An incubation experiment was conducted to evaluate the potential for water contamination with sludge-derived organic substances and copper following land application of alkaline-stabilised sewage sludge. Twocontrastin...An incubation experiment was conducted to evaluate the potential for water contamination with sludge-derived organic substances and copper following land application of alkaline-stabilised sewage sludge. Twocontrasting sludge-amended soils were studied. Both soils were previously treated with urban and ruralalkaline biosolids separately at sludge application rates of 0, 30 and 120 t ha-1 fresh product. The air-driedsoil/sludge mixtures were wetted with distilled water, maintained at 40 % of water-holding capacity andequilibrated for three weeks at 4 ℃ before extraction. Subsamples were extracted with either distilled wateror 0.5 mol L-1 K2SO4 solution. The concentrations of organic C in the aqueous and chemical extractswere determined directly with a total organic carbon (TOC) analyser. The concentrations of Cu in the twoextracts were also determined by atomic absorption spectrophotometry The relationship between the twoextractable organic C fractions was examined, together with展开更多
The leaching kinetics of low grade zinc oxide ore in NH3-NH4Cl-H2O system was studied. The effects of ore particle size, reaction temperature and the sum concentration of ammonium ion and ammonia on the leaching effic...The leaching kinetics of low grade zinc oxide ore in NH3-NH4Cl-H2O system was studied. The effects of ore particle size, reaction temperature and the sum concentration of ammonium ion and ammonia on the leaching efficiency of zinc were examined. The leaching kinetics of low-grade zinc oxide ore in NH3-NH4Cl-H2O system follows the kinetic law of shrinking-core model. The results show that diffusion through the inert particle pores is the leaching kinetics rate controlling step. The calculated apparent activation energy of the process is about 7.057 kJ/mol. The leaching efficiency of zinc is 92.1% under the conditions of ore particle size of 69 μm, holding at 80 ℃ for 60 min, sum ammonia concentration of 7.5 mol/L, the molar ratio of ammonium to ammonia being 2-1, and the ratio (g/mL) of solid to liquid being 1-10.展开更多
As the multibarrier system has been adopted to dispose HLW glass in geological formation in many coun- tries, it was important to study the leaching behavior of vitrification under geological formation. This article d...As the multibarrier system has been adopted to dispose HLW glass in geological formation in many coun- tries, it was important to study the leaching behavior of vitrification under geological formation. This article describes the leaching behavior of simulated high level waste glass (90Nd/10), which can incorporate 16 wt.% simulated HLW in five kinds of geological media, such as granite, cement, bentonite, Fe3O4, etc. The durable experimental results show that the glass had less mass loss in granite and more mass loss in bentonite after a two-year leaching test. The SEM/XEDS analysis shows some element distributions on the leached specimen’s surface, i.e., Na, Si and Mg ele- ments were reduced on the specimen’s surface, whereas Ba, Al, and Fe were enriched on the specimen’s surface.展开更多
基金National Natural Science Foundation of China(No.49831070 and 40125005)theNational Key Basic Research Support Foundation (NKBRSF) of China (No. G1999011807) the Jiangsu Provincial Foundation for Young Scientists (No. BQ98050).
文摘An incubation experiment was conducted to evaluate the potential for water contamination with sludge-derived organic substances and copper following land application of alkaline-stabilised sewage sludge. Twocontrasting sludge-amended soils were studied. Both soils were previously treated with urban and ruralalkaline biosolids separately at sludge application rates of 0, 30 and 120 t ha-1 fresh product. The air-driedsoil/sludge mixtures were wetted with distilled water, maintained at 40 % of water-holding capacity andequilibrated for three weeks at 4 ℃ before extraction. Subsamples were extracted with either distilled wateror 0.5 mol L-1 K2SO4 solution. The concentrations of organic C in the aqueous and chemical extractswere determined directly with a total organic carbon (TOC) analyser. The concentrations of Cu in the twoextracts were also determined by atomic absorption spectrophotometry The relationship between the twoextractable organic C fractions was examined, together with
基金Project(2007CB613604) supported by the Major State Basic Research Development Program of ChinaProject(50674104) supported by the National Natural Science Foundation of ChinaProject(GJJ08279) supported by the Department of Education of Jiangxi Province
文摘The leaching kinetics of low grade zinc oxide ore in NH3-NH4Cl-H2O system was studied. The effects of ore particle size, reaction temperature and the sum concentration of ammonium ion and ammonia on the leaching efficiency of zinc were examined. The leaching kinetics of low-grade zinc oxide ore in NH3-NH4Cl-H2O system follows the kinetic law of shrinking-core model. The results show that diffusion through the inert particle pores is the leaching kinetics rate controlling step. The calculated apparent activation energy of the process is about 7.057 kJ/mol. The leaching efficiency of zinc is 92.1% under the conditions of ore particle size of 69 μm, holding at 80 ℃ for 60 min, sum ammonia concentration of 7.5 mol/L, the molar ratio of ammonium to ammonia being 2-1, and the ratio (g/mL) of solid to liquid being 1-10.
文摘As the multibarrier system has been adopted to dispose HLW glass in geological formation in many coun- tries, it was important to study the leaching behavior of vitrification under geological formation. This article describes the leaching behavior of simulated high level waste glass (90Nd/10), which can incorporate 16 wt.% simulated HLW in five kinds of geological media, such as granite, cement, bentonite, Fe3O4, etc. The durable experimental results show that the glass had less mass loss in granite and more mass loss in bentonite after a two-year leaching test. The SEM/XEDS analysis shows some element distributions on the leached specimen’s surface, i.e., Na, Si and Mg ele- ments were reduced on the specimen’s surface, whereas Ba, Al, and Fe were enriched on the specimen’s surface.
