The effects of basicity and temperature on the reduction process of Hongge high-chromium vanadium-titanium magnetite(HCVTM)sinter were investigated in this work.The main characterization methods of X-ray fluorescence(...The effects of basicity and temperature on the reduction process of Hongge high-chromium vanadium-titanium magnetite(HCVTM)sinter were investigated in this work.The main characterization methods of X-ray fluorescence(XRF),X-ray diffraction(XRD),scanning electron microscope(SEM),and metallographic microscope were employed in this study.In this work,the reduction of HCVTM sinter with different temperature and basicity were experimented.The Fe,FeO,and TiO in reductive samples increase with increasing basicity and temperatures.The increase of basicity and temperature is favorable to the reduction of HCVTM sinter.The Fe phase has out-migration tendency to the surface of sinter while the perovskite and silicate phases have in-migration tendency to the inside of sinter.The reduction degradation index(RDI)decreases while the reduction index(RI)increases with increasing basicity.The RI increases from 67.14%to 82.09%with increasing temperature from 1073 K to 1373 K.展开更多
The electrokinetic properties and flotation of diaspore, kaolinite, pyrophyllite and illite with quaternary ammonium salts collectors were studied. The results of flotation tests show that the collecting ability of qu...The electrokinetic properties and flotation of diaspore, kaolinite, pyrophyllite and illite with quaternary ammonium salts collectors were studied. The results of flotation tests show that the collecting ability of quaternary ammonium salts for the four minerals is in the order（from strong to weak） ofoctadecyl dimethyl benzyl ammonium chloride（ODBA）, cetyl trimethyl ammonium bromide（CTAB）, dodecyl trimethyl ammonium chloride（DTAC）. Under the condition of alkalescence, it is possible to separate the diaspore from the silicate minerals such as kaolinite, illite and pyrophyllite using quaternary ammonium salts as collector. Isoelectric points （IEP） of diaspore, kaolinite, pyrophyllite and illite are pH=6.0, 3.4, 2.3 and 3.2, respectively. Quaternary ammonium salts can change ζ-potential of the aluminosilicate minerals obviously. The flotation mechanisms were explained by ζ-potential and Fourier transform infrared spectrum （FT-IR） measurements. The results demonstrate that only electrostatic interaction takes place between aluminosilicate minerals （diaspore, kaolinite, pyrophyllite and illite） and quaternary ammonium salts.展开更多
Mine drainage could be filtered and purified through goaf. This innovative technique shows merits, such as high treatment efficiency, remarkable economic benefit and extensive wastewater recycle use. However, it was d...Mine drainage could be filtered and purified through goaf. This innovative technique shows merits, such as high treatment efficiency, remarkable economic benefit and extensive wastewater recycle use. However, it was detected that capacities of purifying mine drainage for goaf were decreased after a period of application. As a result, the effluent could not meet the standard of recycle water. To solve the problem, coagulant was considered to add into mine drainage reducing its high turbid degrees to certain level. After the preliminary flocculation treatment, mine drainage was piped into goaf to purify. In this way, the load of goaf was eased up. Its usage time was also prolonged. Therefore, this paper carried out the coagulation-flocculation jar test for mine drainage to discuss the flocculation parameters. By the experiment, 10 % iron trichloride is selected from four inorganic coagulants as the optimum coagulant. The optimum dose, PH value and sedirs6-7 and 25 min. Velocity mentation time are respectively 2 mL per 800 mL Wastewater gradient G during the process of mixing and reaction is 696 .And the value of GT is 6.264 × 10^5. The values of G and GT will supply the basis for the design of flocculation pool in the project. The flocculation parameters will be significant for the reference of practice.展开更多
基金Project(2013CB632603)supported by the National Basic Research Program of ChinaProject(2015BAB19B02)supported by the National Key Technology R&D Program of ChinaProjects(51674084,51174051,51574082)supported by National Natural Science Foundation of China
文摘The effects of basicity and temperature on the reduction process of Hongge high-chromium vanadium-titanium magnetite(HCVTM)sinter were investigated in this work.The main characterization methods of X-ray fluorescence(XRF),X-ray diffraction(XRD),scanning electron microscope(SEM),and metallographic microscope were employed in this study.In this work,the reduction of HCVTM sinter with different temperature and basicity were experimented.The Fe,FeO,and TiO in reductive samples increase with increasing basicity and temperatures.The increase of basicity and temperature is favorable to the reduction of HCVTM sinter.The Fe phase has out-migration tendency to the surface of sinter while the perovskite and silicate phases have in-migration tendency to the inside of sinter.The reduction degradation index(RDI)decreases while the reduction index(RI)increases with increasing basicity.The RI increases from 67.14%to 82.09%with increasing temperature from 1073 K to 1373 K.
基金Project(2005CB623701) supported by the National Key Fundamental Research and Development Program of China
文摘The electrokinetic properties and flotation of diaspore, kaolinite, pyrophyllite and illite with quaternary ammonium salts collectors were studied. The results of flotation tests show that the collecting ability of quaternary ammonium salts for the four minerals is in the order（from strong to weak） ofoctadecyl dimethyl benzyl ammonium chloride（ODBA）, cetyl trimethyl ammonium bromide（CTAB）, dodecyl trimethyl ammonium chloride（DTAC）. Under the condition of alkalescence, it is possible to separate the diaspore from the silicate minerals such as kaolinite, illite and pyrophyllite using quaternary ammonium salts as collector. Isoelectric points （IEP） of diaspore, kaolinite, pyrophyllite and illite are pH=6.0, 3.4, 2.3 and 3.2, respectively. Quaternary ammonium salts can change ζ-potential of the aluminosilicate minerals obviously. The flotation mechanisms were explained by ζ-potential and Fourier transform infrared spectrum （FT-IR） measurements. The results demonstrate that only electrostatic interaction takes place between aluminosilicate minerals （diaspore, kaolinite, pyrophyllite and illite） and quaternary ammonium salts.
文摘Mine drainage could be filtered and purified through goaf. This innovative technique shows merits, such as high treatment efficiency, remarkable economic benefit and extensive wastewater recycle use. However, it was detected that capacities of purifying mine drainage for goaf were decreased after a period of application. As a result, the effluent could not meet the standard of recycle water. To solve the problem, coagulant was considered to add into mine drainage reducing its high turbid degrees to certain level. After the preliminary flocculation treatment, mine drainage was piped into goaf to purify. In this way, the load of goaf was eased up. Its usage time was also prolonged. Therefore, this paper carried out the coagulation-flocculation jar test for mine drainage to discuss the flocculation parameters. By the experiment, 10 % iron trichloride is selected from four inorganic coagulants as the optimum coagulant. The optimum dose, PH value and sedirs6-7 and 25 min. Velocity mentation time are respectively 2 mL per 800 mL Wastewater gradient G during the process of mixing and reaction is 696 .And the value of GT is 6.264 × 10^5. The values of G and GT will supply the basis for the design of flocculation pool in the project. The flocculation parameters will be significant for the reference of practice.
