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Kinetic and Thermodynamic Studies of Acid Scarlet 3R Adsorption onto Low-cost Adsorbent Developed from Sludge and Straw 被引量:2
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作者 任晓莉 杨玲敏 刘敏 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2014年第2期208-213,共6页
A low-cost adsorbent was prepared from sludge and straw by pyrolysis in a dried state with the surface area of the adsorbent of 829.49 ma. g-l, micropore volume of 0.176 cm2·g-1 and average pore radius of 5.0 nm.... A low-cost adsorbent was prepared from sludge and straw by pyrolysis in a dried state with the surface area of the adsorbent of 829.49 ma. g-l, micropore volume of 0.176 cm2·g-1 and average pore radius of 5.0 nm. The kinetic, equilibrium isotherm and thermodynamic characteristics of trisodium 1-(1-naphthylazo)-2-hydroxynaphthalene- 4',6,8-trisulphonate (acid scarlet 3R) onto the adsorbent from sludge and straw were investigated. The results indicated that the pseudo second order adsorption was the predominant adsorption mechanism of acid scarlet 3R. Thus, the adsorption phenomenon was suggested as a chemical process. The adsorption data were fitted better with Langmuir model than Freundlich model, indicating that the adsorption of acid scarlet 3R belonged to the monolayer adsorption and mainly occurred in micropores. 展开更多
关键词 KINETIC THErMODYNAMIC acid scarlet 3r ADSOrBENT SLUDGE STrAW
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Fe_2O_3/Al_2O_3催化剂制备及催化降解酸性染料废水 被引量:10
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作者 吕树祥 魏佳 +1 位作者 胡炀 邱元来 《工业水处理》 CAS CSCD 北大核心 2009年第4期27-30,共4页
以γ-Al2O3为载体,采用浸渍-焙烧法制备了Fe2O3/Al2O3催化剂,并将其用于催化降解模拟酸性大红-3R染料废水。对于质量浓度为1 000 mg/L的高浓度酸性大红-3R染料废水,最佳的处理工艺条件为:温度60℃、pH=3.0、H2O2投加质量浓度9.4 g/L、... 以γ-Al2O3为载体,采用浸渍-焙烧法制备了Fe2O3/Al2O3催化剂,并将其用于催化降解模拟酸性大红-3R染料废水。对于质量浓度为1 000 mg/L的高浓度酸性大红-3R染料废水,最佳的处理工艺条件为:温度60℃、pH=3.0、H2O2投加质量浓度9.4 g/L、催化剂投加质量浓度1.5 g/L。在此工艺条件下酸性大红染料废水的降解率为99%,CODCr的去除率>83%。而对于质量浓度≤100 mg/L的酸性大红-3R染料废水在此条件下的降解速率接近100%。且催化剂连续使用6次后仍有较高的催化活性。 展开更多
关键词 Fe2O3/Al2O3催化剂 催化降解 酸性大红-3r
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