利用ATR单点全反射技术以及XPS(X光电子能谱 )测试方法对聚苯乙烯 聚二甲基硅氧烷嵌段 (PS b PDMS)和接枝共聚物 (PS g PDMS)进行了研究 ,发现聚合物膜表面存在着有机硅富集层 ,PS b PDMS有机硅表面富集程度要高于PS g PDMS ,而且不同...利用ATR单点全反射技术以及XPS(X光电子能谱 )测试方法对聚苯乙烯 聚二甲基硅氧烷嵌段 (PS b PDMS)和接枝共聚物 (PS g PDMS)进行了研究 ,发现聚合物膜表面存在着有机硅富集层 ,PS b PDMS有机硅表面富集程度要高于PS g PDMS ,而且不同溶解度参数的成膜溶剂和不同极性的成膜介质对有机硅富集程度有一定的影响 .展开更多
A modified fractal growth model based on the deposition, diffusion, and aggregation (DDA) with cluster rotation is presented to simulate two-dimensional fractal aggregation on liquid surfaces. The mobility (including ...A modified fractal growth model based on the deposition, diffusion, and aggregation (DDA) with cluster rotation is presented to simulate two-dimensional fractal aggregation on liquid surfaces. The mobility (including diffusion, and rotation) of clusters is related to its mass, which is given by D-m = D-0s(-gamma D) and theta(m) = theta(0)s (-gamma theta,) respectively. We concentrate on revealing the details of the influence of deposition flux F, cluster diffusion factor gamma(D) and cluster rotation factor gamma(B) on the dynamics of fractal aggregation on liquid surfaces. It is shown that the morphologies of clusters and values of cluster density and fractal dimension depend dramatically on the deposition flux and migration factors of clusters.展开更多
文摘利用ATR单点全反射技术以及XPS(X光电子能谱 )测试方法对聚苯乙烯 聚二甲基硅氧烷嵌段 (PS b PDMS)和接枝共聚物 (PS g PDMS)进行了研究 ,发现聚合物膜表面存在着有机硅富集层 ,PS b PDMS有机硅表面富集程度要高于PS g PDMS ,而且不同溶解度参数的成膜溶剂和不同极性的成膜介质对有机硅富集程度有一定的影响 .
文摘A modified fractal growth model based on the deposition, diffusion, and aggregation (DDA) with cluster rotation is presented to simulate two-dimensional fractal aggregation on liquid surfaces. The mobility (including diffusion, and rotation) of clusters is related to its mass, which is given by D-m = D-0s(-gamma D) and theta(m) = theta(0)s (-gamma theta,) respectively. We concentrate on revealing the details of the influence of deposition flux F, cluster diffusion factor gamma(D) and cluster rotation factor gamma(B) on the dynamics of fractal aggregation on liquid surfaces. It is shown that the morphologies of clusters and values of cluster density and fractal dimension depend dramatically on the deposition flux and migration factors of clusters.
