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静电纺聚偏二氟乙烯纤维膜的制备及其在油水分离中的应用 被引量:2
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作者 杨冬 杨凯棣 +2 位作者 贾彤彤 李旭华 贾顺田 《陕西科技大学学报》 北大核心 2023年第2期78-87,共10页
选择性透过膜用于油水分离具有能耗低、装置简便、易操作、效率高的特点,其核心在于采用过滤效率高及使用寿命长的膜材.本文采用了高压静电纺丝工艺,以聚偏二氟乙烯(PVDF)为原料,制备一种超疏水、结构可调控的电纺PVDF膜(EPVDF膜).利用... 选择性透过膜用于油水分离具有能耗低、装置简便、易操作、效率高的特点,其核心在于采用过滤效率高及使用寿命长的膜材.本文采用了高压静电纺丝工艺,以聚偏二氟乙烯(PVDF)为原料,制备一种超疏水、结构可调控的电纺PVDF膜(EPVDF膜).利用扫描电子显微镜(SEM)、傅立叶红外光谱(FTIR)、粉末X-射线衍射(XRD)、X-光电子能谱(XPS)等对EPVDF膜进行了形貌成份的表征,采用水接触角(WCA)对膜材表面特性进行了测试.结果表明,电纺PVDF膜的油水分离效率可达95%以上,对三种油水混合物均可实现30次以上的有效分离,其最大油通量可达到5 300 L/(m^(2)·h). 展开更多
关键词 静电纺聚偏二氟乙烯纳米纤维膜(EPVDF) 聚偏二氟乙烯(PVDF) 静电纺丝 水分离 油通量
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基于静电纺的超疏水超亲油串珠结构聚乳酸薄膜的制备及性能研究 被引量:7
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作者 孟鑫 谈书航 +6 位作者 曹齐茗 公维光 李捷 姚中阳 翟紫航 段润梓 辛忠 《中国塑料》 CAS CSCD 北大核心 2019年第4期48-53,共6页
分别采用物理添加和固载的方式在聚乳酸(PLA)基体当中引入聚硅氧烷(PSQ)粒子,并以此为基料进行电纺串珠结构的PLA纤维薄膜构筑。结果表明,PSQ的引入有利于串珠结构纤维的形成,并且串珠结构的形成使得PLA纤维膜的水接触角和孔隙率都明显... 分别采用物理添加和固载的方式在聚乳酸(PLA)基体当中引入聚硅氧烷(PSQ)粒子,并以此为基料进行电纺串珠结构的PLA纤维薄膜构筑。结果表明,PSQ的引入有利于串珠结构纤维的形成,并且串珠结构的形成使得PLA纤维膜的水接触角和孔隙率都明显上升,特别是PSQ的固载化处理,使得纤维膜的水接触角和孔隙率分别达到158°和54%,相对于单纯PLA纤维膜分别提高了5%和50%,进而使得纤维膜的疏水性能和油通量得到明显提升;此外,PSQ在PLA体系当中的固载,抑制了其在水解过程中的迁移,使得其可以长期保留在纤维膜当中发挥提升PLA疏水性能的作用,进而使得固载PSQ的PLA(PLA-PSQ)纤维膜体现出最佳的耐水解性能。 展开更多
关键词 静电纺丝 聚乳酸 串珠结构 油通量 耐水解
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亲油PVDF管式膜的改性及性能 被引量:2
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作者 刘恩华 王芳兵 +1 位作者 杨利娟 张苏广 《天津工业大学学报》 CAS 北大核心 2021年第3期21-25,共5页
为了提高聚偏氟乙烯(PVDF)管式膜的亲油性,以PVDF管式膜作为基膜,采用不同处理剂对其进行后处理,得到亲油管式膜;研究不同处理工艺条件、不同处理剂对膜透油通量的影响以及处理前后膜结构和性能的变化情况;采用电子显微镜(SEM)、原子力... 为了提高聚偏氟乙烯(PVDF)管式膜的亲油性,以PVDF管式膜作为基膜,采用不同处理剂对其进行后处理,得到亲油管式膜;研究不同处理工艺条件、不同处理剂对膜透油通量的影响以及处理前后膜结构和性能的变化情况;采用电子显微镜(SEM)、原子力显微镜(AFM)、Zeta电位测量仪对改性前后PVDF管式膜进行了表征。结果表明:改性后PVDF管式膜的接触角明显增加,粗糙度略有增大;处理剂1、处理剂2和处理剂3都能使基膜转化为亲油膜,在处理剂2处理1 h、晾干1 d的条件下,膜油通量可达到330.8 L/(m^(2)·h),表明改性后PVDF管式膜的亲油性有了很大的提高;用改性PVDF管式膜对废冷镦油进行了过滤,对亲油管式膜过滤后的废冷镦油的黏度、浊度、密度和含水率进行测试结果表明过滤后的废冷镦油黏度下降,浊度整体小于0,密度和含水率也有了一定的改善,表明改性PVDF管式膜对废冷镦油的处理效果良好。 展开更多
关键词 管式膜 油通量 PVDF
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PVDF/PBS纤维膜的制备及其在油水分离中的应用:基于静电纺丝 被引量:2
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作者 张佳敏 罗丹 +3 位作者 杨璐 张妍 刘丹凤 杨静晖 《功能材料》 EI CAS CSCD 北大核心 2019年第1期1199-1202,1209,共5页
通过静电纺丝制备疏水性PVDF/PBS纤维膜,并利用PVDF对PBS进行疏水改性。研究表明,PVDF的引入能使纤维膜的水接触角从86.5°转变至137.4°,表明PVDF能够有效改善PBS的疏水性。并且,PVDF的引入能够显著提高纤维膜的成膜性能与油... 通过静电纺丝制备疏水性PVDF/PBS纤维膜,并利用PVDF对PBS进行疏水改性。研究表明,PVDF的引入能使纤维膜的水接触角从86.5°转变至137.4°,表明PVDF能够有效改善PBS的疏水性。并且,PVDF的引入能够显著提高纤维膜的成膜性能与油水分离效率,并使纤维膜的油通量最高可达582L/(m^2·h)。 展开更多
关键词 静电纺丝 PVDF/PBS 水分离 油通量
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Control of Quackgrass in Grasslands Using Different Mechanical Weeding Strategies
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作者 Rym Khorchani Mohamed Khelifi Murielle Bournival 《Journal of Environmental Science and Engineering(B)》 2012年第11期1254-1262,共9页
It is well known that quackgrass is both very aggressive and persistent. In agriculture, many attempts have been made to eliminate this weed without success. Within the context of a sustainable agriculture, mechanical... It is well known that quackgrass is both very aggressive and persistent. In agriculture, many attempts have been made to eliminate this weed without success. Within the context of a sustainable agriculture, mechanical control of quackgrass represents an interesting alternative to chemical means. The use of a "C" shaped mounted tine cultivator, a rotary cross-harrow, and an "S" shaped trailed tine cultivator (alone or in combination) to control quackgrass in grassland was investigated. The rate of quackgrass present in each experimental plot was determined before and after the treatments using a one square meter quadrant. Also, the time required for each passage as well as the fuel consumption were computed. Results revealed that the fuel consumption and the time required by the "C" and "S" shaped tine cultivators to transport and expose the rhizomes to the sun on the soil surface highly depend on the quality of tillage during the first stubble passage. Also, subsequent tillage with the "C" shaped tine cultivator after a first passage with a rotary cross-harrow resulted in less fuel consumption and passage time. On the other hand, stubble and subsequent soil tillage with only the "C" shaped tine cultivator is the least successful method. 展开更多
关键词 WEEDS quackgrass Elymus repens GRASSLAND mechanical control tillage tools rotary cross-harrow cultivator.
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Full-Scale Measurement and Numerical Analysis of Liquefied Petroleum Gas Water Heaters with Ventilation Factors in Balcony
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作者 Chen-Wei Chiu Chiun-Hsun Chen +1 位作者 Chun-Wan Chen Yueh-Jen Chen 《Journal of Civil Engineering and Architecture》 2015年第11期1341-1353,共13页
This study carried out full-scale gas water heater combustion experiments and adopted FDS (fire dynamics simulator) to simulate three scenarios--different balcony environments when using water heater, such as airtig... This study carried out full-scale gas water heater combustion experiments and adopted FDS (fire dynamics simulator) to simulate three scenarios--different balcony environments when using water heater, such as airtight balcony, indoor door with openings and force ventilation to compare with full-scale combustion experiments. According to FDS simulation results, 02, CO and CO2 simulation concentration value correspond with full-scale experimental results. When the indoor O2 concentration was lower than 15%, which causes incomplete combustion, the CO concentration would rise rapidly and even reached above 1,500 ppm, causing death in short time. In addition, when the force ventilation model supplied the water heater with enough air to bum, the indoor CO concentration will keep low and harmless to humans. The study also adopted diverse variables, such as the opening area of window, outdoor wind speed and water heater types, to analyze deeply user's safety regarding gas water heater. In a result, while balcony area is larger than 14 mE, the volume of water heater is below 16 L (33.1 kW), and the indoor window, connecting balcony with room, is closed, if the opening on the outdoor window of the balcony is larger than 0.2 mE, this can ensure the personal security of the indoor space. 展开更多
关键词 Water heater carbon monoxide FDS POISON LPG (liquefied petroleum gas).
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Breakup Structure of Two-phase Jets with Various Momentum Flux from a Porous Injector 被引量:2
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作者 Inchul Lee Dohun Kim Jaye Koo 《Journal of Thermal Science》 SCIE EI CAS CSCD 2014年第1期60-67,共8页
Spray structure and atomization characteristics were investigated through a comparison of a porous and a shear coaxial injector. The porous injector shows better atomization performance than the shear coaxial injector... Spray structure and atomization characteristics were investigated through a comparison of a porous and a shear coaxial injector. The porous injector shows better atomization performance than the shear coaxial injector. To in- crease atomization performance and mixing efficiency of two-phase jets, a coaxial porous injector which can be applicable to liquid rocket combustors was designed and tested. The characteristics of atomization and spray from a porous and a shear coaxial injector were characterized by the momentum flux ratio. The breakup mechanism of the porous injector is governed by Taylor-Culick flow and axial shear forces. Momentum of injected gas flow through a porous material which is composed of sintered metal is radically transferred to the center of the liquid column, and then liquid column is effectively broken up. Although the shapes of spray from porous and shear co- axial jets were similar for various momentum ratio, spray structures such as spray angle and droplet sizes were different. As increasing the momentum flux ratio, SMD from the porous injector showed smaller value than the shear coaxial injector 展开更多
关键词 Porous injector Shear coaxial injector Breakup mechanism Momentum flux ratio
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Quantitative description of steam channels after steam flooding
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作者 ZHENG Qiang LIU HuiQing +3 位作者 LI Fang WANG Qing WANG ChangJiu LU Chuan 《Science China(Technological Sciences)》 SCIE EI CAS 2013年第5期1164-1168,共5页
Steam channeling is one of the main barriers for EOR after steam flooding.In order to enhance the oil recovery in steam flooded reservoirs,steam channel volumes should be precisely known.In this paper,a set of methods... Steam channeling is one of the main barriers for EOR after steam flooding.In order to enhance the oil recovery in steam flooded reservoirs,steam channel volumes should be precisely known.In this paper,a set of methods has been established in order to study steam channeling quantitatively by using dynamic data.Firstly,steam channeling wells are identified through curves of watercut and temperature.Then,considering the hysteresis phenomenon,channeling relations are identified with the correlation coefficients between injection wells and production wells under different conditions.Lastly,an analytic model,in which steam condensation,pressure and temperature are considered,is established to calculate the steam channel volumes.A production well named L31615 in some block in Henan Oilfield in China is systematically analyzed by using the method established.The whole block is further analyzed,and the distribution map of steam channels and the steam channel volumes are obtained.The results show that steam channeling does not only occur inside a well group,but also sometimes occurs between wells in different well groups.The calculation of the steam channel volumes provides a theoretical basis for bringing a remedial action like plugging into operation. 展开更多
关键词 heavy oil reservoir steam flooding steam channel dynamic data correlation coefficient
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