Noble metals have been widely used as heterogeneous catalysts because they exhibit high activity and selectivity for many reactions of both academic and industrial interest.The introduction of light atomic species(e.g...Noble metals have been widely used as heterogeneous catalysts because they exhibit high activity and selectivity for many reactions of both academic and industrial interest.The introduction of light atomic species(e.g.,H,B,C,and N)into noble metal lattices plays an important role in optimizing catalytic performance by modulating structural and electronic properties.In this review,we present a general overview of the recent advances in the modification of noble metals with light alloying elements for various catalytic reactions,particularly for energy‐related applications.We summarize the types,location,concentration,and ordering degree of light atoms as major factors in the performance of noble metal‐based catalysts,with emphasis on how they can be rationally controlled to promote activity and selectivity.We then summarize the synthetic strategies developed to incorporate light elements and highlight the theoretical and experimental methods for understanding the alloying effects.We further focus on the wide usage of noble metal‐based catalysts modified with different light alloying atoms and attempt to correlate the structural features with their catalytic performances.Finally,we discuss current challenges and future perspectives regarding the development of highly efficient noble metal‐based catalysts modified with light elements.展开更多
An approximation method based on Regge behavior is presented. This new methodrelates the reduced cross section derivative and the structure function Regge behavior at low x.With the use of this approximation method, t...An approximation method based on Regge behavior is presented. This new methodrelates the reduced cross section derivative and the structure function Regge behavior at low x.With the use of this approximation method, the C and λ parameters are calcuiated from the HERAreduced cross section data taken at low-x. Also, we calculate the structure functions F_2(x, Q~2)even for low-x values, which have not been investigated. To test the validity of calculatedstructure functions, we find the gluon distribution function in the Leading order approximationbased on Regge behaviour of structure function and compare to the NLO QCD fit to H1 data and NLOparton distribution function.展开更多
文摘Noble metals have been widely used as heterogeneous catalysts because they exhibit high activity and selectivity for many reactions of both academic and industrial interest.The introduction of light atomic species(e.g.,H,B,C,and N)into noble metal lattices plays an important role in optimizing catalytic performance by modulating structural and electronic properties.In this review,we present a general overview of the recent advances in the modification of noble metals with light alloying elements for various catalytic reactions,particularly for energy‐related applications.We summarize the types,location,concentration,and ordering degree of light atoms as major factors in the performance of noble metal‐based catalysts,with emphasis on how they can be rationally controlled to promote activity and selectivity.We then summarize the synthetic strategies developed to incorporate light elements and highlight the theoretical and experimental methods for understanding the alloying effects.We further focus on the wide usage of noble metal‐based catalysts modified with different light alloying atoms and attempt to correlate the structural features with their catalytic performances.Finally,we discuss current challenges and future perspectives regarding the development of highly efficient noble metal‐based catalysts modified with light elements.
文摘An approximation method based on Regge behavior is presented. This new methodrelates the reduced cross section derivative and the structure function Regge behavior at low x.With the use of this approximation method, the C and λ parameters are calcuiated from the HERAreduced cross section data taken at low-x. Also, we calculate the structure functions F_2(x, Q~2)even for low-x values, which have not been investigated. To test the validity of calculatedstructure functions, we find the gluon distribution function in the Leading order approximationbased on Regge behaviour of structure function and compare to the NLO QCD fit to H1 data and NLOparton distribution function.
