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环氧树脂-水性聚酰胺改性豆粕胶黏剂压制胶合板的研究 被引量:2
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作者 赵艳 张泽宇 +2 位作者 徐宁 谭博文 庞久寅 《吉林林业科技》 2021年第3期31-36,共6页
本文采用环氧树脂和水性聚酰胺对豆粕进行复合改性制备无醛胶黏剂,对豆粕胶黏剂的性能指标和胶合板的胶合强度进行了研究。通过正交试验得出以下最佳工艺参数:当热压温度为120℃、环氧树脂与水性聚酰胺改性豆粕溶液的质量比为20∶80、... 本文采用环氧树脂和水性聚酰胺对豆粕进行复合改性制备无醛胶黏剂,对豆粕胶黏剂的性能指标和胶合板的胶合强度进行了研究。通过正交试验得出以下最佳工艺参数:当热压温度为120℃、环氧树脂与水性聚酰胺改性豆粕溶液的质量比为20∶80、热压时间600 s时胶合板的胶合强度最高,为0.7628 MPa,达到国家标准GB/T 9846-2015中Ⅱ类胶合板使用要求。 展开更多
关键词 水性聚酰胺 环氧树脂 豆粕基胶黏剂 胶合板 胶合强度
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碳纤维增强水性聚酰胺酰亚胺涂层摩擦学性能 被引量:6
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作者 刘高尚 刘雅玄 +2 位作者 黄国栋 卞达 赵永武 《塑料》 CAS CSCD 北大核心 2021年第3期28-32,共5页
将水性聚酰胺酰亚胺(PAI)作为基体,碳纤维(CF)和二硫化钼(MoS_(2))作为固体填料,采用刮涂的方法制备了环保型自润滑复合涂层,研究了固体填料中CF和MoS_(2)的比例对复合涂层硬度、摩擦学性能和热稳定性的影响。结果表明,复合涂层的硬度随... 将水性聚酰胺酰亚胺(PAI)作为基体,碳纤维(CF)和二硫化钼(MoS_(2))作为固体填料,采用刮涂的方法制备了环保型自润滑复合涂层,研究了固体填料中CF和MoS_(2)的比例对复合涂层硬度、摩擦学性能和热稳定性的影响。结果表明,复合涂层的硬度随着CF比例的增加呈明显上升趋势。复合涂层的摩擦因数和磨损量均随CF比例的增加,呈先下降后上升的趋势,当CF比例为20%时,二者均达到最低值,分别为0.211和0.64×10^(-4)mm^(3)Nm,与单纯MoS_(2)固体填料相比,分别降低了22.4%和73%。复合涂层的热稳定性随CF比例的增加呈先上升后下降的趋势,当CF比例为15%时,质量损失率为10%,温度(T10)最高为454℃,与纯MoS_(2)固体填料相比,提升30%。 展开更多
关键词 水性聚酰胺酰亚胺 硬度 摩擦因数 磨损量 热稳定性
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水性聚酰胺固化剂的研究进展 被引量:4
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作者 陈力 祝宝英 +2 位作者 张汉青 刘汉功 狄志刚 《上海涂料》 CAS 2021年第1期34-39,共6页
概述了水性聚酰胺固化剂的研发简史,总结了离子型和非离子型水性聚酰胺固化剂的制备方法和应用现状,探讨了新型水性聚酰胺加成物固化剂的研究现状,最后展望了水性聚酰胺固化剂的发展趋势。
关键词 水性聚酰胺固化剂 离子型 非离子型 酰胺加成物 研究进展
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聚酰胺基质亲水性亲和膜上染料配基辛巴蓝含量的测定 被引量:2
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作者 夏宝林 古凤才 +1 位作者 张国亮 张凤宝 《分析化学》 SCIE EI CAS CSCD 北大核心 2004年第3期348-351,共4页
发展了以聚酰胺为基质的亲水性亲和膜上活性染料配基辛巴蓝含量的测定方法。将实验室制备的聚酰胺基质亲和膜在 12 .0mol/L盐酸中水解后 ,采用分光光度法对水解液直接进行检测 ,即可得到膜上染料配基含量。实验确定了适宜的分析条件 ,... 发展了以聚酰胺为基质的亲水性亲和膜上活性染料配基辛巴蓝含量的测定方法。将实验室制备的聚酰胺基质亲和膜在 12 .0mol/L盐酸中水解后 ,采用分光光度法对水解液直接进行检测 ,即可得到膜上染料配基含量。实验确定了适宜的分析条件 ,探讨了体系的吸收光谱和影响因素。对亲和膜体系分析得到了体系中辛巴蓝浓度和吸光度之间的线性关系 ,相关系数均在 0 .999以上 ,检出限为 0 .31~ 0 .34mg/L ;相对标准偏差为 1.1%~ 3.4 %。实验体系中的共存物质对于检测结果影响较小。用本方法对样品进行分析 ,回收率在99.8%~ 10 4 .2 %之间 ;与元素分析法等进行比较 ,表明本法能较准确地确定聚酰胺基质亲和膜上配基含量 ,且具有简便、适用和快速的特点。 展开更多
关键词 酰胺基质亲水性亲和膜 染料配基 辛巴蓝 含量测定 生物大分子 亲和分离
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水性二硫化钼基粘结固体润滑涂层制备及其摩擦学性能 被引量:14
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作者 李斌 冶银平 +2 位作者 万宏启 陈磊 陈建敏 《中国表面工程》 EI CAS CSCD 北大核心 2017年第4期142-149,共8页
为研制兼具环保性和良好摩擦学性能的水性粘接固体润滑涂层,以去离子水作为分散介质,水性聚酰胺酰亚胺为粘结剂,二硫化钼为润滑剂,加以适量的润湿分散剂采用油漆喷涂工艺研制水性粘结固体润滑涂层,探究了粘结剂的固化温度以及润滑剂的... 为研制兼具环保性和良好摩擦学性能的水性粘接固体润滑涂层,以去离子水作为分散介质,水性聚酰胺酰亚胺为粘结剂,二硫化钼为润滑剂,加以适量的润湿分散剂采用油漆喷涂工艺研制水性粘结固体润滑涂层,探究了粘结剂的固化温度以及润滑剂的含量对涂层力学和摩擦学性能的影响。结果表明,当固化温度为270℃时粘结剂可以完全固化,且此时涂层具有较高的显微硬度。涂层的摩擦因数随着润滑剂与粘结剂质量比的增大逐渐降低,而显微硬度和耐磨寿命呈现出先增大后减小的趋势,当润滑剂和粘结剂的质量比为1.7时,涂层具有较高的硬度和良好的抗磨减摩性能,此时耐磨寿命达到187 m/μm,稳定阶段的摩擦因数为0.11。 展开更多
关键词 粘结固体润滑涂层 水性聚酰胺酰亚胺 固化温度 摩擦学性能
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水性超支化环氧树脂的合成及应用 被引量:3
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作者 李帅 张坤 +2 位作者 王义刚 陈洁 聂小安 《精细化工》 EI CAS CSCD 北大核心 2022年第3期611-617,共7页
以丙三醇三缩水甘油醚和二甘醇为原料,合成了水性超支化环氧树脂HE-32。以己二酸和二乙烯三胺为原料,合成了水性聚酰胺PA236,将其接枝到HE-32上得到了改性水性聚酰胺PA236G。向PA236G水溶液中加入其质量2%的水性固化剂906得到粘缸剂CA-2... 以丙三醇三缩水甘油醚和二甘醇为原料,合成了水性超支化环氧树脂HE-32。以己二酸和二乙烯三胺为原料,合成了水性聚酰胺PA236,将其接枝到HE-32上得到了改性水性聚酰胺PA236G。向PA236G水溶液中加入其质量2%的水性固化剂906得到粘缸剂CA-21。采用^(1)HNMR、^(13)CNMR、FTIR、GPC、TG对HE-32、PA236和PA236G进行了表征和性能测试,对CA-21进行了薄膜性能和力学性能的测试。结果表明,聚合物已成功合成,且PA236已成功接枝到HE-32上。PA236G的热稳定性大幅提高,CA-21的平均剪切强度可达0.17311 MPa,对基材的平均附着力可达171.2 N,分别约是市售产品1(主要成分为改性聚酰胺环氧氯丙烷树脂)的2.06倍和1.84倍,具有作为粘缸剂使用的潜力。 展开更多
关键词 水性聚酰胺 水性环氧树脂 起皱粘缸剂 造纸化学品
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水性粘缸剂的制备及表征
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作者 李帅 肖来辉 +3 位作者 王义刚 陈洁 李文斌 聂小安 《林产化学与工业》 CAS CSCD 北大核心 2022年第5期83-90,共8页
在己二酸与二乙烯三胺合成水性聚酰胺PA236的基础上,将水性环氧树脂接枝到PA236上,得到改性PA236(PA236G),然后向PA236G中加入一定量的羟乙基纤维素溶液和水性固化剂906,制得水性粘缸剂CA514。采用红外、核磁氢谱、碳谱和凝胶色谱分析对... 在己二酸与二乙烯三胺合成水性聚酰胺PA236的基础上,将水性环氧树脂接枝到PA236上,得到改性PA236(PA236G),然后向PA236G中加入一定量的羟乙基纤维素溶液和水性固化剂906,制得水性粘缸剂CA514。采用红外、核磁氢谱、碳谱和凝胶色谱分析对PA236和改性PA236的结构和相对分子质量进行了表征,证实了PA236的成功合成以及水性环氧树脂的成功接枝;用热重分析测定了二者的热性能,表明二者均可用作粘缸剂的原料使用。对CA514所形成的薄膜性能进行了测试,结果表明:CA514烘干后形成的薄膜与市售产品(改性PAE)具有相似的性质,且耐水性更好,平均溶胀度可达188.3%;CA514可提供的平均剪切强度可达122.4 kPa,为市售产品的2倍多,基材附着力为136.6 N,约为市售产品的1.4倍。薄膜良好的耐水性能和力学性能说明CA514具有作为粘缸剂使用的潜力。 展开更多
关键词 水性聚酰胺 水性环氧树脂 起皱粘缸剂
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Separation of diaspore from bauxite by selective flocculation using hydrolyzed polyacrylamide 被引量:6
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作者 刘文莉 胡岳华 孙伟 《Journal of Central South University》 SCIE EI CAS 2014年第4期1470-1476,共7页
Selective flocculation is a new method to solve the problem of China's bauxite de-silication besides flotation and reverse flotation. The method of selective flocculation of bauxite using hydrolyzed polyacrylamide... Selective flocculation is a new method to solve the problem of China's bauxite de-silication besides flotation and reverse flotation. The method of selective flocculation of bauxite using hydrolyzed polyacrylamide as flocculant was experimented and evaluated. The results of diaspore and kaolinite single mineral settling tests show that the difference between settlement yield of kaolinite(settling 15 min) and diaspore(settling 3 min) increases from 16% to 60% by adding flocculant at pH=7. Results of selective flocculation experiment of bauxite show that the higher concentrate grade(65.75) and Al-Si ratio(7.34) could be obtained with sodium carbonate as dispersant compared with sodium hexametaphosphate; under the action of flocculating agent, the concentrate grade and Al-Si ratio increase to 67.99 and 9.01. These results could meet the requirements of Bayer production, and the simpler process was expected to cost far less than traditional flotation method and a promising de-silication method of bauxite. 展开更多
关键词 hydrolyzed polyacrylamide selective flocculation diaspore anion maromolecular
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Effects of High Hydrostatic Pressure Treatment on Physicochemical Characteristics of Sea Cucumber 被引量:1
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作者 Yuanjing Xia Zhijun Liu Zhiyi Li 《Journal of Food Science and Engineering》 2012年第4期227-238,共12页
The effects of high hydrostatic pressure (HHP) treatment on sea cucumber qualities, such as shelf-life, autoenzyme, total volatile basic nitrogen (TVB-N), mucopolysaccha ride and protein, were investigated experim... The effects of high hydrostatic pressure (HHP) treatment on sea cucumber qualities, such as shelf-life, autoenzyme, total volatile basic nitrogen (TVB-N), mucopolysaccha ride and protein, were investigated experimentally. The shelf-life of sea cucumber was greatly prolonged by HHP treatment. High pressure treatment of sea cucumber significantly reduced the activity of autoenzyme at 550 MPa. The TVB-N content was 8.4 mg/100 g in the HHP-treated samples after 38 days' storage at 4 ~C, while it had already reached 11.2 mg/100 g in the untreated ones after 5 days' storage under the same condition. The relative mucopolysaccharide content of the HHP-treated samples was 94.3%, while that of the heat-treated ones was only 35.5%. The sodium dodecyl sulfate polyacrylamide gel electrophoresis (SDS-PAGE), Differential scanning calorimetric (DSC), ANS fluorescence probe method and fourier-transform infrared (FTIR) spectroscopy results indicated some changes in protein subunits, denaturation, surface hydrophobicity and secondary structure of sea cucumber protein. This study has provided complementary information of pressure-induced structural changes on both the molecular and the sub-molecular level of sea cucumber protein. 展开更多
关键词 High hydrostatic pressure sea cucumber shelf-life autoenzyme.
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Research on Dyeing Process for Polyamide with Aqueous Extracted from the Fruits of Diospyros Mollis
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作者 Hong Phuong Pham Thi Linh Hoang Thi +1 位作者 TrungKien Tran Thu Lan Nguyen Thi 《Journal of Environmental Science and Engineering(B)》 2016年第8期385-389,共5页
In this study, polyamide fabrics were dyed with aqueous extracts from Diospyros Mollis fruits. The aqueous extracts from Diospyros Mollis fruits were extracted with water solution at room temperature and a ratio of 1... In this study, polyamide fabrics were dyed with aqueous extracts from Diospyros Mollis fruits. The aqueous extracts from Diospyros Mollis fruits were extracted with water solution at room temperature and a ratio of 1:5 for Diospyros Mollis to water. The influences of temperature in range of 50-100 ℃, time in range of 30-80 minutes and a ratio of aqueous extracts to water in range of 3/1-1/11 were investigated. The results showed that the aqueous extracts from Diospyros Mollis fruits could dye polyamide fabrics to have black color with color strength and fastness properties to be very good level of 4-5. 展开更多
关键词 POLYAMIDE natural dyes Diospyros Mollis fruit.
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Interaction between Cross-Linked Polyacrylamide and Water and Solute Flow in a Sand and Loam
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作者 Mesude ümran Oyman Seval Sütinal Sabit Ersahin 《Journal of Environmental Science and Engineering(A)》 2012年第9期1117-1121,共5页
Superabsorbents such as cross-linked PAM (polyacrylamides) are frequently used to increase water availability to plants. Commercial PAM providers suggest that besides its increasing water availability, PAMs also inc... Superabsorbents such as cross-linked PAM (polyacrylamides) are frequently used to increase water availability to plants. Commercial PAM providers suggest that besides its increasing water availability, PAMs also increase nutrient availability to plants. To test this premise, four application rates (0.0 g·kg^-1, 0.33 g·kg^-1, 1.66 g·kg^-1, 3.33 g·kg^-1 and 6.66 g·kg^-1) ofa PAM were mixed with sandy and loamy soils to evaluate its effect on nutrient leaching and retention in these soils. Miscible displacements of chloride were conducted on columns of PAM-soil mixtures and results were evaluated by an equilibrium CDE (convection dispersion equation) model. Increasing the PAM rates up to 1.66 g·kg^-1 resulted in increased early appearance and dispersive transport of chloride in sand. In addition, increasing the PAM rates gradually caused increased tailing of the breakthrough curves of chloride in both soils. These suggested that PAM increased preferential transport of chloride while it increased retention of chloride in soils. Effect of PAM on preferential transport and retardation of CI was greater in sand than loam. 展开更多
关键词 PAM equilibrium CDE model preferential flow miscible displacement breakthrough curve.
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Experimental study on low temperature performance of polymer drilling mud agents
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作者 ZHAN Jiajia XU Huiwen CAI Hongliang 《Global Geology》 2009年第1期32-35,共4页
Drilling fluid additives has a major impact on rheology behavior and other performances of the drilling fluid.The key to low temperature drilling fluids is choosing antifreeze and polymer agent which have a strong abi... Drilling fluid additives has a major impact on rheology behavior and other performances of the drilling fluid.The key to low temperature drilling fluids is choosing antifreeze and polymer agent which have a strong ability in resisting low temperature.On the basis of determining glycol as antifreeze agent,the low-temperature-performance and capacities of anti-collapse of regular validity mud agents have been studied,the mechanism of anti-caving of the partially hydrolyzed polyacrylamide(PHPA),polypropylene potassium(KPA) and PAC-141 polymer additives have been also analyzed.A pilot study of compatibility between ethylene glycol and the polymers has educed that the polymers,ethylene glycol and inorganic salt are compatible,and they can significantly reduce the freezing point of drilling fluid.Anti-collapse ability of the drilling mud is the results of synergistic action among the agents. 展开更多
关键词 POLYMER low temperature performance antifreeze agent mechanism of anti-caving synergistic action
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