The influences of temperature, pressure, catalyst content, H 2O 2 content and mol ratio of propylene to H 2O 2 on epoxidation of propylene with H 2O 2 over TS-1 in a small-scale three phase loop thermosphonic reactor ...The influences of temperature, pressure, catalyst content, H 2O 2 content and mol ratio of propylene to H 2O 2 on epoxidation of propylene with H 2O 2 over TS-1 in a small-scale three phase loop thermosphonic reactor were investigated. The proper reaction condition was determined as follows: mol ratio of propylene to H 2O 2 was 1.1—1.3, temperature was 30—45?℃, reaction temperature rise was below 15?℃, pressure was 0—0.1?MPa, catalyst content was 3%—6%,and H 2O 2 content was 3%—5%.The conversion of H 2O 2 is above 94%,and selectivity of propylene is up to 96%. At these conditions, the yield of PO is higher than a figure of about 80%,which is achieved using conventional reactor. This reactor can realize catalyst regeneration continuously. This viable reactor can also be applied in other oxidation processes using TS-1, i.e. hydroxylation of phenol, ammoxidation of cyclohexanone.The results will lay a foundation for the development of the reactor in propylene epoxidation process.展开更多
介绍了应用三维断裂分析软件FRANC3D(Fracture Analysis Code in 3Dimensions)进行疲劳裂纹扩展分析的相关原理,利用该程序对热壁加氢反应器堆焊层表面裂纹在疲劳载荷作用下的扩展进行了数值分析;将数值模拟结果和相关试验结果进行了对...介绍了应用三维断裂分析软件FRANC3D(Fracture Analysis Code in 3Dimensions)进行疲劳裂纹扩展分析的相关原理,利用该程序对热壁加氢反应器堆焊层表面裂纹在疲劳载荷作用下的扩展进行了数值分析;将数值模拟结果和相关试验结果进行了对比。结果表明:数值模拟和实际表面裂纹扩展路径基本相似;在加氢反应器使用寿命范围内,用FRANC3D程序预测的裂纹扩展速率比实验值保守。展开更多
文摘The influences of temperature, pressure, catalyst content, H 2O 2 content and mol ratio of propylene to H 2O 2 on epoxidation of propylene with H 2O 2 over TS-1 in a small-scale three phase loop thermosphonic reactor were investigated. The proper reaction condition was determined as follows: mol ratio of propylene to H 2O 2 was 1.1—1.3, temperature was 30—45?℃, reaction temperature rise was below 15?℃, pressure was 0—0.1?MPa, catalyst content was 3%—6%,and H 2O 2 content was 3%—5%.The conversion of H 2O 2 is above 94%,and selectivity of propylene is up to 96%. At these conditions, the yield of PO is higher than a figure of about 80%,which is achieved using conventional reactor. This reactor can realize catalyst regeneration continuously. This viable reactor can also be applied in other oxidation processes using TS-1, i.e. hydroxylation of phenol, ammoxidation of cyclohexanone.The results will lay a foundation for the development of the reactor in propylene epoxidation process.
文摘介绍了应用三维断裂分析软件FRANC3D(Fracture Analysis Code in 3Dimensions)进行疲劳裂纹扩展分析的相关原理,利用该程序对热壁加氢反应器堆焊层表面裂纹在疲劳载荷作用下的扩展进行了数值分析;将数值模拟结果和相关试验结果进行了对比。结果表明:数值模拟和实际表面裂纹扩展路径基本相似;在加氢反应器使用寿命范围内,用FRANC3D程序预测的裂纹扩展速率比实验值保守。
