A facile method was proposed to prepare stretchable silver-based composite coatings with excellent conductivity and stability for flexible electronics.Silver coating was firstly deposited on thermoplastic polyurethane...A facile method was proposed to prepare stretchable silver-based composite coatings with excellent conductivity and stability for flexible electronics.Silver coating was firstly deposited on thermoplastic polyurethane(TPU)elastomer rubber surface via two-component spraying technique,then the superhydrophobic surface was obtained by one-step electrodeposition of cerium compounds(CeM)and graphene nanosheets(GNS)to produce Ag/CeM/GNS composite coatings.The obtained Ag/CeM/GNS composite coatings maintained high conductivity after experiencing bending cycles and stretching cycles.Furthermore,the as-prepared Ag/CeM/GNS composite coatings showed excellent self-cleaning and anti-fouling properties,and the corrosion resistance has improved significantly compared to the original Ag coating.In addition,the Ag/CeM/GNS composite coatings could drive the circuit normally in the states of tensile,bending and twisting deformation,showing excellent mechanical stability and applicability.As a result,it is believed that the prepared Ag/CeM/GNS composite coatings with excellent conductivity and stability have promising applications for flexible electronics in harsh conditions.展开更多
By taking advantage of silylanization, Al2O3 support was modified by organosilane and supported Pd-Cu-Clx/Al2O3 catalysts were prepared. The effects of hydrophobicity on catalyst stability during CO oxidation were inv...By taking advantage of silylanization, Al2O3 support was modified by organosilane and supported Pd-Cu-Clx/Al2O3 catalysts were prepared. The effects of hydrophobicity on catalyst stability during CO oxidation were investigated. The physicochemical properties and redox potential of the catalyst were characterized by N2 adsorption-desorption, XRD, H2-TPR, and XPS. In order to understand the relationship between the oxidation stability of CO and the presence of water, the CO oxidation mechanism was studied by in situ DRIFT. Support pretreatment markedly promoted catalyst stability during CO oxidation; CO conversion was 78% after 150 h at saturated humidity and freezing point. Modification led to an obvious decrease in chloride ion concentration and enhancement in hydrophobicity. The role of water in CO oxidation was complicated. The presence of water favored CO oxidation over active Pd~＋ species and Pd0 reoxidation by Cu^（2＋） species. Meanwhile, water also inhibited the formation of the active Pd~＋ species and helped to produce carbonate species. Compared with the form of the carbonate species, the inhibition of water to produce active Pd~＋ species played the main detrimental role in catalyst stability.展开更多
Water stability of soil is crucial to the durability of earthen monuments,especially those located in the humid weather condition.This paper discusses the selection reason of materials(tung oil and quicklime) for eart...Water stability of soil is crucial to the durability of earthen monuments,especially those located in the humid weather condition.This paper discusses the selection reason of materials(tung oil and quicklime) for earthen monument treatment,and then validates the applicability of these materials with tests of soil-water characteristic curve(SWCC),aggregate stability test(AST) and scanning electron microscope(SEM).The soil tested was sampled from Da Bao'en temple in Nanjing,Jiangsu province,China.The test results indicate that the carbonation reaction of quicklime offers a favorable environment for the formation of tung oil film.Meanwhile,the regulatory function of tung oil restricts the crystallinity of calcium carbonate(CaCO3) and forms fine crystals.Soil treated with both of tung oil and quicklime has good water repellency and aggregate stability without obvious changing in aesthetic appearance.Hydrophobicity and carbonation treatment can be applied prospectively in the conservation of earthen monument located in humid weather condition.展开更多
基金support from the National Natural Science Foundation of China(No.52105186)the Guangdong Basic and Applied Basic Research Foundation,China(Nos.2019A1515011282,2022A1515011547,2021B1515120014)the Fangchenggang Scientific Research and Technology Development Project,China(No.AB21014008).
文摘A facile method was proposed to prepare stretchable silver-based composite coatings with excellent conductivity and stability for flexible electronics.Silver coating was firstly deposited on thermoplastic polyurethane(TPU)elastomer rubber surface via two-component spraying technique,then the superhydrophobic surface was obtained by one-step electrodeposition of cerium compounds(CeM)and graphene nanosheets(GNS)to produce Ag/CeM/GNS composite coatings.The obtained Ag/CeM/GNS composite coatings maintained high conductivity after experiencing bending cycles and stretching cycles.Furthermore,the as-prepared Ag/CeM/GNS composite coatings showed excellent self-cleaning and anti-fouling properties,and the corrosion resistance has improved significantly compared to the original Ag coating.In addition,the Ag/CeM/GNS composite coatings could drive the circuit normally in the states of tensile,bending and twisting deformation,showing excellent mechanical stability and applicability.As a result,it is believed that the prepared Ag/CeM/GNS composite coatings with excellent conductivity and stability have promising applications for flexible electronics in harsh conditions.
基金supported by the National Key Research and Development Program of China(2016YFC0204300)National Natural Science Foundation of China(21207037,21333003,21571061)+1 种基金the "Shu Guang" Project of the Shanghai Municipal Education Commission(12SG29)the Commission of Science and Technology of Shanghai Municipality(15DZ1205305)~~
文摘By taking advantage of silylanization, Al2O3 support was modified by organosilane and supported Pd-Cu-Clx/Al2O3 catalysts were prepared. The effects of hydrophobicity on catalyst stability during CO oxidation were investigated. The physicochemical properties and redox potential of the catalyst were characterized by N2 adsorption-desorption, XRD, H2-TPR, and XPS. In order to understand the relationship between the oxidation stability of CO and the presence of water, the CO oxidation mechanism was studied by in situ DRIFT. Support pretreatment markedly promoted catalyst stability during CO oxidation; CO conversion was 78% after 150 h at saturated humidity and freezing point. Modification led to an obvious decrease in chloride ion concentration and enhancement in hydrophobicity. The role of water in CO oxidation was complicated. The presence of water favored CO oxidation over active Pd~＋ species and Pd0 reoxidation by Cu^（2＋） species. Meanwhile, water also inhibited the formation of the active Pd~＋ species and helped to produce carbonate species. Compared with the form of the carbonate species, the inhibition of water to produce active Pd~＋ species played the main detrimental role in catalyst stability.
基金supported by the National Key Technology R & D Program in the 11th Five Year Plan of China (Grant No. 2010BAK67B16)the Outstanding Doctorial Research Scholarship of Lanzhou University (Grant No. )
文摘Water stability of soil is crucial to the durability of earthen monuments,especially those located in the humid weather condition.This paper discusses the selection reason of materials(tung oil and quicklime) for earthen monument treatment,and then validates the applicability of these materials with tests of soil-water characteristic curve(SWCC),aggregate stability test(AST) and scanning electron microscope(SEM).The soil tested was sampled from Da Bao'en temple in Nanjing,Jiangsu province,China.The test results indicate that the carbonation reaction of quicklime offers a favorable environment for the formation of tung oil film.Meanwhile,the regulatory function of tung oil restricts the crystallinity of calcium carbonate(CaCO3) and forms fine crystals.Soil treated with both of tung oil and quicklime has good water repellency and aggregate stability without obvious changing in aesthetic appearance.Hydrophobicity and carbonation treatment can be applied prospectively in the conservation of earthen monument located in humid weather condition.
