Micromixing in the submerged circulative impinging stream reactor (SCISR) developed by the authors is investigated with the Bourne's reaction scheme. The values measured for the impinging velocity, u0, under the ...Micromixing in the submerged circulative impinging stream reactor (SCISR) developed by the authors is investigated with the Bourne's reaction scheme. The values measured for the impinging velocity, u0, under the conditions of SCISR normal operation, only is of the order of 0.1m·s^-1, are much slower than that inferred,suggesting low power requirement for operation. The values of the characteristic time constant for micromixing,tM, determined in the impinging velocity range of 0.184m·s^-1 < u0 < 0.326m·s^-1 are ranged from 192ms to 87 ms, showing that impinging streams promotes micromixing very efficiently. The data follow approximately the relationship of tM∝ u0^-1.5. A comparative study shows that the micromixing performance of SCISR is much better than that of the traditional stirred tank reactor. The tM values predicted with the existing theoretical model are systematically longer than those measured by about 2--3 times, implying that the regularity of impinging streams promoting micromixing is unclear yet.展开更多
Palladium oxide(PdOx)and cobalt oxide(Co3O4)are efficient catalysts for methane(CH4)combustion,and Pd‐doped Co3O4catalysts have been found to exhibit better catalytic activities,which suggest synergism between the tw...Palladium oxide(PdOx)and cobalt oxide(Co3O4)are efficient catalysts for methane(CH4)combustion,and Pd‐doped Co3O4catalysts have been found to exhibit better catalytic activities,which suggest synergism between the two components.We carried out first‐principles calculations at the PBE+U level to investigate the Pd‐doping effect on CH4reactivity over the Co3O4catalyst.Because of the structural complexity of the Pd‐doped Co3O4catalyst,we built Pd‐doped catalyst models using Co3O4(001)slabs with two different terminations and examined CH4reactivity over the possible Pd?O active sites.A low energy barrier of0.68eV was predicted for CH4dissociation over the more reactive Pd‐doped Co3O4(001)surface,which was much lower than the0.98and0.89eV that was predicted previously over the more reactive pure Co3O4(001)and(011)surfaces,respectively.Using a simple model,we predicted CH4reaction rates over the pure Co3O4(001)and(011)surfaces,and Co3O4(001)surfaces with different amounts of Pd dopant.Our theoretical results agree well with the available experimental data,which suggests a strong synergy between the Pd dopant and the Co3O4catalyst,and leads to a significant increase in CH4reaction rate.展开更多
Different sized single droplets of Cu-6%Sn alloy were prepared by drop on demand(DOD)technique.The secondarydendrite arm spacing was measured and correlated with the droplet cooling rate by a semi-empirical formula.Th...Different sized single droplets of Cu-6%Sn alloy were prepared by drop on demand(DOD)technique.The secondarydendrite arm spacing was measured and correlated with the droplet cooling rate by a semi-empirical formula.The microstructure ofdroplets was observed by optical microscopy(OM)and electro backscatter diffraction(EBSD).The dendrite feature of singledroplets depends on solidification rate,cooling medium and flight distance.When droplets collide with each other at temperaturesbetween solidus and liquidus,the dendrites and grains are refined obviously possibly because the collision enhances the heat transfer.The cooling rate of colliding droplets is estimated to be more than4×104K/s based on a Newton’s cooling model.The dendritesgrow along the colliding direction because of the temperature gradient induced by the internal flow inside the droplets.展开更多
During the 100%front impact,all the parts of front car will participate in the course;the crash stiffness of bodywork will also reach the peak.During the crash,rational structure of bodywork can resist the distortion,...During the 100%front impact,all the parts of front car will participate in the course;the crash stiffness of bodywork will also reach the peak.During the crash,rational structure of bodywork can resist the distortion,absorb more energy and get better mode of distortion and low deceleration rate,so as to meet the performance of crash safety.The paper mainly makes optimization analysis based on the problems of front side rails,subframe,firewall,and optimization cases are confirmed which can decrease the intrusion and deceleration rate of the whole car.The structure of bodywork after optimization can meet the performance of crash safety.展开更多
基金Supported by the National Natural Science Foundation of China (No. 29276260, No. 20176043).
文摘Micromixing in the submerged circulative impinging stream reactor (SCISR) developed by the authors is investigated with the Bourne's reaction scheme. The values measured for the impinging velocity, u0, under the conditions of SCISR normal operation, only is of the order of 0.1m·s^-1, are much slower than that inferred,suggesting low power requirement for operation. The values of the characteristic time constant for micromixing,tM, determined in the impinging velocity range of 0.184m·s^-1 < u0 < 0.326m·s^-1 are ranged from 192ms to 87 ms, showing that impinging streams promotes micromixing very efficiently. The data follow approximately the relationship of tM∝ u0^-1.5. A comparative study shows that the micromixing performance of SCISR is much better than that of the traditional stirred tank reactor. The tM values predicted with the existing theoretical model are systematically longer than those measured by about 2--3 times, implying that the regularity of impinging streams promoting micromixing is unclear yet.
基金supported by the National Natural Science Foundation of China(21473233,21403277)the Energy Technologies Institute LLP,UK~~
文摘Palladium oxide(PdOx)and cobalt oxide(Co3O4)are efficient catalysts for methane(CH4)combustion,and Pd‐doped Co3O4catalysts have been found to exhibit better catalytic activities,which suggest synergism between the two components.We carried out first‐principles calculations at the PBE+U level to investigate the Pd‐doping effect on CH4reactivity over the Co3O4catalyst.Because of the structural complexity of the Pd‐doped Co3O4catalyst,we built Pd‐doped catalyst models using Co3O4(001)slabs with two different terminations and examined CH4reactivity over the possible Pd?O active sites.A low energy barrier of0.68eV was predicted for CH4dissociation over the more reactive Pd‐doped Co3O4(001)surface,which was much lower than the0.98and0.89eV that was predicted previously over the more reactive pure Co3O4(001)and(011)surfaces,respectively.Using a simple model,we predicted CH4reaction rates over the pure Co3O4(001)and(011)surfaces,and Co3O4(001)surfaces with different amounts of Pd dopant.Our theoretical results agree well with the available experimental data,which suggests a strong synergy between the Pd dopant and the Co3O4catalyst,and leads to a significant increase in CH4reaction rate.
基金Project(51301143)supported by the National Natural Science Foundation of ChinaProject(2014M560727)supported by the National Postdoctoral Foundation of China+1 种基金Project(2015GZ0228)supported by the Sichuan Province Science-Technology Support Plan,ChinaProject(2682014CX001)supported by the Science and Technology Innovation Project of SWJTU University,China
文摘Different sized single droplets of Cu-6%Sn alloy were prepared by drop on demand(DOD)technique.The secondarydendrite arm spacing was measured and correlated with the droplet cooling rate by a semi-empirical formula.The microstructure ofdroplets was observed by optical microscopy(OM)and electro backscatter diffraction(EBSD).The dendrite feature of singledroplets depends on solidification rate,cooling medium and flight distance.When droplets collide with each other at temperaturesbetween solidus and liquidus,the dendrites and grains are refined obviously possibly because the collision enhances the heat transfer.The cooling rate of colliding droplets is estimated to be more than4×104K/s based on a Newton’s cooling model.The dendritesgrow along the colliding direction because of the temperature gradient induced by the internal flow inside the droplets.
基金"Twelfth Five-year Plan"for Sci & Tech Research of China(No.2011BAG03B02No.2011BAG03B06)
文摘During the 100%front impact,all the parts of front car will participate in the course;the crash stiffness of bodywork will also reach the peak.During the crash,rational structure of bodywork can resist the distortion,absorb more energy and get better mode of distortion and low deceleration rate,so as to meet the performance of crash safety.The paper mainly makes optimization analysis based on the problems of front side rails,subframe,firewall,and optimization cases are confirmed which can decrease the intrusion and deceleration rate of the whole car.The structure of bodywork after optimization can meet the performance of crash safety.
