We show that by scanning the frequency of a single mode infrared （IR） optical parametric oscillator （IR- OPO） laser to excite the molecular species of interest and fixing the frequency of a vacuum ultraviolet （VU...We show that by scanning the frequency of a single mode infrared （IR） optical parametric oscillator （IR- OPO） laser to excite the molecular species of interest and fixing the frequency of a vacuum ultraviolet （VUV） laser to photoionize the IR excited species, high-resolution IR spectra of polyatomic neutrals can be obtained with high sensitivity. The fact that this IR-VUV-photoion （IR-VUV-PI） method is based on VUV photoionization probe, and thus, allows the identification of the neutral IR absorber, makes it applicable for IR spectroscopy measurements of isotopemers, radicals, and clusters, which usually exist as impure samples. The highly resolved IR-VUV-PI measurements achieved using the single mode IR-OPO laser have made possible the selection of single rovibrational states of CH3X （X=Br and I）, C2H4, and C3H4 for VUV-pulsed field ionization-photoelectron （VUV-PFI-PE） measurements, resulting in rovibrationally resolved photoelectron spectra for these polyatomic molecules. These experiments show that the signal- to-noise ratios of the IR-VUV-PI and IR-VUV-PFI-PE spectra obtained by employing the high-resolution IR-OPO laser are significantly higher than those observed in previous IR-VUV-PI and IR-VUV-PFI-PE studies using a low-resolution IR-OPO laser. Further improvement in sensitivity of IR-VUV-PI and IR- VUV-PFI-PE measurements by using the collinear arrangement of IR-VUV lasers and molecular beam is discussed.展开更多
Emission in the X-ray and ultraviolet （200-300 nanometers） region of spectrum is found out during combustion of heterogeneous systems with the formation of condensed products, and pulses from microwave emission with...Emission in the X-ray and ultraviolet （200-300 nanometers） region of spectrum is found out during combustion of heterogeneous systems with the formation of condensed products, and pulses from microwave emission with short duration are recorded as well. Combustion of a Ti-B powder system showed that self-propagating high-temperature synthesis （SHS） is accompanied by two types of X-ray radiation. Radiation of the first type has the maximum quantum energy - 5 keV. It is supposed that this type is caused by micro-breakdowns due to the charge separation in combustion products. Runaway electrons and soft X-ray radiation are generated due to the concentration of electric field on microparticles during breakdown. Radiation of the second type has the quantum energy up to - 15 keV. It is supposed that it is caused by exoemission of photons. UV radiation in the region of 200-300 nm is recorded during SHS in different gases （He, Ar, N2）. This radiation is shown to have the highest intensity in helium at the pressure - 25 x 103 Pa.展开更多
We theoretically study the high-order harmonic generation （HHG） from a hydrogen atom in an intense few-cycle chirped fundamental laser in combination with an ultraviolet （uv） controlling pulse. The high-order harm...We theoretically study the high-order harmonic generation （HHG） from a hydrogen atom in an intense few-cycle chirped fundamental laser in combination with an ultraviolet （uv） controlling pulse. The high-order harmonic spectrum is calculated by solving the time-dependent Schr6dinger equation using the split-operator method. In our calculation, we present the difference of the high-order harmonic spectrum from one-dimensional （1D） model hydrogen atom and three-dimensional （3D） real hydrogen atom. We found that the plateau of the high-order harmonic generation from the 1D ease and 3D case are all extended effectively to Iv -k 35Up due to the presence of the chirped laser pulse and the HHG supercontinuum spectrum is generated by adding an ultraviolet controlling pulse at a proper time, but the efficiency of the HHC for 3D case is more higher at the near cut-off region than the 1D case. Therefore, the generation of the attosecond pulse by synthesizing the harmonics near cut-off region have some slight differences between 1D and 3D simulations. As a real 3D case study, we show that an isolated 18 as pulse with a bandwidth of 232.5 eV is generated directly by optmizing the combination laser fields.展开更多
文摘[目的]研究4℃条件贮藏过程中脉冲紫外线对新鲜葡萄抗氧化活性的影响。[方法]通过测定脉冲强光处理后4℃条件贮藏8 d过程中新鲜葡萄中DPPH·、O_2^-·、·OH和H2_O_2等的活性及还原能力来评价新鲜葡萄的抗氧化活性。[结果]脉冲紫外线处理可提高新鲜葡萄的抗氧化活性,且与辐照剂量有关,不同抗氧化活性提高程度有所不同。在贮藏过程中,各处理组的抗氧化活性均逐渐降低。当辐照剂量为1 350 m J/cm2时,葡萄的还原力及对DPPH·、O_2^-·、·OH和H_2O_2活性的清除率分别提高了8.5%、7.8%、9.2%、16.2%和33.4%。[结论]研究表明,脉冲紫外线可用来提高新鲜葡萄的品质。
文摘We show that by scanning the frequency of a single mode infrared （IR） optical parametric oscillator （IR- OPO） laser to excite the molecular species of interest and fixing the frequency of a vacuum ultraviolet （VUV） laser to photoionize the IR excited species, high-resolution IR spectra of polyatomic neutrals can be obtained with high sensitivity. The fact that this IR-VUV-photoion （IR-VUV-PI） method is based on VUV photoionization probe, and thus, allows the identification of the neutral IR absorber, makes it applicable for IR spectroscopy measurements of isotopemers, radicals, and clusters, which usually exist as impure samples. The highly resolved IR-VUV-PI measurements achieved using the single mode IR-OPO laser have made possible the selection of single rovibrational states of CH3X （X=Br and I）, C2H4, and C3H4 for VUV-pulsed field ionization-photoelectron （VUV-PFI-PE） measurements, resulting in rovibrationally resolved photoelectron spectra for these polyatomic molecules. These experiments show that the signal- to-noise ratios of the IR-VUV-PI and IR-VUV-PFI-PE spectra obtained by employing the high-resolution IR-OPO laser are significantly higher than those observed in previous IR-VUV-PI and IR-VUV-PFI-PE studies using a low-resolution IR-OPO laser. Further improvement in sensitivity of IR-VUV-PI and IR- VUV-PFI-PE measurements by using the collinear arrangement of IR-VUV lasers and molecular beam is discussed.
文摘Emission in the X-ray and ultraviolet （200-300 nanometers） region of spectrum is found out during combustion of heterogeneous systems with the formation of condensed products, and pulses from microwave emission with short duration are recorded as well. Combustion of a Ti-B powder system showed that self-propagating high-temperature synthesis （SHS） is accompanied by two types of X-ray radiation. Radiation of the first type has the maximum quantum energy - 5 keV. It is supposed that this type is caused by micro-breakdowns due to the charge separation in combustion products. Runaway electrons and soft X-ray radiation are generated due to the concentration of electric field on microparticles during breakdown. Radiation of the second type has the quantum energy up to - 15 keV. It is supposed that it is caused by exoemission of photons. UV radiation in the region of 200-300 nm is recorded during SHS in different gases （He, Ar, N2）. This radiation is shown to have the highest intensity in helium at the pressure - 25 x 103 Pa.
基金Supported by the National Natural Science Foundation of China under Grant Nos. 11044007 and 11047016the Specialized Research Fund for the Doctoral Program of Higher Education of China under Grant No. 20096203110001+1 种基金the Young Teachers Foundation of Northwest Normal University under Grant No. NWNU-LKQN-10-5Foundation of North west Normal University under Grant No. NWNU-KJCXGC-03-62
文摘We theoretically study the high-order harmonic generation （HHG） from a hydrogen atom in an intense few-cycle chirped fundamental laser in combination with an ultraviolet （uv） controlling pulse. The high-order harmonic spectrum is calculated by solving the time-dependent Schr6dinger equation using the split-operator method. In our calculation, we present the difference of the high-order harmonic spectrum from one-dimensional （1D） model hydrogen atom and three-dimensional （3D） real hydrogen atom. We found that the plateau of the high-order harmonic generation from the 1D ease and 3D case are all extended effectively to Iv -k 35Up due to the presence of the chirped laser pulse and the HHG supercontinuum spectrum is generated by adding an ultraviolet controlling pulse at a proper time, but the efficiency of the HHC for 3D case is more higher at the near cut-off region than the 1D case. Therefore, the generation of the attosecond pulse by synthesizing the harmonics near cut-off region have some slight differences between 1D and 3D simulations. As a real 3D case study, we show that an isolated 18 as pulse with a bandwidth of 232.5 eV is generated directly by optmizing the combination laser fields.
