A microphone and a seismic sensor always become a basic unit of UGS(unattended ground sensors) system. The mechanism of acoustic and seismic property of target and its propagation are described. The acoustic and seism...A microphone and a seismic sensor always become a basic unit of UGS(unattended ground sensors) system. The mechanism of acoustic and seismic property of target and its propagation are described. The acoustic and seismic signals of targets are analyzed with time frequency distribution according to its non stationary property. Narrow band energy function (NEF) and local power spectral density (LPSD) are proposed to extract features for target identification. Experiment results show that local power spectral density indicates corresponding target clearly.展开更多
According to the definition of interface traps,a new application of relaxation spectral technique to sub-threshold swing shift and sub-threshold gate voltage shift is proposed to extract interface trap density in 1.9n...According to the definition of interface traps,a new application of relaxation spectral technique to sub-threshold swing shift and sub-threshold gate voltage shift is proposed to extract interface trap density in 1.9nm MOSFET.And thus the energy distribution of interface trap can be determined.According to the two methods,the energy profile of interface traps agrees with those reported in literature.Compared to other methods,this method is simpler and more convenient.展开更多
We investigated the structural evolution and elecfronic properties of ConC3-/0 and ConC4-/0 （n=1-4） clusters by using mass-selected photoelectron spectroscopy and density functional theory calculations. The adiabati...We investigated the structural evolution and elecfronic properties of ConC3-/0 and ConC4-/0 （n=1-4） clusters by using mass-selected photoelectron spectroscopy and density functional theory calculations. The adiabatic and vertical detachment energies of CO1-4C3- and COl-4C4- were obtained from their photoelectron spectra. By comparing the theoretical results with the experimental data, the global minimum structures were determined. The results indicate that the carbon atoms of ConC3-/0 and ConC4-/0 （n=1-4） are separated from each other gradually with increasing number of cobalt atoms but a C2 unit still remains at n=4. It is interesting that the Co2C3- and Co2C4- anions have planar structures whereas the neutral Co2C3 and Co2C4 have linear structures with the Co atoms at two ends. The Co3C3- anion has a planar structure with a Co2C2 four-membered ring and a Co3C four-membered ring sharing a Co-Co bond, while the neutral Co3C3 is a three-dimensional structure with a C2 unit and a C atom connecting to two faces of the Co3 triangle.展开更多
The growth pattern and electronic properties of TiGen^- （n=7-12） clusters were investigated using anion photoelectron spectroscopy and density functional theory calculations. For both anionic and neutral TiGen clust...The growth pattern and electronic properties of TiGen^- （n=7-12） clusters were investigated using anion photoelectron spectroscopy and density functional theory calculations. For both anionic and neutral TiGen clusters, a half-encapsulated boat-shaped structure appears at n=8, and the boat-shaped structure is gradually covered by the additional Ge atoms to form Gen cage at n=9-11. TiGe12^- cluster has a distorted hexagonal prism cage structure. According to the natural population analysis, the electron transfers from the Gen framework to the Ti atom for TiGen^-/0 clusters at n=8-12, implying that the electron transfer pattern is related to the structural evolution.展开更多
A styryl phosphonate ester(SPE) collector was used to improve the flotation performance of ilmenite, and the adsorption mechanism and model were revealed and established, respectively. Microflotation tests showed that...A styryl phosphonate ester(SPE) collector was used to improve the flotation performance of ilmenite, and the adsorption mechanism and model were revealed and established, respectively. Microflotation tests showed that SPE exhibited a stronger collecting ability for ilmenite than the traditional collector styrene phosphonic acid(SPA). Zeta potential measurements revealed that both SPE and SPA could negatively shift the zeta potential of ilmenite, while SPE had more effects than SPA, suggesting the stronger adsorption of SPE. The analysis of X-ray photoelectron spectroscopy confirmed the chemisorption of SPA and SPE onto the Fe/Ti sites of ilmenite. According to frontier orbital theory, the chemical activities of SPE are greater than those of SPA. The partial densities of states analysis indicated that the PO—H groups of the collectors could interact with the Ti/Fe atoms of the ilmenite surface to generate a stable four-membered ring. The bonding model of the collector and(104) ilmenite surface showed that the adsorption energy of SPE was higher than that of SPA. Overall, SPE presented a better collecting ability and interaction effect for ilmenite flotation than SPA, and had the potential to replace SPA in the industry.展开更多
We measured the photoelectron spectra of AuC_(n)^(-)(n=3-8)and conducted theoretical study on the structures and properties of AuC_(n)^(-/0)(n=3-8).It is found that the photoelectron spectra of AuC_(n)^(-)exhibit odd-...We measured the photoelectron spectra of AuC_(n)^(-)(n=3-8)and conducted theoretical study on the structures and properties of AuC_(n)^(-/0)(n=3-8).It is found that the photoelectron spectra of AuC_(n)^(-)exhibit odd-even alternation.The spectral features of AuC_(3)^(-),AuC_(5)^(-),and AuC_(7)^(-)are much broader than those of AuC_(4)^(-),AuC_(6)^(-),and AuC_(5)^(-).The vertical detachment energies of AuC_(3)^(-),AuC_(5)^(-),and AuC_(7)^(-)are lower than those of AuC_(4)^(-),AuC_(6)^(-),and AuCs_(8)^(-).The most stable structures of AuC_(n)^(-)(n=3-8)are chain structures.The most stable structures of neutral AuC_(n)(n=3-8)are linear structures except that those of AuC_(3) and AuC_(5) are slightly bent.The calculated∠AuCC angles,Au-C bond lengths,and the charges on Au atom also show odd-even alternations,consistent with the experimental observations.展开更多
The photophysics of 3-dimethylamino-2-methyl-propenal （DMAMP） after excitation to the S2 （ππ^＊） electronic state was studied using the resonance Raman spectroscopy and complete active space self-consistent fiel...The photophysics of 3-dimethylamino-2-methyl-propenal （DMAMP） after excitation to the S2 （ππ^＊） electronic state was studied using the resonance Raman spectroscopy and complete active space self-consistent field method calculations. The transition barriers of the ground state tautomerization reactions between DMAMP and its three isomers were determined at B3LYP/6-311＋＋G（d,p） level of theory. The vibrational spectra were assigned. The A- band resonance Raman spectra were obtained in acetonitrile with excitation wavelengths in resonance with the first intense absorption band to probe the structural dynamics of DMAMP. The B3LYP-TD computation was carried out to determine the relative A-band resonance Raman intensities of the fundamental modes, and the result indicated that the vibronic-coupling existed in Franck-Condon region. Complete active space self-consistent field （CASSCF） calculations were carried out to determine the excitation energies of the lower-lying singlet and triplet excited states, the conical intersection points and the intersystem crossing points. The A-band short-time structural dynamics and the corresponding decay dynamics of DMAMP were obtained by analysis of the resonance Raman intensity pattern and CASSCF computations. It was found that a sudden de-conjugation between C1=O6 and C2=C3 occurred at the Franck-Condon region of the S2（ππ^＊） state, while the enhancement of the conjugation interaction between C3 and N（CH3）2, and between C1 and C2 evolutions shortly after the wavepacket leaves away the Pranck-Condon region via the excited state charge redistribution. The de-conjugation interaction between C1=O6 and C2=C3 made the rotation of C3=N（CH3）2 group around the C2-C3 bond much easier, while the enhanced conjugation between C1 and C2, and between C3 and N（CH3）2 made the rotation around the C1-C2 bond and C3-N5 more difficult. It was revealed that the initial structural dynamics of DMAMP was predominantly towards the CI-I（S2/S0） point, while the opportunities towards either CI-2（S2/S0） or CI-3（S2/S0） point were negligible. Two decay channels of DMAMP from S2,FC（ππ^＊） to So or Tl,min via various CIs and ISCs were proposed.展开更多
This paper analyzes the unified performance of energy detection(ED) of spectrum sensing(SS) over generalized fading channels in cognitive radios(CRs). The detective performance of SS will be obviously affected by fadi...This paper analyzes the unified performance of energy detection(ED) of spectrum sensing(SS) over generalized fading channels in cognitive radios(CRs). The detective performance of SS will be obviously affected by fading channels among communication nodes, and ED has the advantages of fast implementation, no requirement of priori received information and low complexity, so it is meaningful to investigate ED over various fading channels. The probability density function(p.d.f.) of α-κ-μ distribution is derived to evaluate energy efficiency for sensing systems.The detection probability with Marcum-Q function has been derived and the close-form expressions with moment generating function(MGF) method are deduced to achieve SS.Furthermore, exact closed-form analytic expressions for average area under the receiver operating characteristics curve( AUC) also have been deduced to analyze the performance characteristics of ED over α-κ-μ fading channels.Besides, cooperative spectrum sensing(CSS) with diversity reception has been applied to improve the detection accuracy and mitigate the shadowed fading features with OR-rule. At last, the results show that the detection capacity of ED will be evidently affected by α-κ-μ fading channels, but appropriate channel parameters can improve sensing performance. In addition, the establishedED-fading pattern is approved by simulations,and it can significantly enhance the detection performance of proposed algorithms.展开更多
The vibration of an elastic beam experiencing vortex-induced vibration is numerically analyzed employing a wake-oscillator model. The influence of the excited mode, the initial velocity, the shedding pulsation and the...The vibration of an elastic beam experiencing vortex-induced vibration is numerically analyzed employing a wake-oscillator model. The influence of the excited mode, the initial velocity, the shedding pulsation and the mass ratio on the energy transfer among modes and the vibration amplitude is determined. Multiple frequencies are detected, and the power spectral density of the beam tip time series is used to calculate the dominant frequency.展开更多
文摘A microphone and a seismic sensor always become a basic unit of UGS(unattended ground sensors) system. The mechanism of acoustic and seismic property of target and its propagation are described. The acoustic and seismic signals of targets are analyzed with time frequency distribution according to its non stationary property. Narrow band energy function (NEF) and local power spectral density (LPSD) are proposed to extract features for target identification. Experiment results show that local power spectral density indicates corresponding target clearly.
文摘According to the definition of interface traps,a new application of relaxation spectral technique to sub-threshold swing shift and sub-threshold gate voltage shift is proposed to extract interface trap density in 1.9nm MOSFET.And thus the energy distribution of interface trap can be determined.According to the two methods,the energy profile of interface traps agrees with those reported in literature.Compared to other methods,this method is simpler and more convenient.
文摘We investigated the structural evolution and elecfronic properties of ConC3-/0 and ConC4-/0 （n=1-4） clusters by using mass-selected photoelectron spectroscopy and density functional theory calculations. The adiabatic and vertical detachment energies of CO1-4C3- and COl-4C4- were obtained from their photoelectron spectra. By comparing the theoretical results with the experimental data, the global minimum structures were determined. The results indicate that the carbon atoms of ConC3-/0 and ConC4-/0 （n=1-4） are separated from each other gradually with increasing number of cobalt atoms but a C2 unit still remains at n=4. It is interesting that the Co2C3- and Co2C4- anions have planar structures whereas the neutral Co2C3 and Co2C4 have linear structures with the Co atoms at two ends. The Co3C3- anion has a planar structure with a Co2C2 four-membered ring and a Co3C four-membered ring sharing a Co-Co bond, while the neutral Co3C3 is a three-dimensional structure with a C2 unit and a C atom connecting to two faces of the Co3 triangle.
基金Wei-jun Zheng acknowledges the Knowledge Innovation Program of the Chinese Academy of Sciences （No.KJCX2-EW-H01） and Hong-guang Xu acknowl- edges the National Natural Science Foundation of China （No.21103202） for financial support. The theoretical calculations were conducted on the ScGrid and Deep- Comp 7000 of the Supercomputing Center, Computer Network Information Center of the Chinese Academy of Sciences.
文摘The growth pattern and electronic properties of TiGen^- （n=7-12） clusters were investigated using anion photoelectron spectroscopy and density functional theory calculations. For both anionic and neutral TiGen clusters, a half-encapsulated boat-shaped structure appears at n=8, and the boat-shaped structure is gradually covered by the additional Ge atoms to form Gen cage at n=9-11. TiGe12^- cluster has a distorted hexagonal prism cage structure. According to the natural population analysis, the electron transfers from the Gen framework to the Ti atom for TiGen^-/0 clusters at n=8-12, implying that the electron transfer pattern is related to the structural evolution.
基金the support from the National Natural Science Foundation of China(Nos.51904214 and 51804238)the Young Elite Scientists Sponsorship Program by CAST(No.YESS20200276)+3 种基金the Natural Science Foundation of Hubei Province,China(No.ZRMS2021000085)the Fundamental Research Funds for the Central Universities,China(No.2021IVA039)the Open Foundation of State Key Laboratory of Mineral Processing,BGRIMM Technology,China(Nos.BGRIMM-KJSKL-202122 and BGRIMM-KJSKL-2022-02)the Open Project of Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of Education,China(No.201904)。
文摘A styryl phosphonate ester(SPE) collector was used to improve the flotation performance of ilmenite, and the adsorption mechanism and model were revealed and established, respectively. Microflotation tests showed that SPE exhibited a stronger collecting ability for ilmenite than the traditional collector styrene phosphonic acid(SPA). Zeta potential measurements revealed that both SPE and SPA could negatively shift the zeta potential of ilmenite, while SPE had more effects than SPA, suggesting the stronger adsorption of SPE. The analysis of X-ray photoelectron spectroscopy confirmed the chemisorption of SPA and SPE onto the Fe/Ti sites of ilmenite. According to frontier orbital theory, the chemical activities of SPE are greater than those of SPA. The partial densities of states analysis indicated that the PO—H groups of the collectors could interact with the Ti/Fe atoms of the ilmenite surface to generate a stable four-membered ring. The bonding model of the collector and(104) ilmenite surface showed that the adsorption energy of SPE was higher than that of SPA. Overall, SPE presented a better collecting ability and interaction effect for ilmenite flotation than SPA, and had the potential to replace SPA in the industry.
基金supported by the Beijing Municipal Science&Technology Commission(No.Z191100007219009)。
文摘We measured the photoelectron spectra of AuC_(n)^(-)(n=3-8)and conducted theoretical study on the structures and properties of AuC_(n)^(-/0)(n=3-8).It is found that the photoelectron spectra of AuC_(n)^(-)exhibit odd-even alternation.The spectral features of AuC_(3)^(-),AuC_(5)^(-),and AuC_(7)^(-)are much broader than those of AuC_(4)^(-),AuC_(6)^(-),and AuC_(5)^(-).The vertical detachment energies of AuC_(3)^(-),AuC_(5)^(-),and AuC_(7)^(-)are lower than those of AuC_(4)^(-),AuC_(6)^(-),and AuCs_(8)^(-).The most stable structures of AuC_(n)^(-)(n=3-8)are chain structures.The most stable structures of neutral AuC_(n)(n=3-8)are linear structures except that those of AuC_(3) and AuC_(5) are slightly bent.The calculated∠AuCC angles,Au-C bond lengths,and the charges on Au atom also show odd-even alternations,consistent with the experimental observations.
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China （No.21033002 and No.21202032） and the National Basic Research Program of China （No.2013CB834604）.
文摘The photophysics of 3-dimethylamino-2-methyl-propenal （DMAMP） after excitation to the S2 （ππ^＊） electronic state was studied using the resonance Raman spectroscopy and complete active space self-consistent field method calculations. The transition barriers of the ground state tautomerization reactions between DMAMP and its three isomers were determined at B3LYP/6-311＋＋G（d,p） level of theory. The vibrational spectra were assigned. The A- band resonance Raman spectra were obtained in acetonitrile with excitation wavelengths in resonance with the first intense absorption band to probe the structural dynamics of DMAMP. The B3LYP-TD computation was carried out to determine the relative A-band resonance Raman intensities of the fundamental modes, and the result indicated that the vibronic-coupling existed in Franck-Condon region. Complete active space self-consistent field （CASSCF） calculations were carried out to determine the excitation energies of the lower-lying singlet and triplet excited states, the conical intersection points and the intersystem crossing points. The A-band short-time structural dynamics and the corresponding decay dynamics of DMAMP were obtained by analysis of the resonance Raman intensity pattern and CASSCF computations. It was found that a sudden de-conjugation between C1=O6 and C2=C3 occurred at the Franck-Condon region of the S2（ππ^＊） state, while the enhancement of the conjugation interaction between C3 and N（CH3）2, and between C1 and C2 evolutions shortly after the wavepacket leaves away the Pranck-Condon region via the excited state charge redistribution. The de-conjugation interaction between C1=O6 and C2=C3 made the rotation of C3=N（CH3）2 group around the C2-C3 bond much easier, while the enhanced conjugation between C1 and C2, and between C3 and N（CH3）2 made the rotation around the C1-C2 bond and C3-N5 more difficult. It was revealed that the initial structural dynamics of DMAMP was predominantly towards the CI-I（S2/S0） point, while the opportunities towards either CI-2（S2/S0） or CI-3（S2/S0） point were negligible. Two decay channels of DMAMP from S2,FC（ππ^＊） to So or Tl,min via various CIs and ISCs were proposed.
基金supported by the science and technology project of state grid headquarters of China (SGLNDK00KJJS1700200)
文摘This paper analyzes the unified performance of energy detection(ED) of spectrum sensing(SS) over generalized fading channels in cognitive radios(CRs). The detective performance of SS will be obviously affected by fading channels among communication nodes, and ED has the advantages of fast implementation, no requirement of priori received information and low complexity, so it is meaningful to investigate ED over various fading channels. The probability density function(p.d.f.) of α-κ-μ distribution is derived to evaluate energy efficiency for sensing systems.The detection probability with Marcum-Q function has been derived and the close-form expressions with moment generating function(MGF) method are deduced to achieve SS.Furthermore, exact closed-form analytic expressions for average area under the receiver operating characteristics curve( AUC) also have been deduced to analyze the performance characteristics of ED over α-κ-μ fading channels.Besides, cooperative spectrum sensing(CSS) with diversity reception has been applied to improve the detection accuracy and mitigate the shadowed fading features with OR-rule. At last, the results show that the detection capacity of ED will be evidently affected by α-κ-μ fading channels, but appropriate channel parameters can improve sensing performance. In addition, the establishedED-fading pattern is approved by simulations,and it can significantly enhance the detection performance of proposed algorithms.
文摘The vibration of an elastic beam experiencing vortex-induced vibration is numerically analyzed employing a wake-oscillator model. The influence of the excited mode, the initial velocity, the shedding pulsation and the mass ratio on the energy transfer among modes and the vibration amplitude is determined. Multiple frequencies are detected, and the power spectral density of the beam tip time series is used to calculate the dominant frequency.
