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大比表面积介孔g-C_(3)N_(4)材料的制备及其产氢性能
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作者 王聪 颉启东 +1 位作者 傅雅琴 司银松 《浙江理工大学学报(自然科学版)》 2023年第6期665-673,共9页
为获得大比表面积和优异产氢性能的石墨相氮化碳(g-C_(3)N_(4)),将单氰胺和甲醛溶液溶入二氧化硅(SiO_(2))溶胶,形成单氰胺、甲醛和SiO_(2)凝胶组成的杂化前驱体,并将该杂化前驱体在通气条件下煅烧以制备介孔g-C_(3)N_(4)(命名为VCN),... 为获得大比表面积和优异产氢性能的石墨相氮化碳(g-C_(3)N_(4)),将单氰胺和甲醛溶液溶入二氧化硅(SiO_(2))溶胶,形成单氰胺、甲醛和SiO_(2)凝胶组成的杂化前驱体,并将该杂化前驱体在通气条件下煅烧以制备介孔g-C_(3)N_(4)(命名为VCN),在密闭条件下煅烧以制备介孔g-C_(3)N_(4)(命名为ACN);利用透射电镜、X射线衍射仪、傅里叶变换红外光谱等对介孔g-C_(3)N_(4)的形貌、晶体结构等进行表征,通过荧光光谱和气相色谱仪等分析介孔g-C_(3)N_(4)的产氢性能。结果表明:VCN在获得大比表面积(约312 m^(2)/g)的同时,拓宽了光吸收范围(约760 nm),提高了光致电子-空穴对分离效率。加入40 mg甲醛的VCN(VCN-40)具有最佳的产氢速率,为2826μmol/(h·g),比通气条件下未加入甲醛的g-C_(3)N_(4)(VCN-0)提高了1.8倍。研究结果为开发高产氢效率g-C_(3)N_(4)基复合催化剂提供了有益参考。 展开更多
关键词 g-C_(3)N_(4) SiO_(2)溶胶 甲醛 多孔结构 热聚合过程 产氢性能
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De-polymerization of Waste Polymers to Produce Hydrocarbon Fuel Utilizing Thermal Degradation
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作者 Moinuddin Sarker Mohammad Mamunor Rashid Mohammed Molla Ashiquz Zaman 《Journal of Chemistry and Chemical Engineering》 2011年第2期129-134,共6页
Waste plastics are one of the biggest environmental concerns the world faces today. Waste plastics exposure to the environment is very hazardous. Over time waste plastics photo-degrade and become very tiny dust partic... Waste plastics are one of the biggest environmental concerns the world faces today. Waste plastics exposure to the environment is very hazardous. Over time waste plastics photo-degrade and become very tiny dust particles. These dust particles contain very harmful compounds including benzene, sulfur, carbon and many others. According to studies, waste plastic pollutions are one of the biggest reasons for the depletion of the ozone layer and contributor of global warming. Many scientists have been trying to figure out how to utilize these waste plastics and convert them into useful energy sources. It is possible to convert waste plastics into energy because they are made from petroleum. Scientists have succeeded in developing many methods including pyrolysis, catalytic cracking, thermal degrading and others. The purpose of this experiment is to convert these environmentally harmful waste materials into useful energy source using simple and viable methods. A particular thermal degradation process was successful in extracting fuel from waste plastics at 370-420 ~C. In this paper we will discuss our performed experiment and provide detailed analysis of the produced fuel. Thorough instrumental analysis of the produced fuel showed very considerable results including high energy contents, low levels of harmful emissions and compatibility with various types of existing appliances. 展开更多
关键词 Thermal degradation HYDROCARBON waste plastics FUEL
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Fabrication and thermal decomposition of glycidyl azide polymer modified nitrocellulose double base propellants 被引量:2
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作者 Benbo Zhao Tianfu Zhang +1 位作者 Zhen Ge Yunjun Luo 《Science China Chemistry》 SCIE EI CAS CSCD 2016年第4期472-477,共6页
Glycidyl azide polymer (GAP) with the advantages of non-volatility and excellent thermal stability is a candidate as a re- placement for nitroglycerine (NG) in a double base propellant. The GAP-NC double base prop... Glycidyl azide polymer (GAP) with the advantages of non-volatility and excellent thermal stability is a candidate as a re- placement for nitroglycerine (NG) in a double base propellant. The GAP-NC double base propellants were formulated with GAP and nitrocellulose (NC) fibers. Tensile test and SEM characterization indicated that GAP-NC propellants had a homoge- neous structure. Thermogravimetric analysis of GAP-NC propellants revealed that the onset decomposition temperature reached a high level ranging from 192.9 to 194.6 ℃, which indicated that the substitution of NG with GAP contributed to the safe storage and process operations for double base propellant. The result analysis of decomposition products of GAP-NC propellants showed that the main gas decomposition products of the propellants were NO, NO〉 CO, CO2, NH3, CH4, HCN, N2 CH20 and C2H40. The thermal decomposition process of the specimens was proposed. 展开更多
关键词 glycidyl azide polymers (GAP) NITROCELLULOSE double base propellant NITROGLYCERINE thermal decomposition
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