The synthesis of the title compound was carried out by the zinc dust reduction of 4-(4-methylphenoxy)benzaldoxime, which was obtained from commercially available p-bromobezaldehyde by reaction with potassium p-methylp...The synthesis of the title compound was carried out by the zinc dust reduction of 4-(4-methylphenoxy)benzaldoxime, which was obtained from commercially available p-bromobezaldehyde by reaction with potassium p-methylphenoxide. The method has the advantages of cheapness and high yield, without necessity of using toxic cyanide and handling of toxic organic cyanide.展开更多
Solid complexes of rare earth nitrates with a new amide type podand ligand, 2,3-bis{[(2′-benzylaminoformyl)phenoxyl]methyl}quinoxaline (L), were prepared. These complexes were characterized by elemental analysis, con...Solid complexes of rare earth nitrates with a new amide type podand ligand, 2,3-bis{[(2′-benzylaminoformyl)phenoxyl]methyl}quinoxaline (L), were prepared. These complexes were characterized by elemental analysis, conductivity measurements and IR spectroscopy. Spectrographic analyses suggest that the complexes show a similar coordination mode. At the same time, the luminescence properties of the Eu(III) and Tb(III) complexes were also studied.展开更多
文摘The synthesis of the title compound was carried out by the zinc dust reduction of 4-(4-methylphenoxy)benzaldoxime, which was obtained from commercially available p-bromobezaldehyde by reaction with potassium p-methylphenoxide. The method has the advantages of cheapness and high yield, without necessity of using toxic cyanide and handling of toxic organic cyanide.
文摘Solid complexes of rare earth nitrates with a new amide type podand ligand, 2,3-bis{[(2′-benzylaminoformyl)phenoxyl]methyl}quinoxaline (L), were prepared. These complexes were characterized by elemental analysis, conductivity measurements and IR spectroscopy. Spectrographic analyses suggest that the complexes show a similar coordination mode. At the same time, the luminescence properties of the Eu(III) and Tb(III) complexes were also studied.
