针对石化生产过程的高危性,开发了石化过程在线故障监测系统。通过OPC(OLE for process control)接口从生产现场采集实时数据,采用BP神经网络(back-propagation artificial neural network,BPNN)的模式识别方法,对生产过程进行实时故障...针对石化生产过程的高危性,开发了石化过程在线故障监测系统。通过OPC(OLE for process control)接口从生产现场采集实时数据,采用BP神经网络(back-propagation artificial neural network,BPNN)的模式识别方法,对生产过程进行实时故障监测,及时发现故障工况并提示操作人员采取相应措施,以减小系统运行的风险。BP神经网络的训练数据来自历史数据库,用户根据已发生过的故障工况确定训练数据的时间范围。BP网络模型的各项参数根据多次试验得到。对某工段的10个故障,其故障诊断准确率达到90%以上,具有较高的实时性和准确性。展开更多
In order to reveal the nonlinear dynamics characteristics of unsteady self-heating process of sulfide ores, nine different kinds of sulfide ore samples from a pyrite mine in China were taken as experimental materials ...In order to reveal the nonlinear dynamics characteristics of unsteady self-heating process of sulfide ores, nine different kinds of sulfide ore samples from a pyrite mine in China were taken as experimental materials and their self-heating characteristics were measured in laboratory. Furthermore, the measured temperature was studied by integrating wavelet transform, nonlinear characteristic parameters extraction and fuzzy comprehensive evaluation. The results indicate that only the ore samples 1, 2, 6 and 9 have obvious self-heating phenomenon, and their self-heating initiative temperatures are 220 ℃, 239 ℃, 220 ℃ and 220 ℃, respectively, which means that they are difficult to produce self-heating under normal mining conditions. The correlation dimension of self-heating process is fraction and the maximum Lyapunov exponent is positive, which means that it is feasible to study the self-heating process based on chaotic dynamics theory. The nonlinearities of self-heating process of these four samples （ore samples 1, 2, 6 and 9） are 0.8227, 0.7521, 0.9401 and 0.8827 respectively and the order of the samples according to these results is： sample 6, sample 9, sample 1, sample 2, which is consistent with the measured results of self-heating characteristics. Therefore, the nonlinearity method can be used to evaluate the self-heating tendency of sulfide ores, and it is an effective verification of the reliability of measured results.展开更多
A first principles-based dynamic model for a continuous catalyst regeneration (CCR) platforming process, the UOP commercial naphtha catalytic reforming process, is developed in this paper. The lumping details of the n...A first principles-based dynamic model for a continuous catalyst regeneration (CCR) platforming process, the UOP commercial naphtha catalytic reforming process, is developed in this paper. The lumping details of the naphtha feed and reaction scheme of the reaction model are given. The process model is composed of the reforming reaction model with catalyst deactivation, the furnace model and the separator model, which is capable of capturing the major dynamics that occurs in this process system. Dynamic simulations are performed based on Gear numerical algorithm and method of lines (MOL), a numerical technique dealing with partial differential equations (PDEs). The results of simulation are also presented. Dynamic responses caused by disturbances in the process system can be correctly predicted through simulations.展开更多
Effects of metal oxide in ZSM-5 zeolite on its catalytic performance in fluid catalytic cracking reaction were studied via characterization by XRD and FT-IR spectroscopy using pyridine and collidine as molecular probe...Effects of metal oxide in ZSM-5 zeolite on its catalytic performance in fluid catalytic cracking reaction were studied via characterization by XRD and FT-IR spectroscopy using pyridine and collidine as molecular probes,and the modified ZSM-5 zeolite was evaluated in a micro reactor using standard light diesel fraction as the feedstock.Test results indicate that the metal species introduced into the ZSM-5 zeolite had led to the formation of Lewis acid centers.When the modified ZSM-5 zeolite with the metal species on its surface was used as the catalyst in FCC reaction,both the propylene yield and the propylene concentration in the liquefied petroleum gas increased,but in the meantime,more hydrogen and coke were formed at high conversion rate under the joint action of nonselective cracking of Lewis acid centers and dehydrogenation at metal centers on its outside surface.展开更多
High temperature affects rocks in a way that changes the physical and mechanical properties of them. The temperature field in rock overlying a high temperature zone has been estimated using experimental research on th...High temperature affects rocks in a way that changes the physical and mechanical properties of them. The temperature field in rock overlying a high temperature zone has been estimated using experimental research on thermal conductivity of the overlying strata. Numerical analysis software was used to esti- mate rock thermal conductivity at different temperatures. These estimates were then used with COMSOL Multiphysics to perform a numerical analysis with the heat conduction model. The results show that rock thermal conductivity decreases as the temperature increases and that various lithologies show similar behavior. The thermal conductivity of each rock type differs from the others at a given temperature. Exact values for the temperature distribution in the overlying strata during the process of underground coal gasification are obtained from the numerical simulation. The temperature in the rock changes with the height and direction from the gasifier. Temperature gradients vary for different types of rock. This result provides an important reference for further study of the strength of overlying strata subject to the process of underground coal gasification.展开更多
Although rare earth elements(REEs)in magmatic zircons have been widely used to identify the type and compositional evolution of host rocks,REE distribution patterns during the chemical alteration of zircons need clari...Although rare earth elements(REEs)in magmatic zircons have been widely used to identify the type and compositional evolution of host rocks,REE distribution patterns during the chemical alteration of zircons need clarification.We investigated REE characteristics in zircons with different degrees of chemical weathering through systematic observation of a granodiorite-weathering profile in southeast China.Despite the relatively stable provenance of the studied profile(zircon U–Pb ages are95.2±4.8 Ma),the zircon REEs exhibited systematic differences in abundance and fractionation patterns from the bedrock to upper layers,e.g.∑PREE,(LREE/HREE)_(CN),and Ce/Ce*.This evidence suggests chemical alteration of zircons during intensive chemical weathering and an expected influence on REE variability in the weathered products due to the presence of REE-bearing minerals.展开更多
In petrochemical plant, the in-operation repairing is usually a repairing strategy with pressured inoperation repairing for avoiding huge economic losses caused by unplanned shutdown when some slight local leakage hap...In petrochemical plant, the in-operation repairing is usually a repairing strategy with pressured inoperation repairing for avoiding huge economic losses caused by unplanned shutdown when some slight local leakage happens in pipes. This paper studies the effects of repairing strategies on the failure probability of the pipe systems in process industries based on the time-average fault tree approach, especially the in-operation repairing strategies including pressured in-operation repairing activities. The fault tree model can predict the effect of different repairing plans on the pipe failure probability, which is significant to the optimization of the repairing plans. At first pipes are distinguished into four states in this model, i.e., successive state, flaw state, leakage state and failure state. Then the fault tree approach, which is usually applied in the studies of dynamic equipment, is adopted to model the pipe failure. Moreover, the effect of pressured in-operation repairing is also considered in the model. In addition, this paper proposes a series of time-average parameters of the fault tree model, all of which are used to calculate node parameters of the fault tree model. At last, a practical case is calculated based on the fault tree model in a repairing activity of pipe thinning.展开更多
To investigate the relationship between nonlinear parameters and spontaneous combustion tendency of sulfide ores, nine different sulfide ore samples were taken from a pyrite mine in China, and induced spontaneous comb...To investigate the relationship between nonlinear parameters and spontaneous combustion tendency of sulfide ores, nine different sulfide ore samples were taken from a pyrite mine in China, and induced spontaneous combustion experiment was carried out in the laboratory. Different stages of the induced spontaneous combustion process were studied by integrating wavelet technology and nonlinear dynamics theory. The results show that ignition points of all the ore samples are above 330 ℃, indicating that sulfide ores of the pyrite mine are difficult to combust spontaneously under normal mining conditions. Spontaneous combustion process includes three stages： incubation stage, development stage and approaching stage. The average temperature rising rate of the three stages are 1.0 ~C/min, 2.0 ~C/min and 4.2 ~C/min, respectively. During the spontaneous combustion process, mean values of approximate entropy and correlation dimension increase at first, and then decrease in the following stage. The mean value of the maximum Lyapunov exponent increases with the passage of reaction time. In a whole, correlation among the three nonlinear parameters firstly weakens, then enhances, and the best correlation period is at approaching stage. As ignition point increases, the maximum Lyapunov exponent of approaching stage decreases. Therefore, combustible tendency of sulfide ores could be qualitatively evaluated based on the maximum Lyapunov exponent of this stage.展开更多
Although the FCC process has been used for more than halfa century, new and important developments continue to be made in several areas. Some of these new developments are a direct response to environmental regulation...Although the FCC process has been used for more than halfa century, new and important developments continue to be made in several areas. Some of these new developments are a direct response to environmental regulation. Sulfur oxides （SOx-SO2＋SO3） emitted from fluid catalytic cracking units （FCCU） are one of the most hazardous atmospheric pollutants, which may cause serious environmental problems such as the formation of acid rain and the destruction of the ozone layer. Thus, great attention has been focused on the SOx removal from FCC in last few years. The present papers will focus on the spinel material studies include three samples they were prepared by acidic method, solid solution MgAl2O4, solid solution with cerium10%Ce/MgAl2O4, iron mixed spinel with cerium 10%Ce/MgAl2-xFeO4.MgO and two samples solid solution with cerium introduce by vanadium as second co-catalyst prepared by basic method, 1% V/10%Ce/MgAl2O4.MgO were tested in TGA for oxidation half cycle to study some parameters effect on performance of SOx additives in TGA under condition similar to those of FCC units. Thermogravimetry analysis experiments have been used to demonstrate the pick-up and release of sulfur oxides in the development of additives for SOx control in the FCCU.展开更多
From the view of energy state of material, this paper introduces a concept of weathering potential in carrying out quantitative calculation of the relevant products at different stages of rock-weathering and primary s...From the view of energy state of material, this paper introduces a concept of weathering potential in carrying out quantitative calculation of the relevant products at different stages of rock-weathering and primary soil-forming processes, elaborates respectively on weathering degree in the bio-weathering layer of rocks and during the formation of soil material and clay, and evaluats the further tendency of weathering in the above-mentioned stages. The authors have discovered that the scales of weathering potential of the materials increase successively in the three stages, which indicates that the products in the above-mentioned three stages must have undergone stronger and stronger weathering in the primitive forming process of soil in Fildes Peninsula, Antarctic. But, because of relatively weak chemical weathering, it is reasonable that there are much more skeleton grains and little clay in primary soils in this region. Meanwhile, the authors have also verified that the weathering potential of crude rock determines to some extent decrease in the products' weathering potential in the different stages in primary soil-forming, thereby plays an important role in the genesis and development of the primary soil in the studied area.展开更多
Due to the complexity of earthwork allocation system for the construction of high concrete face rockfill dam,traditional allocation and planning are not able to function properly in the construction process with stron...Due to the complexity of earthwork allocation system for the construction of high concrete face rockfill dam,traditional allocation and planning are not able to function properly in the construction process with strong randomness.In this paper,the working mechanism of earthwork dynamic allocation system is analyzed comprehensively and a solution to fuzzy earthwork dynamic allocation is proposed on the basis of uncertain factors in the earthwork allocation of a hydropower project.Under the premise of actual situation and the experience of the construction site,an all-coefficient-fuzzy linear programming mathematical model with fuzzy parameters and constraints for earthwork allocation is established according to the structure unit weighted ranking criteria.In this way,the deficiency of certain allocation model can be overcome.The application results indicate that the proposed method is more rational compared with traditional earthwork allocation.展开更多
文摘针对石化生产过程的高危性,开发了石化过程在线故障监测系统。通过OPC(OLE for process control)接口从生产现场采集实时数据,采用BP神经网络(back-propagation artificial neural network,BPNN)的模式识别方法,对生产过程进行实时故障监测,及时发现故障工况并提示操作人员采取相应措施,以减小系统运行的风险。BP神经网络的训练数据来自历史数据库,用户根据已发生过的故障工况确定训练数据的时间范围。BP网络模型的各项参数根据多次试验得到。对某工段的10个故障,其故障诊断准确率达到90%以上,具有较高的实时性和准确性。
基金Project(51304238)supported by the National Natural Science Foundation of ChinaProject(JSK200206)supported by the Foundation of Key Laboratory of Mine Thermo-motive Disaster and Prevention,Ministry of Education,China
文摘In order to reveal the nonlinear dynamics characteristics of unsteady self-heating process of sulfide ores, nine different kinds of sulfide ore samples from a pyrite mine in China were taken as experimental materials and their self-heating characteristics were measured in laboratory. Furthermore, the measured temperature was studied by integrating wavelet transform, nonlinear characteristic parameters extraction and fuzzy comprehensive evaluation. The results indicate that only the ore samples 1, 2, 6 and 9 have obvious self-heating phenomenon, and their self-heating initiative temperatures are 220 ℃, 239 ℃, 220 ℃ and 220 ℃, respectively, which means that they are difficult to produce self-heating under normal mining conditions. The correlation dimension of self-heating process is fraction and the maximum Lyapunov exponent is positive, which means that it is feasible to study the self-heating process based on chaotic dynamics theory. The nonlinearities of self-heating process of these four samples （ore samples 1, 2, 6 and 9） are 0.8227, 0.7521, 0.9401 and 0.8827 respectively and the order of the samples according to these results is： sample 6, sample 9, sample 1, sample 2, which is consistent with the measured results of self-heating characteristics. Therefore, the nonlinearity method can be used to evaluate the self-heating tendency of sulfide ores, and it is an effective verification of the reliability of measured results.
文摘A first principles-based dynamic model for a continuous catalyst regeneration (CCR) platforming process, the UOP commercial naphtha catalytic reforming process, is developed in this paper. The lumping details of the naphtha feed and reaction scheme of the reaction model are given. The process model is composed of the reforming reaction model with catalyst deactivation, the furnace model and the separator model, which is capable of capturing the major dynamics that occurs in this process system. Dynamic simulations are performed based on Gear numerical algorithm and method of lines (MOL), a numerical technique dealing with partial differential equations (PDEs). The results of simulation are also presented. Dynamic responses caused by disturbances in the process system can be correctly predicted through simulations.
文摘Effects of metal oxide in ZSM-5 zeolite on its catalytic performance in fluid catalytic cracking reaction were studied via characterization by XRD and FT-IR spectroscopy using pyridine and collidine as molecular probes,and the modified ZSM-5 zeolite was evaluated in a micro reactor using standard light diesel fraction as the feedstock.Test results indicate that the metal species introduced into the ZSM-5 zeolite had led to the formation of Lewis acid centers.When the modified ZSM-5 zeolite with the metal species on its surface was used as the catalyst in FCC reaction,both the propylene yield and the propylene concentration in the liquefied petroleum gas increased,but in the meantime,more hydrogen and coke were formed at high conversion rate under the joint action of nonselective cracking of Lewis acid centers and dehydrogenation at metal centers on its outside surface.
基金support from the State Key Basic Research Program of China (No. 2010CB226805)the National Natural Science Foundation of China (No. 50874103)+3 种基金the Natural Science Foundation of Jiangsu Province (No. BK2008135)the StateKey Laboratory Program (No. SKLGDUEK0905)the Natural Science Fundsof the Education Department of Anhui Province (No.KJ2009B096Z)the Brain Gain Funds Program of Anhui University of Scienceand Technology (No. 2008yb011)
文摘High temperature affects rocks in a way that changes the physical and mechanical properties of them. The temperature field in rock overlying a high temperature zone has been estimated using experimental research on thermal conductivity of the overlying strata. Numerical analysis software was used to esti- mate rock thermal conductivity at different temperatures. These estimates were then used with COMSOL Multiphysics to perform a numerical analysis with the heat conduction model. The results show that rock thermal conductivity decreases as the temperature increases and that various lithologies show similar behavior. The thermal conductivity of each rock type differs from the others at a given temperature. Exact values for the temperature distribution in the overlying strata during the process of underground coal gasification are obtained from the numerical simulation. The temperature in the rock changes with the height and direction from the gasifier. Temperature gradients vary for different types of rock. This result provides an important reference for further study of the strength of overlying strata subject to the process of underground coal gasification.
基金supported by National Natural Science Foundation of China(No.41506058)Open Financial Grant from Qingdao National Laboratory for Marine Science and Technology(No.QNLM2016ORP0211)State Key Laboratory of Marine Geology,Tongji University(No.MG20170402)
文摘Although rare earth elements(REEs)in magmatic zircons have been widely used to identify the type and compositional evolution of host rocks,REE distribution patterns during the chemical alteration of zircons need clarification.We investigated REE characteristics in zircons with different degrees of chemical weathering through systematic observation of a granodiorite-weathering profile in southeast China.Despite the relatively stable provenance of the studied profile(zircon U–Pb ages are95.2±4.8 Ma),the zircon REEs exhibited systematic differences in abundance and fractionation patterns from the bedrock to upper layers,e.g.∑PREE,(LREE/HREE)_(CN),and Ce/Ce*.This evidence suggests chemical alteration of zircons during intensive chemical weathering and an expected influence on REE variability in the weathered products due to the presence of REE-bearing minerals.
基金Supported by National Science and Technology Pillar Program in the Twelfth Five-Year Plan (No. 2011BAK06B02)National Basic Research Program of China ("973" Program, No. 2012CB026000)
文摘In petrochemical plant, the in-operation repairing is usually a repairing strategy with pressured inoperation repairing for avoiding huge economic losses caused by unplanned shutdown when some slight local leakage happens in pipes. This paper studies the effects of repairing strategies on the failure probability of the pipe systems in process industries based on the time-average fault tree approach, especially the in-operation repairing strategies including pressured in-operation repairing activities. The fault tree model can predict the effect of different repairing plans on the pipe failure probability, which is significant to the optimization of the repairing plans. At first pipes are distinguished into four states in this model, i.e., successive state, flaw state, leakage state and failure state. Then the fault tree approach, which is usually applied in the studies of dynamic equipment, is adopted to model the pipe failure. Moreover, the effect of pressured in-operation repairing is also considered in the model. In addition, this paper proposes a series of time-average parameters of the fault tree model, all of which are used to calculate node parameters of the fault tree model. At last, a practical case is calculated based on the fault tree model in a repairing activity of pipe thinning.
基金Projects(51304238,51534008)supported by the National Natural Science Foundation of ChinaProject(2015CX005)supported by Innovation Driven Plan of Central South University,China
文摘To investigate the relationship between nonlinear parameters and spontaneous combustion tendency of sulfide ores, nine different sulfide ore samples were taken from a pyrite mine in China, and induced spontaneous combustion experiment was carried out in the laboratory. Different stages of the induced spontaneous combustion process were studied by integrating wavelet technology and nonlinear dynamics theory. The results show that ignition points of all the ore samples are above 330 ℃, indicating that sulfide ores of the pyrite mine are difficult to combust spontaneously under normal mining conditions. Spontaneous combustion process includes three stages： incubation stage, development stage and approaching stage. The average temperature rising rate of the three stages are 1.0 ~C/min, 2.0 ~C/min and 4.2 ~C/min, respectively. During the spontaneous combustion process, mean values of approximate entropy and correlation dimension increase at first, and then decrease in the following stage. The mean value of the maximum Lyapunov exponent increases with the passage of reaction time. In a whole, correlation among the three nonlinear parameters firstly weakens, then enhances, and the best correlation period is at approaching stage. As ignition point increases, the maximum Lyapunov exponent of approaching stage decreases. Therefore, combustible tendency of sulfide ores could be qualitatively evaluated based on the maximum Lyapunov exponent of this stage.
文摘Although the FCC process has been used for more than halfa century, new and important developments continue to be made in several areas. Some of these new developments are a direct response to environmental regulation. Sulfur oxides （SOx-SO2＋SO3） emitted from fluid catalytic cracking units （FCCU） are one of the most hazardous atmospheric pollutants, which may cause serious environmental problems such as the formation of acid rain and the destruction of the ozone layer. Thus, great attention has been focused on the SOx removal from FCC in last few years. The present papers will focus on the spinel material studies include three samples they were prepared by acidic method, solid solution MgAl2O4, solid solution with cerium10%Ce/MgAl2O4, iron mixed spinel with cerium 10%Ce/MgAl2-xFeO4.MgO and two samples solid solution with cerium introduce by vanadium as second co-catalyst prepared by basic method, 1% V/10%Ce/MgAl2O4.MgO were tested in TGA for oxidation half cycle to study some parameters effect on performance of SOx additives in TGA under condition similar to those of FCC units. Thermogravimetry analysis experiments have been used to demonstrate the pick-up and release of sulfur oxides in the development of additives for SOx control in the FCCU.
文摘From the view of energy state of material, this paper introduces a concept of weathering potential in carrying out quantitative calculation of the relevant products at different stages of rock-weathering and primary soil-forming processes, elaborates respectively on weathering degree in the bio-weathering layer of rocks and during the formation of soil material and clay, and evaluats the further tendency of weathering in the above-mentioned stages. The authors have discovered that the scales of weathering potential of the materials increase successively in the three stages, which indicates that the products in the above-mentioned three stages must have undergone stronger and stronger weathering in the primitive forming process of soil in Fildes Peninsula, Antarctic. But, because of relatively weak chemical weathering, it is reasonable that there are much more skeleton grains and little clay in primary soils in this region. Meanwhile, the authors have also verified that the weathering potential of crude rock determines to some extent decrease in the products' weathering potential in the different stages in primary soil-forming, thereby plays an important role in the genesis and development of the primary soil in the studied area.
基金Supported by the Science Fund for Creative Research Groups of National Natural Science Foundation of China(No.51021004)Tianjin Research Program of Application Foundation and Advanced Technology(No.12JCZDJC29200)National Key Technology R and D Program in the 12th Five-Year Plan of China(No.2011BAB10B06)
文摘Due to the complexity of earthwork allocation system for the construction of high concrete face rockfill dam,traditional allocation and planning are not able to function properly in the construction process with strong randomness.In this paper,the working mechanism of earthwork dynamic allocation system is analyzed comprehensively and a solution to fuzzy earthwork dynamic allocation is proposed on the basis of uncertain factors in the earthwork allocation of a hydropower project.Under the premise of actual situation and the experience of the construction site,an all-coefficient-fuzzy linear programming mathematical model with fuzzy parameters and constraints for earthwork allocation is established according to the structure unit weighted ranking criteria.In this way,the deficiency of certain allocation model can be overcome.The application results indicate that the proposed method is more rational compared with traditional earthwork allocation.
