As a key factor limiting primary productivity in marine ecosystem, dissolved iron(DFe) export from fluvial systems has increased recently. There is particular concern about discharges of DFe during extreme flooding, w...As a key factor limiting primary productivity in marine ecosystem, dissolved iron(DFe) export from fluvial systems has increased recently. There is particular concern about discharges of DFe during extreme flooding, when they are thought to increase considerably. An extreme flood event that caused inundation of extensive areas of Far Eastern Russia and Northeastern China occurred in the basin of the Amur River during summer and autumn 2013. During this event, water samples were collected in the middle reaches of the Amur River and the lower reaches at Khabarovsk City and analyzed for DFe concentrations and other aquatic parameters. The results show that the average DFe concentrations in the middle reaches of the Amur River(right bank) and at Khabarovsk were 1.11 mg/L and 0.32 mg/L, respectively, during the extreme flood in 2013. The total discharge of DFe during the flood event was 6.25 × 104 t. The high discharge of DFe during the flood reflects the elevated discharge of the river, hydrologically connected riparian wetlands, vast quantities of terrestrial runoff, and flood discharges from the Zeya and Bureya reservoirs. These results show that long-term monitoring is needed to identify and assess the impacts of DFe transport on the downstream reaches, estuarine area, and coastal ecosystems of the Amur River.展开更多
Dissolved organic matter(DOM) is a group of compounds that have complex chemical structures and multiple interactions with their surrounding materials. More than one trillion tons of DOM are stocked in the world's...Dissolved organic matter(DOM) is a group of compounds that have complex chemical structures and multiple interactions with their surrounding materials. More than one trillion tons of DOM are stocked in the world's aquatic ecosystems. DOM is a very important part of aquatic ecosystem productivity and plays a crucial role in global carbon cycling. DOM has rich environmental behaviors and effects such as influencing the bioavailability of contaminants, serving as an important inducer of reactive oxygen species(ROS), and protecting aquatic organisms from the harm of dangerous ultraviolet radiation. There have been many systematic studies on the composition, structure, and sources of DOM because such studies are much easier to conduct than studies on the environmental behaviors and effects of DOM. Due to many factors, the research systems of DOM's environmental behaviors and effects are still being developed and have become a hotspot of environmental science. This review paper focuses on some critical progress, problems, and trends of DOM's environmental behaviors and effects in aquatic ecosystems, including mutual exchange mechanisms between DOM and particulate organic matter(POM) with influencing factors, photochemical behaviors of DOM especially inducing ROS, binding interactions between DOM and anthropogenic organic contaminants(AOC), interactions between DOM and microorganisms, effects of DOM on pollutants' bioavailability, ecotoxicity, and ecological risks. Hopefully, this paper will contribute to a more systematic understanding of the DOM environmental behaviors and effects and to promoting further relevant studies.展开更多
基金Under the auspices of National Natural Science Foundation of China(No.41271499,41471406)
文摘As a key factor limiting primary productivity in marine ecosystem, dissolved iron(DFe) export from fluvial systems has increased recently. There is particular concern about discharges of DFe during extreme flooding, when they are thought to increase considerably. An extreme flood event that caused inundation of extensive areas of Far Eastern Russia and Northeastern China occurred in the basin of the Amur River during summer and autumn 2013. During this event, water samples were collected in the middle reaches of the Amur River and the lower reaches at Khabarovsk City and analyzed for DFe concentrations and other aquatic parameters. The results show that the average DFe concentrations in the middle reaches of the Amur River(right bank) and at Khabarovsk were 1.11 mg/L and 0.32 mg/L, respectively, during the extreme flood in 2013. The total discharge of DFe during the flood event was 6.25 × 104 t. The high discharge of DFe during the flood reflects the elevated discharge of the river, hydrologically connected riparian wetlands, vast quantities of terrestrial runoff, and flood discharges from the Zeya and Bureya reservoirs. These results show that long-term monitoring is needed to identify and assess the impacts of DFe transport on the downstream reaches, estuarine area, and coastal ecosystems of the Amur River.
基金supported by the National Project for Water Pollution Control in China(Grant No.2012ZX07103-002)the National Natural Science Foundation of China(Grant Nos.4150308341271462&41030529)
文摘Dissolved organic matter(DOM) is a group of compounds that have complex chemical structures and multiple interactions with their surrounding materials. More than one trillion tons of DOM are stocked in the world's aquatic ecosystems. DOM is a very important part of aquatic ecosystem productivity and plays a crucial role in global carbon cycling. DOM has rich environmental behaviors and effects such as influencing the bioavailability of contaminants, serving as an important inducer of reactive oxygen species(ROS), and protecting aquatic organisms from the harm of dangerous ultraviolet radiation. There have been many systematic studies on the composition, structure, and sources of DOM because such studies are much easier to conduct than studies on the environmental behaviors and effects of DOM. Due to many factors, the research systems of DOM's environmental behaviors and effects are still being developed and have become a hotspot of environmental science. This review paper focuses on some critical progress, problems, and trends of DOM's environmental behaviors and effects in aquatic ecosystems, including mutual exchange mechanisms between DOM and particulate organic matter(POM) with influencing factors, photochemical behaviors of DOM especially inducing ROS, binding interactions between DOM and anthropogenic organic contaminants(AOC), interactions between DOM and microorganisms, effects of DOM on pollutants' bioavailability, ecotoxicity, and ecological risks. Hopefully, this paper will contribute to a more systematic understanding of the DOM environmental behaviors and effects and to promoting further relevant studies.
