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多层床煤热解提高油气品质的机理研究 被引量:6
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作者 曾令鹏 谢放华 +3 位作者 韩江则 周琦 高士秋 许光文 《煤炭转化》 CAS CSCD 北大核心 2014年第1期55-60,64,共7页
利用两段固定床对三层床煤依次经过450℃低温、650℃中温和900℃高温的分级热解过程进行模拟实验,研究了上两段中低温和下两段中高温热解相邻两段之间的相互作用,揭示了多层床煤热解提高油气品质的机理。通过中低温热解的相互作用,焦油... 利用两段固定床对三层床煤依次经过450℃低温、650℃中温和900℃高温的分级热解过程进行模拟实验,研究了上两段中低温和下两段中高温热解相邻两段之间的相互作用,揭示了多层床煤热解提高油气品质的机理。通过中低温热解的相互作用,焦油中轻质组分(沸点低于360℃的馏分)含量增加,热解气中CH_4含量增加,H_2含量减小,说明中低温热解主要通过半焦对热解产物的原位催化提质作用而提高焦油品质。通过中高温热解的相互作用,焦油收率和焦油中轻质组分含量增加,CH_4和CO含量升高,H_2含量下降,表示中高温热解的主要作用是在富含H_2气氛下热解提高焦油收率和品质.实验结果表明,多层床煤热解主要通过半焦的原位催化提质和富H_2气氛的协同作用而提高热解油气品质. 展开更多
关键词 两段固定床 多层床 煤热解 油气品质
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煤岩油气(矿)藏品质与油基质开发、加工参数分析
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作者 牛嘉玉 侯创业 +2 位作者 王好平 杨元一 金军 《石油学报(石油加工)》 EI CAS CSCD 北大核心 2009年第3期291-306,共16页
化石能源物理模型和煤岩油气(矿)藏的提出,为化石能源——石油和煤炭两大工业系统的资源开发与加工建立起相关的统一评价参数奠定了理论基础,也填补了H/C原子比为0.90~1.35的化石能源资源在自然界中存在方式和储集场所等方面的认识空... 化石能源物理模型和煤岩油气(矿)藏的提出,为化石能源——石油和煤炭两大工业系统的资源开发与加工建立起相关的统一评价参数奠定了理论基础,也填补了H/C原子比为0.90~1.35的化石能源资源在自然界中存在方式和储集场所等方面的认识空白。笔者从煤岩热成烃、与挥发分等参数的对应关系、煤岩组分构成特征、煤岩形成的地质环境和不同组分加工工艺评价参数等方面的分析入手,确定了煤岩油气(矿)藏的品质评价参数和划分方案,提出了我国不同品质煤岩油气(矿)藏的开发与加工技术思路。它区别于煤全岩直接加氢液化工艺,而是通过煤岩油气(矿)藏中油基质的开发,即富集和均质化类似于石油体系中的稠油-特超稠油组分,直接进入现有石油工业稠油加工体系,降低转化为石油制品的技术门槛,提高加工工艺的可控性,实现煤炭工业丰富的油基质资源和石油加工两大工业体系的对接,达到资源优势与加工优势互补的目的。并指出,中、西部地区可造就成为我国未来石油制成品的重要基地。 展开更多
关键词 化石能源工业 煤岩油气(矿)藏品质 油基质开发 油基质加工 油气资源潜力
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Pore structure effect on reservoir electrical properties and well logging evaluation 被引量:5
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作者 边环玲 关雎 +2 位作者 毛志强 鞠晓东 韩桂琴 《Applied Geophysics》 SCIE CSCD 2014年第4期374-383,508,共11页
The reservoir pore structure controls the reservoir quality and resistivity response of hydrocarbon-bearing zones and thus, critically affects logging interpretation. We use petrophysical data in three types of reserv... The reservoir pore structure controls the reservoir quality and resistivity response of hydrocarbon-bearing zones and thus, critically affects logging interpretation. We use petrophysical data in three types of reservoir with different pore structure characteristics to show that the complexity of pore structure had a significant effect on the effective porosity and permeability regardless of geological factors responsible for the formation of pore structure. Moreover,, the distribution and content of conductive fluids in the reservoir varies dramatically owing to pore structure differences, which also induces resistivity variations in reservoir rocks. Hence, the origin of low-resistivity hydrocarbon-bearing zones, except for those with conductive matrix and mud filtrate invasion, is attributed to the complexity of the pore structures. Consequently, reservoir-specific evaluation models, parameters, and criteria should be chosen for resistivity log interpretation to make a reliable evaluation of reservoir quality and fluids. 展开更多
关键词 pore structure reservoir quality RESISTIVITY low-resistivity hydrocarbon-bearing zone log evaluation
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Study on Technology for Quenching Catalytic Pyrolysis Gas
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作者 Lu Weimin 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2011年第1期58-63,共6页
This article describes the application of technology for quenching catalytic pyrolysis gas at the Daqing commercial CPP test unit and the Shenyang commercial CPP production unit.On the basis of results for application... This article describes the application of technology for quenching catalytic pyrolysis gas at the Daqing commercial CPP test unit and the Shenyang commercial CPP production unit.On the basis of results for application of the Shenyang CPP unit this paper puts forward an improved process flow scheme for quenching the pyrolysis gas and made calculations using the process flowsheet software.Case Ⅰ of the process flow scheme,which is designed for full circulation of slurry,intends to use the pyrolysis light oil and fresh feed oil as the quenching media with the product slurry oil and fresh feedstock being discharged from the quench cooler bottom and routed directly to the reactor so that the fresh feed oil can be preheated prior to pyrolysis.Case Ⅱ of the process flow scheme intends to adopt recycle oil as the quenching medium with the product slurry and recycle oil being discharged from the quench cooler bottom to the fractionator,which then delivers the slurry from the bottom.These two cases for improving the process flow diagram can all effectively control the density and viscosity of the quenching medium to secure the smooth operation of quench cooler. 展开更多
关键词 catalytic pyrolysis process quenching medium CPP gas
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