Replacement of volatile organic compounds （VOCs） by greener or more environmentally sustainable solvents is becoming increasingly important due to the increasing health and environmental concerns as well as economic...Replacement of volatile organic compounds （VOCs） by greener or more environmentally sustainable solvents is becoming increasingly important due to the increasing health and environmental concerns as well as economic pressures associated with VOCs. Solvents that are derived from biomass, namely bio-derived solvents, are a type of green solvent that have attracted intensive investigations in recent years because of their advantages over con- ventional VOCs, such as low toxicity, biodegradability and renewability. This review aims to summarize the use of bio-derived solvents in solvent extraction applications, with special emphasis given to utilization of biodiesels and terpenes. Compared with the conventional VOCs, the overall performance of these bio-derived solvents is comparable in terms of extraction yields and selectivity for natural product extraction and no difference was found for metal extraction. To date most researchers have focused on laboratory scale thermodynamics studies. Future work is required to develop and test new bio-derived solvents and understand the kinetic performance as well as solvent extraction nilnt nlant studies.展开更多
All plants emit a wide range of volatile compounds, the so-called biogenic volatile organic compounds(BVOC). BVOC emissions have received increased scientific attention in the last two decades because theymay profound...All plants emit a wide range of volatile compounds, the so-called biogenic volatile organic compounds(BVOC). BVOC emissions have received increased scientific attention in the last two decades because theymay profoundly influence the chemical and physical properties of the atmosphere, and may modulate planttolerance to heat, pollutants, oxidative stress and abiotic stresses, and affect plant-plant and plant-insectinteractions. Urban forestry may have a high impact on atmospheric composition, air quality, environment,and quality of life in urban areas. However, few studies have been carried out where the emission of BVOCcould have important consequence for the quality of air and contribute to pollution episodes. A screening ofBVOC emission by the mixed stand constituting urban forests is therefore required if emissions are to bereliably predicted. Monitoring the emission rates simultaneously with measurements of air quality, plantphysiology and micrometeorology on selected urban forests, will allow detailed quantitative information onthe inventory of BVOC emissions by urban vegetation to be compiled. This information will make itpossible to propose an innovative management of urban vegetation in cities characterised by heavy emissionsof anthropogenic pollutants, aiming at the abatement of BVOC emissions through the introduction or selectionof non-BVOC emitting species in urban areas subjected to pollution episodes and in the new afforestationareas covering peri-urban parks, green belts and green corridors between peri-urban rural areas and theconurbations.展开更多
基金Support from the Australian Research Council (project ID:LP140100650)
文摘Replacement of volatile organic compounds （VOCs） by greener or more environmentally sustainable solvents is becoming increasingly important due to the increasing health and environmental concerns as well as economic pressures associated with VOCs. Solvents that are derived from biomass, namely bio-derived solvents, are a type of green solvent that have attracted intensive investigations in recent years because of their advantages over con- ventional VOCs, such as low toxicity, biodegradability and renewability. This review aims to summarize the use of bio-derived solvents in solvent extraction applications, with special emphasis given to utilization of biodiesels and terpenes. Compared with the conventional VOCs, the overall performance of these bio-derived solvents is comparable in terms of extraction yields and selectivity for natural product extraction and no difference was found for metal extraction. To date most researchers have focused on laboratory scale thermodynamics studies. Future work is required to develop and test new bio-derived solvents and understand the kinetic performance as well as solvent extraction nilnt nlant studies.
文摘All plants emit a wide range of volatile compounds, the so-called biogenic volatile organic compounds(BVOC). BVOC emissions have received increased scientific attention in the last two decades because theymay profoundly influence the chemical and physical properties of the atmosphere, and may modulate planttolerance to heat, pollutants, oxidative stress and abiotic stresses, and affect plant-plant and plant-insectinteractions. Urban forestry may have a high impact on atmospheric composition, air quality, environment,and quality of life in urban areas. However, few studies have been carried out where the emission of BVOCcould have important consequence for the quality of air and contribute to pollution episodes. A screening ofBVOC emission by the mixed stand constituting urban forests is therefore required if emissions are to bereliably predicted. Monitoring the emission rates simultaneously with measurements of air quality, plantphysiology and micrometeorology on selected urban forests, will allow detailed quantitative information onthe inventory of BVOC emissions by urban vegetation to be compiled. This information will make itpossible to propose an innovative management of urban vegetation in cities characterised by heavy emissionsof anthropogenic pollutants, aiming at the abatement of BVOC emissions through the introduction or selectionof non-BVOC emitting species in urban areas subjected to pollution episodes and in the new afforestationareas covering peri-urban parks, green belts and green corridors between peri-urban rural areas and theconurbations.
