Effects of agglomerates on the densification behavior and microstructural evolution during solid-state sintering of a cube of copper particles have been studied with discrete element method (DEM).It is found that the ...Effects of agglomerates on the densification behavior and microstructural evolution during solid-state sintering of a cube of copper particles have been studied with discrete element method (DEM).It is found that the densification of the sintering system decreases as the volume fraction of agglomerates increases.At a given volume fraction of agglomerates,the smaller the size of agglomerates,the poorer the densification and more inhomogeneous the compact is.The morphology and distribution of agglomerates have negligible effects on the densification,especially for the case with a low volume fraction of agglomerates.Agglomerates with a smaller average coordination number would have more restriction on the densification of sintering bodies.To our best knowledge,it is the first time to study the effect of agglomerates on sintering behavior using DEM.This study should be useful for further investigations of the effect of various inhomogeneities of microstructure on the complex sintering process by DEM.展开更多
Nanoparticles monolayer formation by spin coating is considered to be a simple, fast and inexpensive nanopatteming technique However, the parameters that govern the overall growth process in this technique are not com...Nanoparticles monolayer formation by spin coating is considered to be a simple, fast and inexpensive nanopatteming technique However, the parameters that govern the overall growth process in this technique are not completely quantified and techniques for the controlled and continuous growth of close packed monolayer particle arrays without defects need to be developed. In this paper, an ordered particle array formation process is analyzed theoretically, employing material flux balance and parti- cle-subjected forces balance, based on the film thickness model of spin coating and evaporation rate law. A series of experi- ments were conducted using silica particle suspensions with various particle volume fractions and different spin speeds. The results show that the spin speed should match the particle volume fraction to meet the requirements of material flux and particles movement in order to obtain a close packed monolayer film. The formation mechanism of fabrication defects involving particle agglomeration and uncontrollable voids were analyzed qualitatively based on crystal growth theory, and validation experiments were performed. The formation of highly uniform close-packed monolayer films was demonstrated and the condi- tion requirements for achieving monolayer nanoparticles array with good quality presented.展开更多
A multi-lattice deterministic trajectory(MLDT) model is developed to simulate dense gas-particle flow in a vertical channel.The actual inter-particle collision and particle motion are treated by a Lagrangian model wit...A multi-lattice deterministic trajectory(MLDT) model is developed to simulate dense gas-particle flow in a vertical channel.The actual inter-particle collision and particle motion are treated by a Lagrangian model with three sets of lattices to reduce computational time.Cluster formation and motion near the wall are successfully predicted with mean particle volume fraction and velocity,showing quantitatively agreement with experimental results.The mechanism of particles concentrated near the wall is investigated by considering effects of gravity,particle-wall collisions,inter-particle collisions and velocity profiles of the gas phase.It is shown that the inter-particle collision and gas-phase velocity distribution are the essential factors for cluster formation near the wall,while gravity and particle-wall collision only have minor effects on particle concentration near the wall.Particles are unable to remain in the high velocity region due to the strong inter-particle collisions,while they tend to stay in the low velocity region for weak inter-particle collisions.In addition,the effects of channel width and particle sizes on cluster formation are also investigated and it is found that particle concentration near the wall reduces with the decrease of channel width and increase of particle size.展开更多
基金supported by the National Natural Science Foundation of China (Grant Nos.10972220,11021262 and 11125211)the National Basic Research Program of China (Grant No.2012CB937500)
文摘Effects of agglomerates on the densification behavior and microstructural evolution during solid-state sintering of a cube of copper particles have been studied with discrete element method (DEM).It is found that the densification of the sintering system decreases as the volume fraction of agglomerates increases.At a given volume fraction of agglomerates,the smaller the size of agglomerates,the poorer the densification and more inhomogeneous the compact is.The morphology and distribution of agglomerates have negligible effects on the densification,especially for the case with a low volume fraction of agglomerates.Agglomerates with a smaller average coordination number would have more restriction on the densification of sintering bodies.To our best knowledge,it is the first time to study the effect of agglomerates on sintering behavior using DEM.This study should be useful for further investigations of the effect of various inhomogeneities of microstructure on the complex sintering process by DEM.
基金supported by the National Natural Science Foundation of China(Grant Nos.51375381,51575427 and 51675422)the 2015 Overall Planning Innovation Project Foundation of Shaanxi Province(Grant No.2015KTCQ01-36)
文摘Nanoparticles monolayer formation by spin coating is considered to be a simple, fast and inexpensive nanopatteming technique However, the parameters that govern the overall growth process in this technique are not completely quantified and techniques for the controlled and continuous growth of close packed monolayer particle arrays without defects need to be developed. In this paper, an ordered particle array formation process is analyzed theoretically, employing material flux balance and parti- cle-subjected forces balance, based on the film thickness model of spin coating and evaporation rate law. A series of experi- ments were conducted using silica particle suspensions with various particle volume fractions and different spin speeds. The results show that the spin speed should match the particle volume fraction to meet the requirements of material flux and particles movement in order to obtain a close packed monolayer film. The formation mechanism of fabrication defects involving particle agglomeration and uncontrollable voids were analyzed qualitatively based on crystal growth theory, and validation experiments were performed. The formation of highly uniform close-packed monolayer films was demonstrated and the condi- tion requirements for achieving monolayer nanoparticles array with good quality presented.
基金partially supported by the National Basic Research Program of China ("973" Project) (Grant No. 62980532)
文摘A multi-lattice deterministic trajectory(MLDT) model is developed to simulate dense gas-particle flow in a vertical channel.The actual inter-particle collision and particle motion are treated by a Lagrangian model with three sets of lattices to reduce computational time.Cluster formation and motion near the wall are successfully predicted with mean particle volume fraction and velocity,showing quantitatively agreement with experimental results.The mechanism of particles concentrated near the wall is investigated by considering effects of gravity,particle-wall collisions,inter-particle collisions and velocity profiles of the gas phase.It is shown that the inter-particle collision and gas-phase velocity distribution are the essential factors for cluster formation near the wall,while gravity and particle-wall collision only have minor effects on particle concentration near the wall.Particles are unable to remain in the high velocity region due to the strong inter-particle collisions,while they tend to stay in the low velocity region for weak inter-particle collisions.In addition,the effects of channel width and particle sizes on cluster formation are also investigated and it is found that particle concentration near the wall reduces with the decrease of channel width and increase of particle size.
