Aim To investigate the melting behavior of polyamide 6 in polyamide 6/polyethy lene blends crystallized from amorphous state. Methods DSC was used to test effects of annealing temperature, annealing time, DS...Aim To investigate the melting behavior of polyamide 6 in polyamide 6/polyethy lene blends crystallized from amorphous state. Methods DSC was used to test effects of annealing temperature, annealing time, DSC scan rate, and the step wise annealing on the melting peaks of the ice water quenched specimens. Results and Conclusion Varied melting peaks of PA6 component were obtained. The degree of perfection and the crystallization degree of PA6 crystals decreased in the blends, and the crystallization degree of PA6 increased with the increasing of the annealing time. The height of the upper melting peak of reference PA6 is higher than that in blends.展开更多
Aim To investigate the multiple melting behavior of polyamide 6(PA 6) in polyamide 6/linear low density polyethylene blends crystallized from the crystal amorphous state. Methods\ The effects of annealing tempera...Aim To investigate the multiple melting behavior of polyamide 6(PA 6) in polyamide 6/linear low density polyethylene blends crystallized from the crystal amorphous state. Methods\ The effects of annealing temperature, annealing time, heating rate, and the step wise annealing were measured by DSC. Results and Conclusion\ There exists a critical heating rate affecting the middle temperature melting peak. When annealed at the temperature close to the melting peak, the main melting peak of PA 6 shifted to a higher temperature. Within a short time, annealing time has much effect on neat PA 6 but little effect on PA 6 in the blends. Addition of PE results in a decreasing in the height of melting peak. These phenomenon show that the melting behavior of PA 6 was affected by PE, compatibilizer, as well as thermal treatment.展开更多
The effect of sinter basicity on softening-melting behaviors of mixed burden made from chromium-bearing vanadium-titanium magnetite(Cr-V-Ti magnetite) was investigated and the function mechanism was simultaneously ana...The effect of sinter basicity on softening-melting behaviors of mixed burden made from chromium-bearing vanadium-titanium magnetite(Cr-V-Ti magnetite) was investigated and the function mechanism was simultaneously analyzed.The results show that with increasing sinter basicity from 1.71 to 2.36,the softening interval tends to increase from 149.3 ℃ to 181.7 ℃while the melting interval tends to decrease from 178.0 ℃ to 136.7 ℃.The location of cohesive zone moves downwards firstly and then ascends slightly,but the cohesive zone becomes thinner.The softening-melting characteristic value becomes small,which indicates that the permeability of burden column is improved.The dripping ratio of mixed burden tends to increase firstly and then decrease,which comes to the highest value of 74.50%when the sinter basicity is 2.13.The content and the recovery of V and Cr in dripping iron are all increased.The generation amount of components with high melting point in slag becomes little with the increase of sinter basicity,which could improve the permeability of mixed burden.Taking softening-melting behaviors of mixed burden and recovery of valuable elements into account,the proper sinter basicity is no less than 2.13 for smelting mixed burden made from Cr-V-Ti magnetite in blast furnace.展开更多
文摘Aim To investigate the melting behavior of polyamide 6 in polyamide 6/polyethy lene blends crystallized from amorphous state. Methods DSC was used to test effects of annealing temperature, annealing time, DSC scan rate, and the step wise annealing on the melting peaks of the ice water quenched specimens. Results and Conclusion Varied melting peaks of PA6 component were obtained. The degree of perfection and the crystallization degree of PA6 crystals decreased in the blends, and the crystallization degree of PA6 increased with the increasing of the annealing time. The height of the upper melting peak of reference PA6 is higher than that in blends.
文摘Aim To investigate the multiple melting behavior of polyamide 6(PA 6) in polyamide 6/linear low density polyethylene blends crystallized from the crystal amorphous state. Methods\ The effects of annealing temperature, annealing time, heating rate, and the step wise annealing were measured by DSC. Results and Conclusion\ There exists a critical heating rate affecting the middle temperature melting peak. When annealed at the temperature close to the melting peak, the main melting peak of PA 6 shifted to a higher temperature. Within a short time, annealing time has much effect on neat PA 6 but little effect on PA 6 in the blends. Addition of PE results in a decreasing in the height of melting peak. These phenomenon show that the melting behavior of PA 6 was affected by PE, compatibilizer, as well as thermal treatment.
基金Project(51574067)supported by the National Natural Science Fundation of ChinaProjects(2012AA062302,2012AA062304)supported by the National High Technology Research and Development Program of ChinaProject(N110202001)supported by the Fundamental Research Funds for the Central Universities of China
文摘The effect of sinter basicity on softening-melting behaviors of mixed burden made from chromium-bearing vanadium-titanium magnetite(Cr-V-Ti magnetite) was investigated and the function mechanism was simultaneously analyzed.The results show that with increasing sinter basicity from 1.71 to 2.36,the softening interval tends to increase from 149.3 ℃ to 181.7 ℃while the melting interval tends to decrease from 178.0 ℃ to 136.7 ℃.The location of cohesive zone moves downwards firstly and then ascends slightly,but the cohesive zone becomes thinner.The softening-melting characteristic value becomes small,which indicates that the permeability of burden column is improved.The dripping ratio of mixed burden tends to increase firstly and then decrease,which comes to the highest value of 74.50%when the sinter basicity is 2.13.The content and the recovery of V and Cr in dripping iron are all increased.The generation amount of components with high melting point in slag becomes little with the increase of sinter basicity,which could improve the permeability of mixed burden.Taking softening-melting behaviors of mixed burden and recovery of valuable elements into account,the proper sinter basicity is no less than 2.13 for smelting mixed burden made from Cr-V-Ti magnetite in blast furnace.
