本文以甘蔗渣作为生物质碳源制备Na2MnPO4F/C正极材料。通过球磨法及原位热解法制备Na2MnPO4F/C正极材料,利用拉曼光谱对正极材料制备条件进行表征分析,得出Na2MnPO4F/C最佳制备条件为碳源用量15%、煅烧温度600℃。利用XRD、SEM、EDS、...本文以甘蔗渣作为生物质碳源制备Na2MnPO4F/C正极材料。通过球磨法及原位热解法制备Na2MnPO4F/C正极材料,利用拉曼光谱对正极材料制备条件进行表征分析,得出Na2MnPO4F/C最佳制备条件为碳源用量15%、煅烧温度600℃。利用XRD、SEM、EDS、电化学测量技术等手段对材料进行表征分析,结果表明,材料结晶性良好,碳材料很好地包覆在Na2MnPO4F聚氟阴离子材料表面,并且不影响材料结构。组装成纽扣电池,进行电化学性能测试。结果表明Na2MnPO4F/C材料电化学性能优于Na2MnPO4F材料,在0.1C下,Na2MnPO4F/C材料首圈放电比容量为8.71 m Ah/g,而Na2MnPO4F材料首圈放电比容量为1.94 m Ah/g,通过原位热解法进行碳包覆能有效的提高材料的电子电导性,增加容量。展开更多
The planted forest area and carbon sequestration have increased significantly in China,because of large-scale reforestation and afforestation in the past decades.In this study,we developed an age-based volume-to-bioma...The planted forest area and carbon sequestration have increased significantly in China,because of large-scale reforestation and afforestation in the past decades.In this study,we developed an age-based volume-to-biomass method to estimate the carbon storage by planted forests in China in the period of 1973-2003 based on the data from 1209 field plots and national forest inventories.The results show that the total carbon storage of planted forests was 0.7743 Pg C in 1999-2003,increased by 3.08 times since the early 1970s.The carbon density of planted forests varied from 10.6594 Mg/ha to 23.9760 Mg/ha and increased by 13.3166 Mg/ha from 1973-1976 to 1999-2003.Since the early 1970s,the planted forests in China have been always a carbon sink,and the annual rate of carbon sequestration was 0.0217 Pg C/yr.The carbon storage and densities of planted forests varied greatly in space and time.The carbon storage of Middle South China was in the lead in all regions,which accounted for 23%-36% of national carbon storage.While higher C densities (from 17.79 Mg/ha to 26.05 Mg/ha) were usually found in Northeast China.The planted forests in China potentially have a high carbon sequestration since a large part of them are becoming mature and afforestation continues to grow.展开更多
A simple, easily-operated and economical carbonization technology with Eupatorium adenophorum was introduced in terms of instrument selection, carboniza- tion of Eupatorium adenophorum and preparation of carbon rod, a...A simple, easily-operated and economical carbonization technology with Eupatorium adenophorum was introduced in terms of instrument selection, carboniza- tion of Eupatorium adenophorum and preparation of carbon rod, and evaluation was made on economic profits from carbonization of Eupatorium adenophorum.展开更多
文摘本文以甘蔗渣作为生物质碳源制备Na2MnPO4F/C正极材料。通过球磨法及原位热解法制备Na2MnPO4F/C正极材料,利用拉曼光谱对正极材料制备条件进行表征分析,得出Na2MnPO4F/C最佳制备条件为碳源用量15%、煅烧温度600℃。利用XRD、SEM、EDS、电化学测量技术等手段对材料进行表征分析,结果表明,材料结晶性良好,碳材料很好地包覆在Na2MnPO4F聚氟阴离子材料表面,并且不影响材料结构。组装成纽扣电池,进行电化学性能测试。结果表明Na2MnPO4F/C材料电化学性能优于Na2MnPO4F材料,在0.1C下,Na2MnPO4F/C材料首圈放电比容量为8.71 m Ah/g,而Na2MnPO4F材料首圈放电比容量为1.94 m Ah/g,通过原位热解法进行碳包覆能有效的提高材料的电子电导性,增加容量。
基金Under the auspices of National Natural Science Foundation of China (No.40601079)National Key Project of Scientific and Technical Supporting Programs (No.2006BAC08B03,2008BAC34B06)
文摘The planted forest area and carbon sequestration have increased significantly in China,because of large-scale reforestation and afforestation in the past decades.In this study,we developed an age-based volume-to-biomass method to estimate the carbon storage by planted forests in China in the period of 1973-2003 based on the data from 1209 field plots and national forest inventories.The results show that the total carbon storage of planted forests was 0.7743 Pg C in 1999-2003,increased by 3.08 times since the early 1970s.The carbon density of planted forests varied from 10.6594 Mg/ha to 23.9760 Mg/ha and increased by 13.3166 Mg/ha from 1973-1976 to 1999-2003.Since the early 1970s,the planted forests in China have been always a carbon sink,and the annual rate of carbon sequestration was 0.0217 Pg C/yr.The carbon storage and densities of planted forests varied greatly in space and time.The carbon storage of Middle South China was in the lead in all regions,which accounted for 23%-36% of national carbon storage.While higher C densities (from 17.79 Mg/ha to 26.05 Mg/ha) were usually found in Northeast China.The planted forests in China potentially have a high carbon sequestration since a large part of them are becoming mature and afforestation continues to grow.
基金Supported by Qiannan Forestry S&T Promotion Project~~
文摘A simple, easily-operated and economical carbonization technology with Eupatorium adenophorum was introduced in terms of instrument selection, carboniza- tion of Eupatorium adenophorum and preparation of carbon rod, and evaluation was made on economic profits from carbonization of Eupatorium adenophorum.