A series of zeolites,including USY zeolites without sodium,Na-USY at different Na contents,La-USY with different rare earth（RE） contents and La-Na-USY with RE and Na were prepared by an ion exchange method.They were...A series of zeolites,including USY zeolites without sodium,Na-USY at different Na contents,La-USY with different rare earth（RE） contents and La-Na-USY with RE and Na were prepared by an ion exchange method.They were investigated to understand the activation barriers for the destruction of Y zeolite structure under hydrothermal treatment and the effect of V using the solid-state kinetic model.The results showed that the pathways for Y zeolite destruction were dealumination,desiliconization and the disappearance of La-O bonds.Zeolites were destroyed by steam through acid hydrolysis,which was accelerated by V.In addition,Na and V exerted a synergistic effect on the framework destruction,and the formation of NaOH was the rate-determining step.The presence of RE elements decreased hydrolysis and stabilized the structure of the zeolites.The interaction between V and RE destroyed zeolite structure by eliminating the stabilizing La-O[RE-OH-RE]^（5＋）bridges in the sodalite cages.展开更多
Tunnels in an urban area, in many cases, are constructed in soft ground which contains underground water, near existing facilities and structures. Structural stability for the tunnel and also the nearby structures and...Tunnels in an urban area, in many cases, are constructed in soft ground which contains underground water, near existing facilities and structures. Structural stability for the tunnel and also the nearby structures and facilities is vital in this kind of work. Slurry pipe jacking was firmly established as a special method for the non-disruptive construction of underground pipelines of sewage systems. This method utilizes mud slurry that is formed around the pipes in order to stabilize the surrounding soil. In the pipe roof method the tubing elements that are constructed by slurry pipe jacking are near each other longitudinally, and create a rigid and stable lining before the excavation of the main tunnel. This paper discusses ＇the application of a slurry pipe jacking system on ＇the pipe roof method by means of numerical analysis. Because of the rigid behavior of the lining, the results show little subsidence, making this method a reliable method of constructing large tunnels with small cover in an urban area.展开更多
基金supported by the Exploratory Research Program of Petrochemical Research Institute,PetroChina~~
文摘A series of zeolites,including USY zeolites without sodium,Na-USY at different Na contents,La-USY with different rare earth（RE） contents and La-Na-USY with RE and Na were prepared by an ion exchange method.They were investigated to understand the activation barriers for the destruction of Y zeolite structure under hydrothermal treatment and the effect of V using the solid-state kinetic model.The results showed that the pathways for Y zeolite destruction were dealumination,desiliconization and the disappearance of La-O bonds.Zeolites were destroyed by steam through acid hydrolysis,which was accelerated by V.In addition,Na and V exerted a synergistic effect on the framework destruction,and the formation of NaOH was the rate-determining step.The presence of RE elements decreased hydrolysis and stabilized the structure of the zeolites.The interaction between V and RE destroyed zeolite structure by eliminating the stabilizing La-O[RE-OH-RE]^（5＋）bridges in the sodalite cages.
文摘Tunnels in an urban area, in many cases, are constructed in soft ground which contains underground water, near existing facilities and structures. Structural stability for the tunnel and also the nearby structures and facilities is vital in this kind of work. Slurry pipe jacking was firmly established as a special method for the non-disruptive construction of underground pipelines of sewage systems. This method utilizes mud slurry that is formed around the pipes in order to stabilize the surrounding soil. In the pipe roof method the tubing elements that are constructed by slurry pipe jacking are near each other longitudinally, and create a rigid and stable lining before the excavation of the main tunnel. This paper discusses ＇the application of a slurry pipe jacking system on ＇the pipe roof method by means of numerical analysis. Because of the rigid behavior of the lining, the results show little subsidence, making this method a reliable method of constructing large tunnels with small cover in an urban area.
