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二肽类双酰胺导向农药的合成与韧皮部输导性探索 被引量:1
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作者 吴必俊 孙兵 王振锋 《化工管理》 2023年第35期139-141,共3页
文章探索了二肽类氯虫苯甲酰胺偶合物的合成路线,形成了不同偶合物和不同二肽结构的导向农药。再以蓖麻幼苗为实验对象,检测目标合成物在其韧皮部的输导性,并且将无二肽结构的氯虫苯甲酰胺作为对照组。最后制作苋菜样本,使用合成农药对... 文章探索了二肽类氯虫苯甲酰胺偶合物的合成路线,形成了不同偶合物和不同二肽结构的导向农药。再以蓖麻幼苗为实验对象,检测目标合成物在其韧皮部的输导性,并且将无二肽结构的氯虫苯甲酰胺作为对照组。最后制作苋菜样本,使用合成农药对其进行浸泡,观察目标化合物杀灭甜菜夜蛾幼虫和小菜蛾幼虫的能力。结果显示,二肽类双酰胺导向农药在韧皮部具有输导性,但氯虫苯甲酰胺无此特性。 展开更多
关键词 二肽类双酰胺导向农药 合成方法 韧皮部输导性
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济阳坳陷埕岛地区明化镇组断层输导性分析与综合评价 被引量:1
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作者 刘菊 《中国海上油气》 CAS CSCD 北大核心 2014年第6期28-31,36,共5页
在精细分析济阳坳陷埕岛地区断裂分布及发育特征的基础上,利用断层纵向断切层位、断层活动性分析及断面压力分析等3种方法对该地区断层的输导性进行了定性、定量分析。最终结合3种方法的分析结果对研究区内断层的输导性进行了综合评价,... 在精细分析济阳坳陷埕岛地区断裂分布及发育特征的基础上,利用断层纵向断切层位、断层活动性分析及断面压力分析等3种方法对该地区断层的输导性进行了定性、定量分析。最终结合3种方法的分析结果对研究区内断层的输导性进行了综合评价,优选出了埕岛地区沟通明化镇组的有效油源断层,这些断层组成了明化镇组成藏有效油源输导网,并与明化镇组油气分布相匹配,证实了该评价方法的有效性。 展开更多
关键词 断层输导性 断层切至层位 断层活动 断面压力分析 综合评价 明化镇组 埕岛地区 济阳坳陷
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吩嗪-1-羧酸双酰肼衍生物的合成、杀菌活性及韧皮部的输导性研究 被引量:4
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作者 柳豪 余林花 +4 位作者 熊志鹏 张敏 李俊凯 徐志红 吴清来 《农药学学报》 CAS CSCD 北大核心 2017年第3期290-297,共8页
天然产物吩嗪-1-羧酸(PCA,申嗪霉素)及其衍生物吩嗪-1-甲酰肼具有独特的化学结构和优良的杀菌等生物活性,但均没有韧皮部输导性。本文以具有抑菌活性的吩嗪-1-羧酸和具有韧皮部输导性的马来酰肼为先导化合物,将马来酰肼中的双酰肼结构... 天然产物吩嗪-1-羧酸(PCA,申嗪霉素)及其衍生物吩嗪-1-甲酰肼具有独特的化学结构和优良的杀菌等生物活性,但均没有韧皮部输导性。本文以具有抑菌活性的吩嗪-1-羧酸和具有韧皮部输导性的马来酰肼为先导化合物,将马来酰肼中的双酰肼结构引入到吩嗪-1-羧酸中,设计、合成了17个新化合物,其结构均经过核磁共振氢谱、高分辨质谱及X-射线单晶衍射分析确证。初步生物活性测试表明:大部分目标化合物在50 mg/L下对水稻纹枯病菌Thanatephorus cucumeris表现出中等偏上的抑制活性,其中化合物6m的抑制率达92%。但输导性研究结果显示,目标化合物没有明显的韧皮部输导性。 展开更多
关键词 吩嗪-1-羧酸(申嗪霉素) 马来酰肼 双酰肼 合成 杀菌活 韧皮部输导性
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不同培养条件下甲霜灵在蓖麻幼苗韧皮部的输导性 被引量:1
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作者 余林花 余迪雅 +5 位作者 张敏 李旭军 朱祥 徐志红 吴清来 李俊凯 《农药学学报》 CAS CSCD 北大核心 2018年第4期500-505,共6页
甲霜灵是一种能通过植物叶片吸收后在韧皮部向下传导的杀菌剂,为了探明其在韧皮部的传导规律,以蓖麻幼苗为模式植物,通过改变试验过程培养液中甲霜灵含量、pH值以及培养的温度、时间及光照等因子,采用气相色谱-质谱联用(GC-MS)方法,... 甲霜灵是一种能通过植物叶片吸收后在韧皮部向下传导的杀菌剂,为了探明其在韧皮部的传导规律,以蓖麻幼苗为模式植物,通过改变试验过程培养液中甲霜灵含量、pH值以及培养的温度、时间及光照等因子,采用气相色谱-质谱联用(GC-MS)方法,检测了不同培养条件下蓖麻幼苗韧皮部渗出液中甲霜灵的含量。结果表明:光照对甲霜灵在蓖麻幼苗韧皮部中的输导性无显著影响;当培养液中甲霜灵质量浓度为400 mg/L时,其在蓖麻幼苗韧皮部中输导量最大;当培养液pH值为5.5时,甲霜灵在蓖麻幼苗韧皮部中输导量最大;当培养温度为28℃时培养效果最佳,温度过高或过低均会使甲霜灵在蓖麻幼苗韧皮部中的输导量减少;培养3 h以上,蓖麻幼苗韧皮部渗出液中甲霜灵的含量显著高于前2 h渗出液中甲霜灵的含量。该研究优化了蓖麻幼苗获得药剂最大吸收时的适宜培养条件,为检测其他未知化合物在植株韧皮部中的输导性提供了参考。 展开更多
关键词 培养条件 甲霜灵 气相色谱-质谱联用(GC-MS) 蓖麻 韧皮部输导性
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东濮凹陷浅层砂岩的微观输导性能及其油气地质意义 被引量:2
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作者 张丽霞 范昌育 《沉积学报》 CAS CSCD 北大核心 2011年第4期793-797,共5页
砂体作为东濮凹陷浅层发育的主要输导体之一,其微观输导特征,决定了输导性能的优劣。利用场发射环境扫描电镜下的Scandium孔径测量软件,从微观尺度,较为系统地测量了东濮凹陷浅层砂体的孔隙、喉道大小,并总结了它们在纵向上的分布特征,... 砂体作为东濮凹陷浅层发育的主要输导体之一,其微观输导特征,决定了输导性能的优劣。利用场发射环境扫描电镜下的Scandium孔径测量软件,从微观尺度,较为系统地测量了东濮凹陷浅层砂体的孔隙、喉道大小,并总结了它们在纵向上的分布特征,分析了不同层段砂岩的输导性能及其纵向变化,这为研究孔隙结构和砂岩输导性能提供了一种新的方法。研究认为,喉道宽度和孔喉比是影响东濮凹陷浅层砂体输导性的主要因素,在层位上从深到浅,由沙一段→东营组→馆陶组输导性能越来越好,再向上至明化镇组时又变差。据此分析,如果满足油气运移、成藏的其它条件,浅层油气极有可能运移至馆陶组聚集、成藏。 展开更多
关键词 微观输导性 孔隙结构 孔喉比 浅层 东濮凹陷
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葡萄糖基-氟虫腈偶合物、氟虫腈、噻虫嗪和阿维菌素在大豆木质部的输导性比较
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作者 李豫丰 解云 徐汉虹 《华南农业大学学报》 CAS CSCD 北大核心 2016年第2期84-88,共5页
【目的】通过比较葡萄糖基-氟虫腈偶合物(GTF)与氟虫腈、噻虫嗪和阿维菌素在大豆Glycine max植株内的分布差异,评价4种农药的木质部输导性。【方法】选取大豆幼苗作为供试植物,采用药液浸根的处理方法,研磨提取后利用高效液相色谱法(... 【目的】通过比较葡萄糖基-氟虫腈偶合物(GTF)与氟虫腈、噻虫嗪和阿维菌素在大豆Glycine max植株内的分布差异,评价4种农药的木质部输导性。【方法】选取大豆幼苗作为供试植物,采用药液浸根的处理方法,研磨提取后利用高效液相色谱法(HPLC)检测根、茎、叶3部分药物含量,以地上部分输导量评价4种农药木质部输导性。【结果】GTF具有优越的木质部输导性,进入大豆后能较为均匀地分布;噻虫嗪木质部输导性高效,向顶分布明显,短时间即达到饱和;氟虫腈大量在根部积累,仅具有较弱的木质部输导性;阿维菌素能渗透进入大豆根部并积累,但无法向上转运,不具有木质部输导性。【结论】糖基的引入能够显著改善氟虫腈的木质部输导性。对杀虫剂进行糖基化修饰为内吸性农药开发提供了新的思路。 展开更多
关键词 葡萄糖基-氟虫腈偶合物 内吸农药 木质部输导性 高效液相色谱
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断层输导封闭性能及其油气运移机理研究现状 被引量:6
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作者 刘玉祥 张金功 +1 位作者 王永诗 郝雪峰 《兰州大学学报(自然科学版)》 CAS CSCD 北大核心 2008年第S1期54-57,共4页
断层是油气运移的重要通道,同时断层圈闭也是油气圈闭的重要类型.对断层泥、断层非渗透性物质(沥青质、胶结物)、断层两盘的岩性和产状对接关系、断层面应力特征、断层活动性、断层"地震泵"的抽吸作用、断层面上油气运移路径... 断层是油气运移的重要通道,同时断层圈闭也是油气圈闭的重要类型.对断层泥、断层非渗透性物质(沥青质、胶结物)、断层两盘的岩性和产状对接关系、断层面应力特征、断层活动性、断层"地震泵"的抽吸作用、断层面上油气运移路径、油气沿断层走向运移、油气从断层向储集层的运移等对断层输导、封闭性能的影响进行了研究分析,并指出其存在的问题:油气在断层走向上的运移机理;断层中砂泥岩裂缝的发育对油气输导、封闭性能的影响. 展开更多
关键词 断裂 输导性 运移 油气
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新型杀菌剂苯噻菌酯的抑菌活性及生物学特性 被引量:6
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作者 徐从英 侯毅平 +2 位作者 王建新 陈长军 周明国 《农药学学报》 CAS CSCD 北大核心 2014年第6期667-672,共6页
报道了新型Qo I类杀菌剂苯噻菌酯(试验代号Y5247)的生物学特性。在含50μg/m L水杨肟酸(SHAM)旁路氧化专化性抑制剂的AEA培养基上,该杀菌剂抑制水稻纹枯病菌、稻瘟病菌、油菜菌核病菌及草莓灰霉病菌菌丝生长的有效中浓度(EC50)分别为0.... 报道了新型Qo I类杀菌剂苯噻菌酯(试验代号Y5247)的生物学特性。在含50μg/m L水杨肟酸(SHAM)旁路氧化专化性抑制剂的AEA培养基上,该杀菌剂抑制水稻纹枯病菌、稻瘟病菌、油菜菌核病菌及草莓灰霉病菌菌丝生长的有效中浓度(EC50)分别为0.004、0.009、0.016和0.023μg/m L;其抑制辣椒炭疽病菌和草莓灰霉病菌孢子萌发的EC50值分别为0.448和0.019μg/m L。苯噻菌酯对防治小麦白粉病具有保护和治疗作用,EC50值分别为0.991和1.823μg/m L。其在小麦叶片上内吸输导性差,但具有一定的渗透性、良好的粘着性、耐雨水冲刷和较长的持效期。用有效成分为25μg/m L的苯噻菌酯药液喷雾处理的麦苗,14 d后接种小麦白粉病菌,其防效仍达72.48%。 展开更多
关键词 苯噻菌酯 小麦白粉病菌 内吸输导性 持效期
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渤海湾盆地埕岛东斜坡断—砂组合样式及其对油气富集的控制作用
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作者 张在振 曾溅辉 +5 位作者 廖文毫 张本华 王志伟 武群虎 崔虎旺 乔俊程 《石油科学通报》 CAS 2023年第6期707-723,共17页
断层与砂体是埕岛东斜坡东营组主要的油气输导要素。为了探究断-砂组合输导条件控制下油气运移与富集规律,本文基于地震资料精细解释和砂体RMS属性分析,首先划分了埕岛东斜坡东营组的断-砂组合样式,然后应用砂岩输导层相对输导指数RT_(i... 断层与砂体是埕岛东斜坡东营组主要的油气输导要素。为了探究断-砂组合输导条件控制下油气运移与富集规律,本文基于地震资料精细解释和砂体RMS属性分析,首先划分了埕岛东斜坡东营组的断-砂组合样式,然后应用砂岩输导层相对输导指数RT_(i)、断层侧向输导指数F_(LSI)对断-砂组合输导性进行了定量评价,最后结合HMIE指数和Trinity油气运移数值模拟,分析了断-砂组合样式对油气运聚成藏的控制作用。研究表明,埕岛东斜坡断-砂组合样式可以划分为顺向型、反向型和主次复合型3大类。断-砂组合对油气富集的控制作用主要体现在:(1)断-砂组合输导性控制了油气运聚范围、层位及规模。当RT_(i)>0.15时,斜坡区油气的聚集程度与RT_i成正相关,当F_(LSI)≥0.45时,断阶区油气易侧向封堵成藏;(2)断-砂组合的多样性、通源性及输导性控制了油气优势运移路径。研究区主要存在由洼陷区向胜海10南断层附近,向胜海8南断层附近以及向断阶区的3条优势运移路径;(3)顺向型主要起阶梯式输导油气作用,反向型易侧向封堵油气成藏,主次复合型则对油气起着先分流再富集的作用。不同断-砂组合样式控制了油气富集模式,具有“分区控制、垂向分异、多层富集”的成藏特征。 展开更多
关键词 断—砂组合 输导性 油气富集 成藏模式 埕岛东斜坡
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从内部结构出发探讨断裂控藏机理及模式:以珠江口盆地珠一坳陷为例 被引量:14
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作者 姜大朋 王文勇 +2 位作者 高翔 张超 许新明 《地质科技情报》 CAS CSCD 北大核心 2016年第4期91-97,共7页
断层是珠一坳陷油气成藏重要的控制因素。从断裂带内部结构出发,通过认识断层核及破碎带特征和差异性,进而分析断层输导与封闭的机制。综合分析表明:①断移期与过渡期断层输导油气的机制有所不同,断侈期主要沿滑动面和伴生缝以“地... 断层是珠一坳陷油气成藏重要的控制因素。从断裂带内部结构出发,通过认识断层核及破碎带特征和差异性,进而分析断层输导与封闭的机制。综合分析表明:①断移期与过渡期断层输导油气的机制有所不同,断侈期主要沿滑动面和伴生缝以“地震泵”形式垂向输导,侧向分流受控于断层末端未被断穿的厚层泥岩;过渡期主要沿破碎带中的诱导裂缝以浮力流或渗流的方式垂向输导,侧向分流在多套泥岩的遮挡下均会产生分流。②断层封闭又分为垂向封闭和侧向封闭。垂向封闭首先取决于泥岩塑性变形的连续性,珠一坳陷新近系断层错断泥岩的SSF值为5,当SSF值小于5时,泥岩连续垂向封闭;当SSF值大于5时,只有当断层核及破碎带中的通道均无法连通时,垂向才封闭。侧向封闭包括对接封闭和断层岩封闭2种形式.对接封闭依赖于泥岩的塑性变形;断层岩封闭取决于断层岩的岩性、厚度及物性。在断裂带内部结构和断裂控藏机制认识的基础上,总结了珠一坳陷4种(Ⅰ~Ⅳ)断裂控藏的模式,分别为上盘输导上盘成藏型、下盘输导下盘成藏型、侧向遮挡成藏型与组合控藏型,并通过实例进行了详细解析。综合认为,Ⅰ型为珠一坳陷最有利的成藏类型.Ⅲ型和Ⅳ型其次,Ⅱ型发现较少。 展开更多
关键词 断裂控藏 断裂带内部结构 珠一坳陷 输导性 封闭
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Research on coning compensation algorithms for SINS of angular rate input 被引量:1
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作者 魏小莹 付振宪 邓正隆 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2007年第4期541-544,共4页
To compensate the coning error of Strap-down Inertial Navigation Systems (SINS) under high dynamic angular motion, many rotation vector algorithms have been developed using angle increments information. However, most ... To compensate the coning error of Strap-down Inertial Navigation Systems (SINS) under high dynamic angular motion, many rotation vector algorithms have been developed using angle increments information. However, most SINS use angular rate gyros. Aimed at this problem, 18 algorithms are derived based on analysis of the conventional algorithms, and corresponding coning error expressions are given. At last simulation is made which indicates that the new algorithms have much higher precision. 展开更多
关键词 angular rate input SINS coning compensation algorithms error analysis
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Anomalous Transport Characteristics of High Temperature Superconductors and Josephson Currents
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作者 LIANGFang-Ying LIZuo-Hong 《Communications in Theoretical Physics》 SCIE CAS CSCD 2002年第3期379-384,共6页
The transport characteristics of high temperature superconductor current and Josephson current is inves-tigated in the framework of the modified time-dependent Ginzburg-Landau model and the Lawrence-Doniach model.We e... The transport characteristics of high temperature superconductor current and Josephson current is inves-tigated in the framework of the modified time-dependent Ginzburg-Landau model and the Lawrence-Doniach model.We evaluated the vortex equation and found that the signs of the high temperature superconductor current and theJosephson current can reverse. Some explicit expressions for different cases are derived, which accord with experimentaldata. 展开更多
关键词 SUPERCONDUCTIVITY JUNCTION Josephson current
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Influence of PVK:NPB hole transporting layer on the characteristics of organic light-emitting devices
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作者 WEN Wen YU Jun-sheng LI Lu MA Tao TANG Xiao-qing JIANG Ya-dong 《Optoelectronics Letters》 EI 2008年第3期201-204,共4页
A doping system consisting of NPB and PVK is employed as a composite hole transporting layer (CHTL). By adjusting the component ratio of the doping system, a series of devices with different concentration proportion... A doping system consisting of NPB and PVK is employed as a composite hole transporting layer (CHTL). By adjusting the component ratio of the doping system, a series of devices with different concentration proportion of PVK : NPB are constracted. The result shows that doping concentration of NPB enhances the competence of hole transporting ability, and modifies the recombination region of charge as well as affects the surface morphology of doped film. Optimum device with a maximum brightness of 7852 cd/m^2 and a power efficiency of 1.75 lm/W has been obtained by choosing a concentration proportion of PVK : NPB at 1:3. 展开更多
关键词 光散射 半导体 传输过程
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Transport Properties of Si and Ge Liquid Semiconductor Metals
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作者 Aditya M.Vora 《Communications in Theoretical Physics》 SCIE CAS CSCD 2009年第3期550-554,共5页
In the present article, we study the electrical resistivity ρ, the thermoelectric power (TEP) α, thermal conductivity σ, Knight-Shifts and temperature coefficient of the Knight-Shifts of the liquid Si and Ge usin... In the present article, we study the electrical resistivity ρ, the thermoelectric power (TEP) α, thermal conductivity σ, Knight-Shifts and temperature coefficient of the Knight-Shifts of the liquid Si and Ge using the well known model potential for the first time. The structure factor used in the present work is derived from the Percus-Yevick (PY) theory. Various local field correction functions are used to study the screening influence. The present results of resistivity are found in qualitative agreement with available experimental and theoretical whenever exists. 展开更多
关键词 PSEUDOPOTENTIAL electrical resistivity thermoelectric power Knight Shift PY theory local field correction functions
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Fabrication of Highly Conductive Pd Nanowires using PDMS Transfer Method on DNA Scaffolds through Ethanol-Reduction
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作者 Hong-bing Cai Zhen-xing Wang +2 位作者 Jin-yang Liu Kun Zhang Xiao-ping Wang 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2013年第5期607-611,I0004,共6页
We have developed a simple, productive, and ettectlve poly(cllmetnysltoxane) rranu fer method to fabricate highly conductive Pd nanowires following DNA scaffolds on various substrates, based on ethanolreduction at l... We have developed a simple, productive, and ettectlve poly(cllmetnysltoxane) rranu fer method to fabricate highly conductive Pd nanowires following DNA scaffolds on various substrates, based on ethanolreduction at low temperature. Pd nanoparticles were selectively deposited and confined onto the DNA templates on a PDMS sheet to form Pd nanowires and then the nanowires were transferred to other various substrates with a low occurrence of par asitic nanoparticles. The structure, morphology and the conductance of Pd nanowires were characterized with transmission electron microscopy, field emission scanning electron mi croscopy, and electrical transport measurement, respectively. Moreover, the growth process of the Pd nanowires was investigated by varying the incubation time and reaction temper ature. The present strategy provides a new method to fabricate extremely dense, highly conductive, and well aligned Pd nanowires on various substrates, which make it promising for building nanosensors and nanoelectronic devices. 展开更多
关键词 Pd nanowires DNA template Poly(dimethysiloxane) transfer Ethanol reduc-tion
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Novel Synthesis Method of Nonst0ichiometric Na2-xlrO3 Crystal Structure, Transport and Magnetic Properties
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作者 Katharina Rolfs Ekaterina Pomjakushina +1 位作者 Denis Sheptyakov Kazimierz Conder 《Journal of Chemistry and Chemical Engineering》 2016年第4期153-160,共8页
Transition metal oxides with 4d or 5d metals are of great interest due to the competing interactions, of the Coulomb repulsion and the itineracy of the d-electrons, opening a possibility of building new quantum ground... Transition metal oxides with 4d or 5d metals are of great interest due to the competing interactions, of the Coulomb repulsion and the itineracy of the d-electrons, opening a possibility of building new quantum ground states. Particularly the 5d metal oxides containing Iridium have received significant attention within the last years, due to their unexpected physical properties, caused by a strong spin orbit coupling observed in It(IV). A prominent example is the Mott-insulator Sr2IrO4. Another member of this family, the honeycomb lattice compound Na2IrO3, also being a Mott-insulator having, most probably, a Kitaev spin liquid ground state. By deintercalating sodium from Na2IrO3, the authors were able to synthesize a new honeycomb lattice compound with more than 50% reduced sodium content. The reduction of the sodium content in this layered compound leads to a change of the oxidation state of iridium from + IV to + V/+ VI and a symmetry change from C2/c to P-3. This goes along with significant changes of the physical properties. Besides the vanishing magnetic ordering at 15 K, also the transport properties changes and instead insulating semiconducting properties are observed. 展开更多
关键词 Strongly correlated electron systems iridates OXIDATION neutron diffraction
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咯菌腈羧酸衍生物内吸传导性及对香蕉枯萎病的防效测定 被引量:6
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作者 吴瀚翔 陈志彬 +3 位作者 肖春霞 赖多 姚光凯 徐汉虹 《植物保护学报》 CAS CSCD 北大核心 2021年第4期789-797,共9页
为研发用于防治香蕉枯萎病的维管组织导向杀菌剂,基于植物韧皮部"离子井"效应对非内吸杀菌剂咯菌腈进行弱酸化结构修饰,在蓖麻模型上完成韧皮部输导性筛选和机制验证,通过盆栽试验研究咯菌腈羧酸衍生物在香蕉植株上的输导分布... 为研发用于防治香蕉枯萎病的维管组织导向杀菌剂,基于植物韧皮部"离子井"效应对非内吸杀菌剂咯菌腈进行弱酸化结构修饰,在蓖麻模型上完成韧皮部输导性筛选和机制验证,通过盆栽试验研究咯菌腈羧酸衍生物在香蕉植株上的输导分布,并测定衍生物对香蕉枯萎病的防效。结果表明:羧酸基团引入使咯菌腈衍生物在蓖麻幼苗上表现出韧皮部输导性,证明存在pH依赖的"离子井"效应机制;盆栽试验结果显示,衍生物1a在被叶片吸收后能向下传递到香蕉植株球茎和根部,并能够降解释放出咯菌腈,对香蕉枯萎病的防效为54.5%,显著高于咯菌腈原药处理组的防效6.5%。表明基于韧皮部"离子井"效应的结构修饰是香蕉维管组织导向杀菌剂研发的有效途径。 展开更多
关键词 化学防治 尖孢镰刀菌 导向农药 韧皮部 输导性
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Pervoskite-type Bao.sSro.sAl0.1Fe0.9O3-δ as Intermediate-Temperature Solid Oxide Fuel Cell Cathode 被引量:1
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作者 Yun Gan Kui Xie 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2012年第5期605-608,I0004,共5页
A cobalt-free perovskite-type Ba0.5Sr0.5A10.1Fe0.9O3-δ (BSAF) chemically studied as solid oxide fuel cell (SOFC) cathode. The ductivity, and electrode polarizations in symmetrical cell based is developed and elec... A cobalt-free perovskite-type Ba0.5Sr0.5A10.1Fe0.9O3-δ (BSAF) chemically studied as solid oxide fuel cell (SOFC) cathode. The ductivity, and electrode polarizations in symmetrical cell based is developed and electro- structures, electrical con- on mixed ion conducting electrolyte were investigated, respectively. The temperature dependence of conductivity of BSAF in air shows a typical semiconductor behavior with positive temperature coefficient up to 450℃ where the conductivity reaches 14.0 S/cm while above this temperature the negative temperature coefficient dominates the total conductivity. Electrochemical charac- terizations show desirable polarization resistance of BSAF cathode in a symmetric cell based on mixed ion conducting electrolyte at 650-700℃, A single SOFC with BSAF cathode shows OCV of 1.0 V and maximum output of 420 mW/cm2 at 700 ℃ with humidified hydrogen fuel and static air oxidant. 展开更多
关键词 Solid oxide fuel cell PEROVSKITE CATHODE Cobalt-free Mixed ionic conductor
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Influences of a Side-Coupled Triple Quantum Dot on Kondo Transport Through a Quantum Dot
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作者 江兆潭 杨彦楠 秦志杰 《Communications in Theoretical Physics》 SCIE CAS CSCD 2010年第11期925-932,共8页
Kondo transport properties through a Kondo-type quantum dot (QD) with a side-coupled triple-QD structure are systematically investigated by using the non-equilibrium Green's function method. We firstly derive the f... Kondo transport properties through a Kondo-type quantum dot (QD) with a side-coupled triple-QD structure are systematically investigated by using the non-equilibrium Green's function method. We firstly derive the formulae of the current, the linear conductance, the transmission coefficient, and the local density of states. Then we carry out the analytical and numerical studies and some universal conductance properties are obtained. It is shown that the number of the conductance valleys is intrinsically determined by the side-coupled QDs and at most equal to the number of the QDs included in the side-coupled structure in the asymmetric limit. In the process of forming the conductance valleys, the side-coupled QD system plays the dominant role while the couplings between the Kondo-type QD and the side-coupled structure play the subsidiary and indispensable roles. To testify the validity of the universal conductance properties, another different kinds of side-coupled triple-QD structures are considered. It should be emphasized that these universal properties axe applicable in understanding this kind of systems with arbitrary many-QD side structures. 展开更多
关键词 Kondo effect quantum dots
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Finite Element Analysis of the Dynamic Behaviour of Transmission Line Conductors Using MATLAB
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作者 Evans E. Ojo Sergey Shindin 《Journal of Mechanics Engineering and Automation》 2014年第2期142-148,共7页
The dynamic behaviour of power line cables have been a source of interest to researchers ever since the phenomenon was first noticed in the 1920s. Conductor oscillation is mostly caused by the dynamic forces of nature... The dynamic behaviour of power line cables have been a source of interest to researchers ever since the phenomenon was first noticed in the 1920s. Conductor oscillation is mostly caused by the dynamic forces of nature such as wind loading. This imposes a periodic force on the conductors which is highly undesirable. It is therefore important for engineers to account for the possible effect of the wind loading when designing the power line. Investigations have shown that modeling the exact dynamic behaviour of a conductor is very difficult. Based on this fact, getting the exact analytical solution to conductor vibration is difficult, which is almost impossible, hence the numerical approximation becomes an option. This paper presents the developed finite element method used to analyse the dynamic behaviour of transmission line conductors. The developed FEM (finite element method) is implemented on MATLAB. The numerical analysis using MATLAB that is presented in this paper is used to simulate the response of the conductor when subjected to external loading in the time domain. The simulation is used to analyse the transverse vibration of the conductor. The formulation of the stiffness matrix and load vector is done and the results obtained are used to evaluate the conductor's internal energy dissipation. This finite element solution is compared with the results documented in literature. This numerical simulation is also used to investigate the effects of varying the axial tension on energy dissipation within the strands. Hence, this evolved in physically appropriate energy characterization process that can be used to evaluate the conductor self-damping with respect to line contact. 展开更多
关键词 Conductor mechanical vibration analytical model finite element method MATLAB software line contact stiffnessmatrix self-damping.
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