on formal asymptotic expansions of solutions of Cauchy momentum equations in the shallow water scaling and in the neighbourhood of steady solutions so that we can close the average equations on the fluid height h and the total discharge rate q.展开更多
基金Supported by National Natural Science Foundation of China (No.20276074)
文摘The iron-loaded organic phase of naphthenic acid-isooctyl alcohol-kerosene was prepared, and the process kinetics of hydrothermal stripping of iron from the phase was studied. Several factors affecting hydrothermal stripping, such as the polymer of naphthenic acid, initial concentrations of iron and naphthenic acid, temperature and agitation time, were investigated, and based on experimental results and theoretical analysis, two kinetic models were established.The stripping rate equation suggests that the hydrothermal stripping process activation energy is 96.4 kJ·mol-1 and the stripping is controlled by hydrolysis of naphthenic complex of iron. The values calculated by the stripping fraction equation comparatively accord with the experimental data.
文摘Elovicb, two-constant, parabolic diffusion, exponential, second-order, first-order and zero-order equations were used to describe the kinetic characteristics of potassium desorption from six paddy soils df Zhejiang Province in a constant electric field (44.4 V/ cm) of EUF. Results showed that the second-order and Elovich equations could describe the potassium desorption kinetics best, as evidenced by the highest correlation coefficients (r) and the lowest standard errors (SE). The first-order, two-constant and parabolic diffusion equations also described the K desorption kinetics well, as showed by the relatively high correlation coefficients and relatively low standard errors. The zero-order equation did not describe the K desorption satisfactorily with a relatively low correlation coefficient and relatively high standard error. However, the exponential equation could not be used to describe the K desorption kinetics, due to the lowest correlation coefficient and the highest standard error.
文摘Non-consistency of stress results is of ten observed during field measurements. In some cases, even the rneasurernents are made at the same location in a massive rockrnass, the results can vary widely. In order to solve the problem, extensive research has been carried out to study the major factors wh1ch rnay affect stress deterrnlnation. They include the rock behaviour and the stress state. For rocks showing non-isotropic behaviour, the values of Young’s modulus and Poisson ratio vary with the orientation of loading and measurement. Stress condition in the rock affects the rock behaviour. Furtherrnore, the loading condition on rock samples durlng laboratory tests is different from in the field and therefore the determined e1astic constants may not represent the field condi tion. In general , the Young’s modulus may depend on the orientation, the loading path, the stress magnitude and the stress ratio. This paper examines in detail the effects of those factors, especially for rocks showing transversely isotropic behaviour. It is found that the discrepancy of stress results from field measurernents in this type of rock is mainly due to over simplification of the rock behavior and inadequate use of elastic constants of the rock during stress calculation. A case study is given,which indicates the significance of these factors and demonstrates the proper procedure for stress calculation from measurements.
文摘In this note, we provide a consistant thin layer theory for power law and Bingham incompressible fluids flowing down an inclined plane under the effect of gravity. The derivation of such equations is based on formal asymptotic expansions of solutions of Cauchy momentum equations in the shallow water scaling and in the neighbourhood of steady solutions so that we can close the average equations on the fluid height h and the total discharge rate q.
