Phosphate-coating was prepared for C/C composite using liquid-impregnation and different heat-treatment. The results show that the mass-loss rate of sample A with 1-2 ℃/min slow-cooling rate technology is 47%after ox...Phosphate-coating was prepared for C/C composite using liquid-impregnation and different heat-treatment. The results show that the mass-loss rate of sample A with 1-2 ℃/min slow-cooling rate technology is 47%after oxidation at 700 ℃ for 20 h, while that of sample B with air-fast-cooling one is only 0.98%. SEM images reveal that the coating of sample A is full of micro-holes, micro-cracks and many piece-like crystal particles, while that of sample B is integrated and compacted in glassy state with a few of micro-cracks. The coating of sample A is almost exhausted only in 8 h oxidized-test at 700 ℃, while that of sample B remains integrated after 8 h test at 700 ℃ and becomes loose due to much small pores generated after 20 h test at 700 ℃.展开更多
Ti coating on A3 steel was successfully prepared by direct electrochemical reduction of high-velocity oxy-fuel (HVOF) thermally sprayed and room-temperature dip-coating titanium dioxide coating on A3 steel in molten...Ti coating on A3 steel was successfully prepared by direct electrochemical reduction of high-velocity oxy-fuel (HVOF) thermally sprayed and room-temperature dip-coating titanium dioxide coating on A3 steel in molten CaCl2 at 850 ℃. The interfacial microstructure and mutual diffusion between coating and steel substrate were investigated using scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) spectroscopy. The results show that the precursory TiO2 coating prepared by HVOF has closer contact and better adhesion with the A3 steel substrate. After electrolysis, all of the electro-generated Ti coatings show intact contact with the substrates, regardless of the original contact situation between TiO2 layer and the steel substrate in the precursors. The inter-diffusion between the iron substrate and the reduced titanium takes place at the interface. The results demonstrate the possibility of the surface electrochemical metallurgy (SECM) is a promising surface engineering and additive manufacturing method.展开更多
Fish communities in a (third-order) intertidal creek in Dongtan marsh in the Changjiang (Yangtze) River estuary were investigated seasonally for one year. A total of 1 996 fish specimens (10 967.8 g) comprising ...Fish communities in a (third-order) intertidal creek in Dongtan marsh in the Changjiang (Yangtze) River estuary were investigated seasonally for one year. A total of 1 996 fish specimens (10 967.8 g) comprising 26 species and 15 families were collected. Abundances of fish communities in the intertidal salt marsh creek were primarily dominated by Boleophthalmus pectinirostris (19.8%), Collichthys lucidus (18.6%), Periophthalmus magnuspinnatus (18.2%), Liza haematocheilus (17.9%), and secondarily by Mugilogobius abel (8.5%), L. carinatus (7.2%), Odontamblyopus lacepedii (4.3%), and Acanthogobius ommaturus (3.9%); another 18 species were present only occasionally. Non-MDS ordination and SIMPER analysis indicated that there were two fish communities in the intertidal salt marsh creek. In spring, the communities were dominated by B. pectinirostris, P. magnuspinnatus, C. lucidus and M. abei; in summer, autumn, and winter by L. haematocheilus, L. carinatus, A. ommaturus and O. lacepedii. Some species showed strong habitat selection; L. carinatus and P magnuspinnatus were distributed mainly in the upper and middle creek, while B. pectinirostris, M. abei and O. lacepedii inhabited the middle and lower creek. The study indicated that the salt marshes of the Changjiang River estuary are an important nursery and feeding habitat for many fishes and should be protected.展开更多
We evaluated the effects of salinity and body mass on the oxygen consumption rate and ammonia excretion rate of mudskipper Boleophthalmus pectinirostris under laboratory conditions. Salinity and body mass had highly s...We evaluated the effects of salinity and body mass on the oxygen consumption rate and ammonia excretion rate of mudskipper Boleophthalmus pectinirostris under laboratory conditions. Salinity and body mass had highly significant effects on the oxygen consumption rate (Ro) and ammonia excretion rate (RN) (P〈0.01). The interactive effects between salinity and body mass on Ro and RN were insignificant (P〉0.05) and highly significant (P〈0.01), respectively. Ro and RN of B. pectinirostris decreased significantly as the individual body mass increased. The relationship between Ro and body mass was represented by Ro=aWb (R^2=0.956, P〈0.01). The relationship between RN and the body mass ofB. pectinirostris was represented by RN-cW^at (R^2=0.966, P〈0.01). The Ro/RN (O:N) ratios increased significantly as the salinity increased from 12 to 27, but decreased as salinity increased from 27 to 32. The atomic O:N ratios were significantly higher at 27 than at other salinity levels. The average O:N ratio was 25.25. Lipid and carbohydrate were the primary energy sources and protein was the secondary energy significantly higher at 27 than at other salinity levels B, pectinirostris is 27. source within the salinity range 12 32. Ro andRN were Our results suggest that the optimum salinity level for B. pectinirostris is 27.展开更多
Directing at the characteristics of coastal mudfiat saline and alkaline land, the yield of salt-tolerant Spartina and rice could reach 5 925-8 280 kg/hm^2 by the techniques of land and water resource utilization, farm...Directing at the characteristics of coastal mudfiat saline and alkaline land, the yield of salt-tolerant Spartina and rice could reach 5 925-8 280 kg/hm^2 by the techniques of land and water resource utilization, farming improvement, construction of matched water system, seed selection and treatment, water direct seeding, seedling raising on seedbed, field transplanting, weeding, nutrient and water management, and disease and pest control, providing a scientific basis for the cultivation of Spartina and Rice in coast mudflat.展开更多
In order to recover the SiO_2 contained in the mother liquor in the course ofNaY zeolite synthesis to minimize pollution, the influence of various preparation conditions on thefiltering velocity of gel slurry was stud...In order to recover the SiO_2 contained in the mother liquor in the course ofNaY zeolite synthesis to minimize pollution, the influence of various preparation conditions on thefiltering velocity of gel slurry was studied using the SiO_2/Al_2O_3 gel recovered from the NaYmother liquor in the laboratory. The results of study had shown that at a SiO_2/Al_2O_3 ratio in thefeed equating to 9∶1 the SiO_2 recovery rate and Al_2O_3 utilization rate were high with a fasterflow velocity of the filtrate. The pH value of the system had great impact on the flow velocity offiltrate. Between the two methods for regulating the pH value, the one for formation ofsilica/alumina gel slurry by addition of sulfuric acid prior to adding aluminium sulfate in thesolution could secure a faster filtration velocity. The filtration velocity was decreased in tandemwith increasing SiO_2 concentration in mother liquor, meanwhile an increase in dry filter cakeyield.展开更多
A low-toxicity and environment-friendly NaCl−KCl−CsCl−K_(2)NbF_(7) system was used to prepare Nb coatings on Mo substrates.The effects of temperature,current density and electrodeposition time on the micromorphologies...A low-toxicity and environment-friendly NaCl−KCl−CsCl−K_(2)NbF_(7) system was used to prepare Nb coatings on Mo substrates.The effects of temperature,current density and electrodeposition time on the micromorphologies and textures of the electrodeposited Nb coatings were studied.The results showed that Nb coatings obtained at 30−70 mA/cm^(2) in the temperature range of 700−750℃ were continuous and compact,with a hardness range of 2.16−2.45 GPa.As the columnar crystals grew with time,the preferential growth orientations of the Nb coatings changed from<200>to<211>and then became disordered.With increasing polarization,the morphologies of the Nb coatings changed from hexagonal star-like surface to conical or pyramid-like surface.展开更多
Several TAAFS (tetraalkylammonium hexafluorosilicates) with different cations were synthesized. Their thermal properties were studied showing that obtained complexes are stable enough to be suitable for electrochemi...Several TAAFS (tetraalkylammonium hexafluorosilicates) with different cations were synthesized. Their thermal properties were studied showing that obtained complexes are stable enough to be suitable for electrochemical deposition of silicon coatings under temperatures at least up to 200 ℃.展开更多
Antimicrobial and photocatalytic effect of silicate and silicone paints were tested. Silicate paints are based on water styrene-acrylic dispersion with mineral binder into form of potassium water glass. Silicone paint...Antimicrobial and photocatalytic effect of silicate and silicone paints were tested. Silicate paints are based on water styrene-acrylic dispersion with mineral binder into form of potassium water glass. Silicone paints are based on water acrylic dispersion with silicone resin emulsion. Silicate and silicone paints were formulated with photocatalytic active nanooxides TiO2 and ZnO. Photocatalytic efficiency of coatings was measured as an absorbance change of organic dye Orange II solution at a wavelength of 485 nm. Antimicrobial properties of coatings were tested using agar plate methods. As test microorganisms Pseudomonas aeruginosa, Escherichia coli, Staphylococcus aureus, Penicillium chrysogenum and Aspergillus niger suspension (density 10^6 cells/mL) were used. The inhibition effect of tested coatings and inhibitory zones were evaluated after incubation. Coatings containing nanoparticles of titanium dioxide and zinc oxide showed antimicrobial activity against the test microorganisms. Whereas coating with zinc oxide nanoparticles successfully inhibited the growth of both bacteria and fungi, the photocatalytic nanoparticles of titanium dioxide inhibited bacteria but not fungi (weak inhibition was observed).展开更多
An organic-magnesium complex conversion(OMCC)coating on AZ91D magnesium alloy was obtained by treating in a solution containing organic compounds.SEM,FESEM and XPS were used to examine the surface morphology,thickness...An organic-magnesium complex conversion(OMCC)coating on AZ91D magnesium alloy was obtained by treating in a solution containing organic compounds.SEM,FESEM and XPS were used to examine the surface morphology,thickness and structure of the conversion coatings.The results show that the continuous and uniform conversion coating is deposited on AZ91D alloy and the main component of the coatings is organic compound containing benzene ring,which forms a chemical bond with magnesium.The polarization measurement and salt spray test show that the corrosion resistance of the conversion coating is much higher than that of traditional chromate conversion coating.展开更多
A combined process of molten salt electro-deoxidation and vacuum hot-pressing sintering was proposed to prepare AlCrFeNiTi_(x) high-entropy alloy(HEA)-TiN ceramic coating composites on low-carbon steel surfaces,where ...A combined process of molten salt electro-deoxidation and vacuum hot-pressing sintering was proposed to prepare AlCrFeNiTi_(x) high-entropy alloy(HEA)-TiN ceramic coating composites on low-carbon steel surfaces,where nitrides were introduced from BN isolater between graphite mold and HEA powders.The effect of Ti content on the microstructure,ultimate tensile strength,hardness,and wear resistance of the composites was investigated,and the bonding mechanism was elucidated.Results demonstrate that the composites have excellent hardness and wear resistance.The hardness of composites is significantly increased with the increase in Ti content.The extremely high wear resistance is attributed to the extremely high melting point and high thermal hardness of TiN,which can effectively prevent oxidation deformation of the worn surface.展开更多
采用涂Na Cl/Na2SO4盐方法研究了DZ466合金在850℃和950℃条件下热腐蚀行为.结果表明:合金的腐蚀层包括三个区域,最外层为(Ni,Co)O氧化物层,次外层为尖晶石结构氧化层(Ni,Co)Cr2O4,内层为内腐蚀层,850℃时该层为Ni3S2,而950℃时除Ni3S2...采用涂Na Cl/Na2SO4盐方法研究了DZ466合金在850℃和950℃条件下热腐蚀行为.结果表明:合金的腐蚀层包括三个区域,最外层为(Ni,Co)O氧化物层,次外层为尖晶石结构氧化层(Ni,Co)Cr2O4,内层为内腐蚀层,850℃时该层为Ni3S2,而950℃时除Ni3S2外,在靠近次外层还形成内氧化Al2O3;在850℃和950℃时合金的热腐蚀机制相同,氧化膜连续性的破坏,是合金遭受热腐蚀的主要原因;热腐蚀增重曲线均符合抛物线规律,其速率常数分别为3.1×10-11g2·cm-4·s-1和1.5×10-9g2·cm-4·s-1,热腐蚀激活能分别为179.2 k J·mol-1和138.3 k J·mol-1.展开更多
TiN, platinum (Pt) black and iridium oxide are introduced to the stimulating sites to improve the performance of the flexible electrode. Low temperature process is used to fabricate the modifying films. TiN is coate...TiN, platinum (Pt) black and iridium oxide are introduced to the stimulating sites to improve the performance of the flexible electrode. Low temperature process is used to fabricate the modifying films. TiN is coated on the gold sites by magnetron sputtering while platinum black and iridium oxide are coated by electroplating and electrodeposifion, respectively. The impedance of the electrode decreases dramatically after modification. The combined analysis of surface morphology and cyclic voltammograms (CV) in phosphate buffer saline (PBS) solution indicates that the modified electrode sites have larger electrode-electrolyte capacitance and smaller faradic resistance than unmodified sites, thus they have smaller electrochemical impedances.展开更多
基金Projects(09JJ4027)supported by the Natural Science Foundation of Hunan Province,ChinaProject(201206375003)supported by China Scholarship Council
文摘Phosphate-coating was prepared for C/C composite using liquid-impregnation and different heat-treatment. The results show that the mass-loss rate of sample A with 1-2 ℃/min slow-cooling rate technology is 47%after oxidation at 700 ℃ for 20 h, while that of sample B with air-fast-cooling one is only 0.98%. SEM images reveal that the coating of sample A is full of micro-holes, micro-cracks and many piece-like crystal particles, while that of sample B is integrated and compacted in glassy state with a few of micro-cracks. The coating of sample A is almost exhausted only in 8 h oxidized-test at 700 ℃, while that of sample B remains integrated after 8 h test at 700 ℃ and becomes loose due to much small pores generated after 20 h test at 700 ℃.
基金Projects(51071112,51325102)supported by the National Natural Science Foundation of China
文摘Ti coating on A3 steel was successfully prepared by direct electrochemical reduction of high-velocity oxy-fuel (HVOF) thermally sprayed and room-temperature dip-coating titanium dioxide coating on A3 steel in molten CaCl2 at 850 ℃. The interfacial microstructure and mutual diffusion between coating and steel substrate were investigated using scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) spectroscopy. The results show that the precursory TiO2 coating prepared by HVOF has closer contact and better adhesion with the A3 steel substrate. After electrolysis, all of the electro-generated Ti coatings show intact contact with the substrates, regardless of the original contact situation between TiO2 layer and the steel substrate in the precursors. The inter-diffusion between the iron substrate and the reduced titanium takes place at the interface. The results demonstrate the possibility of the surface electrochemical metallurgy (SECM) is a promising surface engineering and additive manufacturing method.
基金Supported by Special Research Fund for the National Non-profit Institutes (East China Sea Fisheries Research Institute) (No.2007M03) and Administration Bureau of Virescence of Shanghai Municipality
文摘Fish communities in a (third-order) intertidal creek in Dongtan marsh in the Changjiang (Yangtze) River estuary were investigated seasonally for one year. A total of 1 996 fish specimens (10 967.8 g) comprising 26 species and 15 families were collected. Abundances of fish communities in the intertidal salt marsh creek were primarily dominated by Boleophthalmus pectinirostris (19.8%), Collichthys lucidus (18.6%), Periophthalmus magnuspinnatus (18.2%), Liza haematocheilus (17.9%), and secondarily by Mugilogobius abel (8.5%), L. carinatus (7.2%), Odontamblyopus lacepedii (4.3%), and Acanthogobius ommaturus (3.9%); another 18 species were present only occasionally. Non-MDS ordination and SIMPER analysis indicated that there were two fish communities in the intertidal salt marsh creek. In spring, the communities were dominated by B. pectinirostris, P. magnuspinnatus, C. lucidus and M. abei; in summer, autumn, and winter by L. haematocheilus, L. carinatus, A. ommaturus and O. lacepedii. Some species showed strong habitat selection; L. carinatus and P magnuspinnatus were distributed mainly in the upper and middle creek, while B. pectinirostris, M. abei and O. lacepedii inhabited the middle and lower creek. The study indicated that the salt marshes of the Changjiang River estuary are an important nursery and feeding habitat for many fishes and should be protected.
基金Supported by the Natural Science Foundation of Guangdong Province(No.8152408801000015)
文摘We evaluated the effects of salinity and body mass on the oxygen consumption rate and ammonia excretion rate of mudskipper Boleophthalmus pectinirostris under laboratory conditions. Salinity and body mass had highly significant effects on the oxygen consumption rate (Ro) and ammonia excretion rate (RN) (P〈0.01). The interactive effects between salinity and body mass on Ro and RN were insignificant (P〉0.05) and highly significant (P〈0.01), respectively. Ro and RN of B. pectinirostris decreased significantly as the individual body mass increased. The relationship between Ro and body mass was represented by Ro=aWb (R^2=0.956, P〈0.01). The relationship between RN and the body mass ofB. pectinirostris was represented by RN-cW^at (R^2=0.966, P〈0.01). The Ro/RN (O:N) ratios increased significantly as the salinity increased from 12 to 27, but decreased as salinity increased from 27 to 32. The atomic O:N ratios were significantly higher at 27 than at other salinity levels. The average O:N ratio was 25.25. Lipid and carbohydrate were the primary energy sources and protein was the secondary energy significantly higher at 27 than at other salinity levels B, pectinirostris is 27. source within the salinity range 12 32. Ro andRN were Our results suggest that the optimum salinity level for B. pectinirostris is 27.
文摘Directing at the characteristics of coastal mudfiat saline and alkaline land, the yield of salt-tolerant Spartina and rice could reach 5 925-8 280 kg/hm^2 by the techniques of land and water resource utilization, farming improvement, construction of matched water system, seed selection and treatment, water direct seeding, seedling raising on seedbed, field transplanting, weeding, nutrient and water management, and disease and pest control, providing a scientific basis for the cultivation of Spartina and Rice in coast mudflat.
文摘In order to recover the SiO_2 contained in the mother liquor in the course ofNaY zeolite synthesis to minimize pollution, the influence of various preparation conditions on thefiltering velocity of gel slurry was studied using the SiO_2/Al_2O_3 gel recovered from the NaYmother liquor in the laboratory. The results of study had shown that at a SiO_2/Al_2O_3 ratio in thefeed equating to 9∶1 the SiO_2 recovery rate and Al_2O_3 utilization rate were high with a fasterflow velocity of the filtrate. The pH value of the system had great impact on the flow velocity offiltrate. Between the two methods for regulating the pH value, the one for formation ofsilica/alumina gel slurry by addition of sulfuric acid prior to adding aluminium sulfate in thesolution could secure a faster filtration velocity. The filtration velocity was decreased in tandemwith increasing SiO_2 concentration in mother liquor, meanwhile an increase in dry filter cakeyield.
基金the Special Fund of Hunan Province for Innovative Province Building-Support Program for Young Talents of Hunan,China(No.2020RC3034).
文摘A low-toxicity and environment-friendly NaCl−KCl−CsCl−K_(2)NbF_(7) system was used to prepare Nb coatings on Mo substrates.The effects of temperature,current density and electrodeposition time on the micromorphologies and textures of the electrodeposited Nb coatings were studied.The results showed that Nb coatings obtained at 30−70 mA/cm^(2) in the temperature range of 700−750℃ were continuous and compact,with a hardness range of 2.16−2.45 GPa.As the columnar crystals grew with time,the preferential growth orientations of the Nb coatings changed from<200>to<211>and then became disordered.With increasing polarization,the morphologies of the Nb coatings changed from hexagonal star-like surface to conical or pyramid-like surface.
文摘Several TAAFS (tetraalkylammonium hexafluorosilicates) with different cations were synthesized. Their thermal properties were studied showing that obtained complexes are stable enough to be suitable for electrochemical deposition of silicon coatings under temperatures at least up to 200 ℃.
文摘Antimicrobial and photocatalytic effect of silicate and silicone paints were tested. Silicate paints are based on water styrene-acrylic dispersion with mineral binder into form of potassium water glass. Silicone paints are based on water acrylic dispersion with silicone resin emulsion. Silicate and silicone paints were formulated with photocatalytic active nanooxides TiO2 and ZnO. Photocatalytic efficiency of coatings was measured as an absorbance change of organic dye Orange II solution at a wavelength of 485 nm. Antimicrobial properties of coatings were tested using agar plate methods. As test microorganisms Pseudomonas aeruginosa, Escherichia coli, Staphylococcus aureus, Penicillium chrysogenum and Aspergillus niger suspension (density 10^6 cells/mL) were used. The inhibition effect of tested coatings and inhibitory zones were evaluated after incubation. Coatings containing nanoparticles of titanium dioxide and zinc oxide showed antimicrobial activity against the test microorganisms. Whereas coating with zinc oxide nanoparticles successfully inhibited the growth of both bacteria and fungi, the photocatalytic nanoparticles of titanium dioxide inhibited bacteria but not fungi (weak inhibition was observed).
基金Project(50871046)supported by the National Natural Science Foundation of ChinaProject(2007KZ09)supported by the 2007 Scienceand Technology Support Plan of Changchun City,China
文摘An organic-magnesium complex conversion(OMCC)coating on AZ91D magnesium alloy was obtained by treating in a solution containing organic compounds.SEM,FESEM and XPS were used to examine the surface morphology,thickness and structure of the conversion coatings.The results show that the continuous and uniform conversion coating is deposited on AZ91D alloy and the main component of the coatings is organic compound containing benzene ring,which forms a chemical bond with magnesium.The polarization measurement and salt spray test show that the corrosion resistance of the conversion coating is much higher than that of traditional chromate conversion coating.
基金National Natural Science Foundation of China(52174315)Youth Scholars Promotion Plan of North China University of Science and Technology(QNTJ202304)。
文摘A combined process of molten salt electro-deoxidation and vacuum hot-pressing sintering was proposed to prepare AlCrFeNiTi_(x) high-entropy alloy(HEA)-TiN ceramic coating composites on low-carbon steel surfaces,where nitrides were introduced from BN isolater between graphite mold and HEA powders.The effect of Ti content on the microstructure,ultimate tensile strength,hardness,and wear resistance of the composites was investigated,and the bonding mechanism was elucidated.Results demonstrate that the composites have excellent hardness and wear resistance.The hardness of composites is significantly increased with the increase in Ti content.The extremely high wear resistance is attributed to the extremely high melting point and high thermal hardness of TiN,which can effectively prevent oxidation deformation of the worn surface.
文摘采用涂Na Cl/Na2SO4盐方法研究了DZ466合金在850℃和950℃条件下热腐蚀行为.结果表明:合金的腐蚀层包括三个区域,最外层为(Ni,Co)O氧化物层,次外层为尖晶石结构氧化层(Ni,Co)Cr2O4,内层为内腐蚀层,850℃时该层为Ni3S2,而950℃时除Ni3S2外,在靠近次外层还形成内氧化Al2O3;在850℃和950℃时合金的热腐蚀机制相同,氧化膜连续性的破坏,是合金遭受热腐蚀的主要原因;热腐蚀增重曲线均符合抛物线规律,其速率常数分别为3.1×10-11g2·cm-4·s-1和1.5×10-9g2·cm-4·s-1,热腐蚀激活能分别为179.2 k J·mol-1和138.3 k J·mol-1.
基金supported by the Major National Scientific Research Plan (Grant Nos. 2011CB933203, 2011CB933102)National Natural Science Foundation of China (Grant Nos. 61036002, 60877035, 31070965)
文摘TiN, platinum (Pt) black and iridium oxide are introduced to the stimulating sites to improve the performance of the flexible electrode. Low temperature process is used to fabricate the modifying films. TiN is coated on the gold sites by magnetron sputtering while platinum black and iridium oxide are coated by electroplating and electrodeposifion, respectively. The impedance of the electrode decreases dramatically after modification. The combined analysis of surface morphology and cyclic voltammograms (CV) in phosphate buffer saline (PBS) solution indicates that the modified electrode sites have larger electrode-electrolyte capacitance and smaller faradic resistance than unmodified sites, thus they have smaller electrochemical impedances.