Mossbauer spectroscopy was established as an analytical method 50 years ago and it is still of current interest in many disciplines as mineralogy, environmental science, archeology and biology. Areas of research where...Mossbauer spectroscopy was established as an analytical method 50 years ago and it is still of current interest in many disciplines as mineralogy, environmental science, archeology and biology. Areas of research where Mossbauer spectroscopy is contributing are metals and alloys, magnetic materials, chemical compounds and oxidation states, nanoparticles and many others. Different types of amorphous and nanocrystalline materials （e.g. finemet, nanoperm and hitperm） can be analyzed under different external influence like neutron irradiation or external magnetic field. Mineralogical samples as potassium white micas in sheared basement cover rocks from the Central Western Carpathians and meteorites can be also effectively investigated using MOssbauer spectroscopy. Phase analysis of meteorites can be helpful in their classification and moreover, particular magnetic and non-magnetic components can be analyzed in details. At present, the Mossbauer spectroscopy is also used to analyze environmental materials like zeolites, volcanic tephra and compounds containing ferrate （Fe6＋）.展开更多
In this work, we fabricate an efficient and stable photocatalyst system which has superior recyclability even under concentrated acidic conditions. The photocatalyst is prepared by assembling magnetic graphitic nanoca...In this work, we fabricate an efficient and stable photocatalyst system which has superior recyclability even under concentrated acidic conditions. The photocatalyst is prepared by assembling magnetic graphitic nanocapsules, titania(Ti O2) and graphene oxide(GO) into a complex system through π-π stacking and electrostatic interactions. Such catalytic complex demonstrates very high stability. Even after dispersal into a concentrated acidic solution for one month, this photocatalyst could still be recycled and maintain its catalytic activity. With methyl orange as the model molecule, the photocatalyst is demonstrated to rapidly decompose the molecules with very high photocatalytic activity under both concentrated acidic and neutral condition. Moreover, this photocatalyst retains approximately 100 wt% of its original photocatalytic activity even after multiple experimental runs, of magnetic recycling. Finally, using different samples from natural water sources and different dyes, this GO/ magnetic graphitic nanocapsule/Ti O2 system also demonstrates its high efficiency and recyclability for practical application.展开更多
文摘Mossbauer spectroscopy was established as an analytical method 50 years ago and it is still of current interest in many disciplines as mineralogy, environmental science, archeology and biology. Areas of research where Mossbauer spectroscopy is contributing are metals and alloys, magnetic materials, chemical compounds and oxidation states, nanoparticles and many others. Different types of amorphous and nanocrystalline materials （e.g. finemet, nanoperm and hitperm） can be analyzed under different external influence like neutron irradiation or external magnetic field. Mineralogical samples as potassium white micas in sheared basement cover rocks from the Central Western Carpathians and meteorites can be also effectively investigated using MOssbauer spectroscopy. Phase analysis of meteorites can be helpful in their classification and moreover, particular magnetic and non-magnetic components can be analyzed in details. At present, the Mossbauer spectroscopy is also used to analyze environmental materials like zeolites, volcanic tephra and compounds containing ferrate （Fe6＋）.
基金supported by the National Basic Research Program of China(2013CB932702)the Research Fund for the Program on National Key Scientific Instruments and Equipment Development(2011YQ0301241402)+1 种基金the National Natural Science Foundation of China(21105025)the Hunan Innovation and Entrepreneurship Program
文摘In this work, we fabricate an efficient and stable photocatalyst system which has superior recyclability even under concentrated acidic conditions. The photocatalyst is prepared by assembling magnetic graphitic nanocapsules, titania(Ti O2) and graphene oxide(GO) into a complex system through π-π stacking and electrostatic interactions. Such catalytic complex demonstrates very high stability. Even after dispersal into a concentrated acidic solution for one month, this photocatalyst could still be recycled and maintain its catalytic activity. With methyl orange as the model molecule, the photocatalyst is demonstrated to rapidly decompose the molecules with very high photocatalytic activity under both concentrated acidic and neutral condition. Moreover, this photocatalyst retains approximately 100 wt% of its original photocatalytic activity even after multiple experimental runs, of magnetic recycling. Finally, using different samples from natural water sources and different dyes, this GO/ magnetic graphitic nanocapsule/Ti O2 system also demonstrates its high efficiency and recyclability for practical application.
