We present a two-photon three-dimensional multiparty quantum secret sharing scheme.The secret messagesare encoded by performing local operations.This is different from those quantum secret sharing protocols that all s...We present a two-photon three-dimensional multiparty quantum secret sharing scheme.The secret messagesare encoded by performing local operations.This is different from those quantum secret sharing protocols that all sharersmust make a state measurement.The merit of our protocol is the high capacity.展开更多
Using the quantum theory for a mesoscopic circuit based on the discretenes of electric charges, the finitedifference Schrodinger equation of the non-dlssipative mesoscopic inductance and capacity coupling circuit is a...Using the quantum theory for a mesoscopic circuit based on the discretenes of electric charges, the finitedifference Schrodinger equation of the non-dlssipative mesoscopic inductance and capacity coupling circuit is achieved. The Coulomb blockade effect, which is caused by the discreteness of electric charges, is studied. Appropriately choose the components in the circuits, the finlte-dlfference Schrodinger equation can be divided into two Mathieu equations in representation.＂ With the WKBJ method, the currents quantum fluctuations in the ground states of the two circuits are calculated. The results show that the currents quantum zero-point fluctuations of the two circuits are exist and correlated.展开更多
An understanding of the physical,chemical,and biological properties of a soil provides a basis for soil use and management.This paper reports the major physico-chemical properties and enzyme activities of the soils of...An understanding of the physical,chemical,and biological properties of a soil provides a basis for soil use and management.This paper reports the major physico-chemical properties and enzyme activities of the soils of Lhasa's main arable lands and the factors that influence these soil properties.Composite and core samples were taken from the three main arable soil types(alluvial soil,subalpine arable steppe soil,and subalpine arable meadow soil) and were analysed using standard methods.The bulk density and the ventilation porosity ratio of the soils were close to the recommended values for arable lands,and the dominant soil texture was sandy.The soil moisture release rates were arable steppe soil > alluvial soil > arable meadow soil.Soil organic matter content,Cation-Exchange Capacity(CEC),total and available nitrogen content,and catalase activity of the arable meadow soil were higher than those of the alluvial and the arable steppe soils,while soil pH in the arable meadow was lower.Most of the measured properties did not show a significant variance among these three soils.However,the measured indices(apart from the total potassium) indicate that there are notable differences among the three types of soil.The results implied that the utilisation patterns of the arable soil or human activities,such as tillage practices and fertiliser applications,have a substantialeffect on the soil properties in this region.Our results suggest that the cultivation practices in the region have apparently positive impact on the soil organic matter,nutrient contents and bulk density probably due to the sound fertiliser management such as the applications of farmyard manure and chemical fertilisers.However,intense cultivation practices lowered the activity of most soil enzymes.The results demonstrate that the choice of soil management strategy had a significant impact on the soil physicochemical and biological properties in the region studied.展开更多
Soils are the foundation of civilizations and the basis for human food production.Mollisols in Ukraine and Northeast China are two out of the four major Mollisol regions in the world.The natural areas from which Molli...Soils are the foundation of civilizations and the basis for human food production.Mollisols in Ukraine and Northeast China are two out of the four major Mollisol regions in the world.The natural areas from which Mollisols developed are the prairies and steppes that experience temperate and freezing conditions.This review paper introduces the general climate,vegetation,and topography of Mollisols regions in Ukraine and Northeast China,analyzes their properties,including soil texture,soil organic matter content,soil bulk density,pH,cation exchange capacity and other chemical properties,and compares the property changes and management practices of Mollisols in relation to sustainable grain production.展开更多
Effects of different lead compounds, PbCl2, Pb(NO3)2 and Pb(OAc)2, on the rice growth and uptake of lead and some microelements by wetland rice were studied. The results showed that the seed germination, rice seedling...Effects of different lead compounds, PbCl2, Pb(NO3)2 and Pb(OAc)2, on the rice growth and uptake of lead and some microelements by wetland rice were studied. The results showed that the seed germination, rice seedling growth, chlorophyl content, grain yield and uptake of Pb, Cu, Zn, Fe and Mn by rice plant were affected by the chemical forms of Pb compounds added in soil to a certain degree. The germination rate and the amount of chlorophyl decreased remarkably with increasing Pb concentration, the root extension was restrained obviously by the presence of Pb, and the effect of PbCl2 was more evident than that of Pb(NO3)2 or Pb(OAc)2. The pot incubation test with yellow brown soil and red soil showed that there was no significant regularity in effect of Pb on grain yield, but the difference in the influence of various Pb compounds on yield was clearer. The effect on the amount of Pb in straw and brown rice was in the sequence of Pb(NO3)2> Pb(OAc)2> PbCl2. In case the content of Pb in brown rice was 0.5 mg/ kg, the relative loading capacities of yellow brown soil for Pb added as PbCl2, Pb(OAc)2 and Pb(NO3)2 were 100, 90 and 60 respectively. Pb uptake by wetland rice was closely related to the chemical species of Pb in soil, but there was no comparability among chemical forms of different Pb compounds in the same soil. The uptake of Cu, Zn, Fe and Mn by wetland rice was markedly affected by the addition of Pb, and different Pb compounds varied in their impacts on the uptake of other metals by different organs of wetland rice, e.g. the concentration of Fe in root increased significantly (r = 0.92), while opposite was true for Fe in brown rice (r =-0.92) due to the application of Pb(OAc), in soil. These results demonstrate that the effect of accompanying anions of Pb on the physiological and biochemical processes of wetland rice was rather complex.展开更多
We propose a method of controlling the dc-SQUID (superconducting quantum interference device) system by changing the gate voltages, which controls the amplitude of the fictitious magnetic fields B-z, and the externall...We propose a method of controlling the dc-SQUID (superconducting quantum interference device) system by changing the gate voltages, which controls the amplitude of the fictitious magnetic fields B-z, and the externally applied current that produces the piercing magnetic flux Phi(x) for the dc-SQUID system. We have also introduced a physical model for the dc-SQUID system. Using this physical model, one can obtain the non-adiabatic geometric phase gate for the single qubit and the non-adiabatic conditional geometric phase gate (controlled NOT gate) for the two qubits. It is shown that when the gate voltage and the externally applied current of the dc-SQUID system satisfies an appropriate constraint condition, the charge state evolution can be controlled exactly on a dynamic phase free path. The non-adiabatic evolution of the charge states is given as well.展开更多
Areas of planting sugarcane are located in subtropical and tropical parts of Guangxi. These areas are characterized by high temperature, heavy rainfall and nutrients leaching. It results in strong decomposition of soi...Areas of planting sugarcane are located in subtropical and tropical parts of Guangxi. These areas are characterized by high temperature, heavy rainfall and nutrients leaching. It results in strong decomposition of soil mineral and a low cation exchange capacity （CEC）, low organic matter, and low phosphorus （P）, potassium （K） and sulfur （S） in soils. In about 30% of the soils in the planting sugarcane regions the total sulfur and the plant-available sulfur are under 150 mg/kg and 12 mg/kg, respectively. The sulfur nutrition is usually supplied insufficiently for sugarcane growth. The total sulfur of and available sulfur are under the medium level in nearly 50% of the soils in the planting sugarcane regions. Therefore, with the improvement of production of the sugarcane, the sulfur soil nutrition will influence and limit sugarcane yield. After application of sulfur fertilizer, available stem, single stem weight increased 5.77%-9.43% of sugarcane yield than without the treatment. It still can improve the cane sugar and fibre content. And the sugarcane can obtain better economic benefits to use the sulfur phosphorus ammonium; it is 18.2-20.23 with output/input （VCR） to use the sulfur fertilizer. Amount of sugarcane absorption sulfur reaches 44.1-67 kg/ha. The treatment with no sulfur fertilizer annual sulfur nutrient lose will be 23.67 kg/ha because sugarcane yield uptake from the field.展开更多
Ammonia volatilization is a major process of N （nitrogen） loss that affects the environment. The best way of capturing volatilized ammonia-N could be using zeolite as a good ion exchange medium before it gets either...Ammonia volatilization is a major process of N （nitrogen） loss that affects the environment. The best way of capturing volatilized ammonia-N could be using zeolite as a good ion exchange medium before it gets either volatilized or nitrified. Thus, captured ammonia-N could be used as a source of inorganic nitrogen in ponds to promote algal production without adding additional organic carbon and BOD （biochemical oxygen demand）. The zeolite used for the study was a commercially available zeolite, （CLINZEX） which was a fine powder （CEC （cation exchange capacity） 3.9-4 meq/g）. The experiment was conducted to assess the difference between manure loaded system and zeolite loaded system in terms of water quality, TAN （total ammoniacal nitrogen） release and algal productivity. The difference between the BOD values recorded in both the controls and treatments utilizing chicken manure as source of manure-N remained mostly above 10 ppm. Similarly, the difference between mean COD （chemical oxygen demand） values of control and treatment tanks always remained above 7 ppm. All the experimental tanks loaded with zeolite samples from chicken manure showed range of variation in TAN values （0.018-0.08 mg/1）. The range of values of chlorophyll a （1,029-5,150 mg/m~） recorded in the treatment tanks was higher than the values （54.6-1347 mg/m3） of chlorophyll a in the control tanks. F-test analysis done using highest mean values of BOD, COD, TAN and chlorophyll a showed a highly significant （P 〈 0.01） variation between the treatment and control tanks and at the same time no significant variation was found between time intervals.展开更多
This study investigated the impact assessment of oil spillage on farmlands of some communities in Ilaje Area of Ondo state. Three farmlands were considered in the course of this study. Two of the three farmlands were ...This study investigated the impact assessment of oil spillage on farmlands of some communities in Ilaje Area of Ondo state. Three farmlands were considered in the course of this study. Two of the three farmlands were within the Ikorigho and Otumara communities that recently experienced oil spillage and they are about 300 m from each other. While the third farm was within the Igbokoda community which is geographically similar but has not experienced oil spillage, it was used as control. The farmland was delineated at each area by the grid technique and soil samples were collected at 0-20 cm depth of the ground. Some physiochemical properties that reflect soil nutrient content and fertility status （pH, electrical conductivity, moisture content, organic matter, nitrogen, phosphorous and cation exchange capacity （CEC）） were determined using standard methods and results from the three areas were compared. There was a significant decrease in the calcium （Ca）, magnesium （Mg）, potassium （K） and organic matter, as well as a significant increase in the electrical conductivity, moisture content and phosphorous content of the oil-spill affected farmlands at Ikorigho and Otumara when compared with the non-affected farmland at Igbokoda. The acidic nature of the farmlands could not be attributed entirely to the oil spill since the control farmland at Igbokoda was slightly acidic. The results show that oil spillage has adversely affected the nutrient level and fertility status of farmland at Ikorigho and Otumara communities, which needs urgent remediation.展开更多
The study area is located in Duhok province-Kurdistan region-Northern Iraq and including two locations the first location is situated in Galbook village and the vegetation cover is trees of （Quercus aegilops L.）, th...The study area is located in Duhok province-Kurdistan region-Northern Iraq and including two locations the first location is situated in Galbook village and the vegetation cover is trees of （Quercus aegilops L.）, the second location is situated in Koradeer village that covered with threes of Prunus dulcis （Mill.） Webb.. Disturbed surface soil samples at depth 0-30 cm were collected at four different distances （1, 5, 10 and 15 m） from the tree with randomized selection three trees in each study location. Soil organic matter decreases with increasing distances from tree in both locations under two different trees species, which is attributed to the effect of tree crown. Ordinarily, organic matter content in both locations correspond to the requirements of Mollisols. Statistical analysis of data showed significant differences in organic matter content between locations. Cation exchange capacity is high under tree crown and decreasing with distances from tree in both locations, as a result of decreasing organic matter and increasing calcium carbonate with distances. Commonly soil pH is slightly increased with increasing distances from tree because of increasing calcium carbonate with distances and decreasing organic matter content. Calcium was not uniform with distances and Mg decreasing with distances in both locations. The values of fine clay/coarse clay and fine clay/total clay of soil samples confirm development of the soils under study. Porosity percentage under tree crown is high and decreasing with distances. Soil bulk density was increased with distances in both locations, as a result of decreasing organic matter content with distances. This study aims to explain the effect of tree distances and species on the mollic horizon properties.展开更多
The cationic group distribution along the polymeric backbones of anion exchange membranes(AEMs)has significant influence on their microscopic morphology and anion conductivity.To develop high-performance AEMs for vana...The cationic group distribution along the polymeric backbones of anion exchange membranes(AEMs)has significant influence on their microscopic morphology and anion conductivity.To develop high-performance AEMs for vanadium redox flow batteries(VRFBs),a series of poly(fluorenyl ether)samples bearing di-and tri-quaternary ammonium side chains with similar ion exchange capacities(IECs)were synthesized by grafting cationic alkyl chains with tertiary amine-containing poly(fluorenyl ether)precursors.The experimental results indicate that the introduction of the multi-cationic side chains facilitates the formation of micro-phase-separated morphologies and enhances anion conductivity.Moreover,the number of spacer atoms between the quaternary ammonium groups on the side chains affects the water uptake of the membranes,thus complicating the relationship between the density of cationic group distribution and anion conductivity.The poly(fluorenyl ether)s with dicationic side chains and six spacing atoms(DQA-PFE-C6)showed the highest anion conductivity.A VRFB assembled with DQA-PFE-C6 exhibited a maximum power density of 239.80 mW cm^−2 at 250 mA cm^−2,which is significantly higher than a VRFB assembled with Nafion 212.Therefore,side chain engineering is an effective chemical approach to enhance the properties of AEMs for VRFB applications.展开更多
Sodium metal anode holds great promise in pursuing high-energy and sustainable rechargeable batteries,but severely suffers from fatal dendrite growth accompanied with huge volume change.Herein,a robust mixed conductin...Sodium metal anode holds great promise in pursuing high-energy and sustainable rechargeable batteries,but severely suffers from fatal dendrite growth accompanied with huge volume change.Herein,a robust mixed conducting sodium metal anode is designed through incorporating Na SICON-type solid Na-ion conductor into bulk Na.A fast and continuous pathway for simultaneous transportation of electrons and Na+is established throughout the composite anode.The intimate contact between Na-ion conducting phase and Na metallic phase constructs abundant two-phase boundaries for fast redox reactions.Further,the compact configuration of the composite anode substantially protects Na metal from being corroded by liquid organic electrolyte for the minimization of side reactions.Benefiting from the unique configuration,the composite anode shows highly reversible and durable Na plating/stripping behavior.The symmetric cells exhibit ultralong lifespan for over 700 h at 1 mA cm^(-2)with a high capacity of 5 m Ah cm^(-2)and outstanding rate capability up to 8 m A cm^(-2)in the carbonate electrolyte.Full cells with Na_(3)V_(2)(PO_(4))_(3)/C cathode demonstrate impressive cycling stability(capacity decay of 0.012%per cycle)and low charge/discharge polarization as well.This work provides new insights into rational design and development of robust sodium metal anode through an architecture engineering strategy for advanced rechargeable sodium batteries.展开更多
A fundamental understanding of the electrochemical reaction process and mechanism of electrodes is very crucial for developing high-performance electrode materials.In this study,we report the sodium ion storage behavi...A fundamental understanding of the electrochemical reaction process and mechanism of electrodes is very crucial for developing high-performance electrode materials.In this study,we report the sodium ion storage behavior and mechanism of orthorhombic V_(2)O_(5) single-crystalline nanowires in the voltage window of 1.0–4.0 V(vs.Na/Na+).The single-crystalline nanowires exhibit a large irreversible capacity loss during the first discharge/charge cycle,and then show excellent cycling stability in the following cycles.At a current density of 100 mA g^(−1),the nanowires electrode delivers initial discharge/charge capacity of 217/88 mA h g^(−1),corresponding to a Coulombic efficiency of only 40.5%;after 100 cycles,the electrode remains a reversible discharge capacity of 78 mA h g^(−1) with a fading rate of only 0.09%per cycle compared with the 2nd cycle discharge capacity.The sodium ion storage mechanism was investigated,illustrating that the large irreversible capacity loss in the first cycle can be attributed to the initially formed single-crystalline α′-Nax V_(2)O_(5)(0.02<x<0.88),in which sodium ions cannot be electrochemically extracted and the α′-Na0.88 V_(2)O_(5) can reversibly host and release sodium ions via a single-phase(solid solution)reaction,leading to excellent cycling stability.The Na^(+) diffusion coefficient in α′-Nax V_(2)O_(5) ranges from 10^(−12) to 10^(−11.5) cm^(2) s^(−1) as evaluated by galvanostatic intermittent titration technique(GITT).展开更多
We investigate the effect of decoherence from a spin environment on the quantum channel capacity.Our results imply that the time evolution of the quantum channel capacity depends on the number of freedom degrees of th...We investigate the effect of decoherence from a spin environment on the quantum channel capacity.Our results imply that the time evolution of the quantum channel capacity depends on the number of freedom degrees of the environment,the tunneling element,the initial state of the environment,and the system-environment coupling strength.From the analysis,we find that the strong tunneling elements and the weak coupling strength can enhance the quantum channel capacity while the environment with a large number of freedom degrees and the strong coupling strength will shrink it.展开更多
This work proposes two fault tolerant quantum secure direct communication （QSDC） protocols which are robust against two kinds of collective noises： the collective-dephasing noises and the collective-rotation noises...This work proposes two fault tolerant quantum secure direct communication （QSDC） protocols which are robust against two kinds of collective noises： the collective-dephasing noises and the collective-rotation noises, respectively. The two QSDC protocols are constructed from four-qubit DF states which consist of two logical qubits. The receiver simply performs two Bell state measurements （rather than four-qubit joint measurements） to obtain the secret message. The protocols have qubit efficiency twice that of the other corresponding fault tolerant QSDC protocols. Furthermore, the proposed protocols are free from Trojan horse attacks.展开更多
As a star representative of transition metal sulfides, Sn S is viewed as a promising anode-material candidate for sodium ion batteries due to its high theoretical capacity and unique layered structure. However,the ext...As a star representative of transition metal sulfides, Sn S is viewed as a promising anode-material candidate for sodium ion batteries due to its high theoretical capacity and unique layered structure. However,the extremely poor electrical conductivity and severe volume expansion strongly hinder its practical application while achieving a high reversible capacity with long-cyclic stability still remains a grand challenge. Herein, different from the conventional enhancement method of elemental doping, we report a rational strategy to introduce PO_(4)^(3-)into the Sn S layers using phytic acid as the special phosphorus source.Intriguingly, the presence of PO_(4)^(3-)in the form of Sn–O–P covalent bonds can act as a conductive pillar to buffer the volume expansion of Sn S while expanding its interlay spacing to allow more Na+storage, supported by both experimental and theoretical evidences. Profiting from this effect combined with microstructural metrics by loading on high pyridine N-doped reduced graphene oxide, the as-prepared material presented an unprecedented ultra-long cyclic stability even after 10,000 cycles along with high reversible capacity and excellent full-cell performances. The findings herein open up new opportunities for elevating electrochemical performances of metal sulfides and provide inspirations for the fabrication of advanced electrode materials for broad energy use.展开更多
Three kinds of quantum relay communication models are proposed,i.e.,the quantum single relay model,quantum serial multi-relay model and quantum parallel multi-relay model.The channel capacities of those three kinds of...Three kinds of quantum relay communication models are proposed,i.e.,the quantum single relay model,quantum serial multi-relay model and quantum parallel multi-relay model.The channel capacities of those three kinds of systems are analyzed with the theory of quantum Markov trace-preserving process and the generalized theory of simple multi-hop channel in quantum system.Motivated by the quantum Fano inequality,the lower bounds of that channel capacities are derived.The illustration and simulation present the trends of the lower bounds on the channel capacities of different quantum relay systems based on the depolarizing noisy channel.展开更多
文摘We present a two-photon three-dimensional multiparty quantum secret sharing scheme.The secret messagesare encoded by performing local operations.This is different from those quantum secret sharing protocols that all sharersmust make a state measurement.The merit of our protocol is the high capacity.
基金The project supported by National Natural Science Foundation of China under Grant No. 10405009 and Natural Science Foundation of Hebei Province of China under Grant No. 103143
文摘Using the quantum theory for a mesoscopic circuit based on the discretenes of electric charges, the finitedifference Schrodinger equation of the non-dlssipative mesoscopic inductance and capacity coupling circuit is achieved. The Coulomb blockade effect, which is caused by the discreteness of electric charges, is studied. Appropriately choose the components in the circuits, the finlte-dlfference Schrodinger equation can be divided into two Mathieu equations in representation.＂ With the WKBJ method, the currents quantum fluctuations in the ground states of the two circuits are calculated. The results show that the currents quantum zero-point fluctuations of the two circuits are exist and correlated.
基金"strategic priority research program - climate change: carbon budget and related issues" of the Chinese Academy of Sciences(Grant No.XDA05050506)the One Hundred Young Persons Project of the Institute of Mountain Hazards and Environment, Chinese Academy of Sciences(Grant No.SDSQB2010-02)
文摘An understanding of the physical,chemical,and biological properties of a soil provides a basis for soil use and management.This paper reports the major physico-chemical properties and enzyme activities of the soils of Lhasa's main arable lands and the factors that influence these soil properties.Composite and core samples were taken from the three main arable soil types(alluvial soil,subalpine arable steppe soil,and subalpine arable meadow soil) and were analysed using standard methods.The bulk density and the ventilation porosity ratio of the soils were close to the recommended values for arable lands,and the dominant soil texture was sandy.The soil moisture release rates were arable steppe soil > alluvial soil > arable meadow soil.Soil organic matter content,Cation-Exchange Capacity(CEC),total and available nitrogen content,and catalase activity of the arable meadow soil were higher than those of the alluvial and the arable steppe soils,while soil pH in the arable meadow was lower.Most of the measured properties did not show a significant variance among these three soils.However,the measured indices(apart from the total potassium) indicate that there are notable differences among the three types of soil.The results implied that the utilisation patterns of the arable soil or human activities,such as tillage practices and fertiliser applications,have a substantialeffect on the soil properties in this region.Our results suggest that the cultivation practices in the region have apparently positive impact on the soil organic matter,nutrient contents and bulk density probably due to the sound fertiliser management such as the applications of farmyard manure and chemical fertilisers.However,intense cultivation practices lowered the activity of most soil enzymes.The results demonstrate that the choice of soil management strategy had a significant impact on the soil physicochemical and biological properties in the region studied.
基金Under the auspices of CAS-Russia,Ukraine and Belarus Cooperation Program (2011)Bureau of International Cooperation Grant,Chinese Academy of Sciences (No.GJHZ0949)Harbin Bureau of Science and Technology for Outstanding Scientist (No.2010RFXYN044)
文摘Soils are the foundation of civilizations and the basis for human food production.Mollisols in Ukraine and Northeast China are two out of the four major Mollisol regions in the world.The natural areas from which Mollisols developed are the prairies and steppes that experience temperate and freezing conditions.This review paper introduces the general climate,vegetation,and topography of Mollisols regions in Ukraine and Northeast China,analyzes their properties,including soil texture,soil organic matter content,soil bulk density,pH,cation exchange capacity and other chemical properties,and compares the property changes and management practices of Mollisols in relation to sustainable grain production.
文摘Effects of different lead compounds, PbCl2, Pb(NO3)2 and Pb(OAc)2, on the rice growth and uptake of lead and some microelements by wetland rice were studied. The results showed that the seed germination, rice seedling growth, chlorophyl content, grain yield and uptake of Pb, Cu, Zn, Fe and Mn by rice plant were affected by the chemical forms of Pb compounds added in soil to a certain degree. The germination rate and the amount of chlorophyl decreased remarkably with increasing Pb concentration, the root extension was restrained obviously by the presence of Pb, and the effect of PbCl2 was more evident than that of Pb(NO3)2 or Pb(OAc)2. The pot incubation test with yellow brown soil and red soil showed that there was no significant regularity in effect of Pb on grain yield, but the difference in the influence of various Pb compounds on yield was clearer. The effect on the amount of Pb in straw and brown rice was in the sequence of Pb(NO3)2> Pb(OAc)2> PbCl2. In case the content of Pb in brown rice was 0.5 mg/ kg, the relative loading capacities of yellow brown soil for Pb added as PbCl2, Pb(OAc)2 and Pb(NO3)2 were 100, 90 and 60 respectively. Pb uptake by wetland rice was closely related to the chemical species of Pb in soil, but there was no comparability among chemical forms of different Pb compounds in the same soil. The uptake of Cu, Zn, Fe and Mn by wetland rice was markedly affected by the addition of Pb, and different Pb compounds varied in their impacts on the uptake of other metals by different organs of wetland rice, e.g. the concentration of Fe in root increased significantly (r = 0.92), while opposite was true for Fe in brown rice (r =-0.92) due to the application of Pb(OAc), in soil. These results demonstrate that the effect of accompanying anions of Pb on the physiological and biochemical processes of wetland rice was rather complex.
文摘We propose a method of controlling the dc-SQUID (superconducting quantum interference device) system by changing the gate voltages, which controls the amplitude of the fictitious magnetic fields B-z, and the externally applied current that produces the piercing magnetic flux Phi(x) for the dc-SQUID system. We have also introduced a physical model for the dc-SQUID system. Using this physical model, one can obtain the non-adiabatic geometric phase gate for the single qubit and the non-adiabatic conditional geometric phase gate (controlled NOT gate) for the two qubits. It is shown that when the gate voltage and the externally applied current of the dc-SQUID system satisfies an appropriate constraint condition, the charge state evolution can be controlled exactly on a dynamic phase free path. The non-adiabatic evolution of the charge states is given as well.
文摘Areas of planting sugarcane are located in subtropical and tropical parts of Guangxi. These areas are characterized by high temperature, heavy rainfall and nutrients leaching. It results in strong decomposition of soil mineral and a low cation exchange capacity （CEC）, low organic matter, and low phosphorus （P）, potassium （K） and sulfur （S） in soils. In about 30% of the soils in the planting sugarcane regions the total sulfur and the plant-available sulfur are under 150 mg/kg and 12 mg/kg, respectively. The sulfur nutrition is usually supplied insufficiently for sugarcane growth. The total sulfur of and available sulfur are under the medium level in nearly 50% of the soils in the planting sugarcane regions. Therefore, with the improvement of production of the sugarcane, the sulfur soil nutrition will influence and limit sugarcane yield. After application of sulfur fertilizer, available stem, single stem weight increased 5.77%-9.43% of sugarcane yield than without the treatment. It still can improve the cane sugar and fibre content. And the sugarcane can obtain better economic benefits to use the sulfur phosphorus ammonium; it is 18.2-20.23 with output/input （VCR） to use the sulfur fertilizer. Amount of sugarcane absorption sulfur reaches 44.1-67 kg/ha. The treatment with no sulfur fertilizer annual sulfur nutrient lose will be 23.67 kg/ha because sugarcane yield uptake from the field.
文摘Ammonia volatilization is a major process of N （nitrogen） loss that affects the environment. The best way of capturing volatilized ammonia-N could be using zeolite as a good ion exchange medium before it gets either volatilized or nitrified. Thus, captured ammonia-N could be used as a source of inorganic nitrogen in ponds to promote algal production without adding additional organic carbon and BOD （biochemical oxygen demand）. The zeolite used for the study was a commercially available zeolite, （CLINZEX） which was a fine powder （CEC （cation exchange capacity） 3.9-4 meq/g）. The experiment was conducted to assess the difference between manure loaded system and zeolite loaded system in terms of water quality, TAN （total ammoniacal nitrogen） release and algal productivity. The difference between the BOD values recorded in both the controls and treatments utilizing chicken manure as source of manure-N remained mostly above 10 ppm. Similarly, the difference between mean COD （chemical oxygen demand） values of control and treatment tanks always remained above 7 ppm. All the experimental tanks loaded with zeolite samples from chicken manure showed range of variation in TAN values （0.018-0.08 mg/1）. The range of values of chlorophyll a （1,029-5,150 mg/m~） recorded in the treatment tanks was higher than the values （54.6-1347 mg/m3） of chlorophyll a in the control tanks. F-test analysis done using highest mean values of BOD, COD, TAN and chlorophyll a showed a highly significant （P 〈 0.01） variation between the treatment and control tanks and at the same time no significant variation was found between time intervals.
文摘This study investigated the impact assessment of oil spillage on farmlands of some communities in Ilaje Area of Ondo state. Three farmlands were considered in the course of this study. Two of the three farmlands were within the Ikorigho and Otumara communities that recently experienced oil spillage and they are about 300 m from each other. While the third farm was within the Igbokoda community which is geographically similar but has not experienced oil spillage, it was used as control. The farmland was delineated at each area by the grid technique and soil samples were collected at 0-20 cm depth of the ground. Some physiochemical properties that reflect soil nutrient content and fertility status （pH, electrical conductivity, moisture content, organic matter, nitrogen, phosphorous and cation exchange capacity （CEC）） were determined using standard methods and results from the three areas were compared. There was a significant decrease in the calcium （Ca）, magnesium （Mg）, potassium （K） and organic matter, as well as a significant increase in the electrical conductivity, moisture content and phosphorous content of the oil-spill affected farmlands at Ikorigho and Otumara when compared with the non-affected farmland at Igbokoda. The acidic nature of the farmlands could not be attributed entirely to the oil spill since the control farmland at Igbokoda was slightly acidic. The results show that oil spillage has adversely affected the nutrient level and fertility status of farmland at Ikorigho and Otumara communities, which needs urgent remediation.
文摘The study area is located in Duhok province-Kurdistan region-Northern Iraq and including two locations the first location is situated in Galbook village and the vegetation cover is trees of （Quercus aegilops L.）, the second location is situated in Koradeer village that covered with threes of Prunus dulcis （Mill.） Webb.. Disturbed surface soil samples at depth 0-30 cm were collected at four different distances （1, 5, 10 and 15 m） from the tree with randomized selection three trees in each study location. Soil organic matter decreases with increasing distances from tree in both locations under two different trees species, which is attributed to the effect of tree crown. Ordinarily, organic matter content in both locations correspond to the requirements of Mollisols. Statistical analysis of data showed significant differences in organic matter content between locations. Cation exchange capacity is high under tree crown and decreasing with distances from tree in both locations, as a result of decreasing organic matter and increasing calcium carbonate with distances. Commonly soil pH is slightly increased with increasing distances from tree because of increasing calcium carbonate with distances and decreasing organic matter content. Calcium was not uniform with distances and Mg decreasing with distances in both locations. The values of fine clay/coarse clay and fine clay/total clay of soil samples confirm development of the soils under study. Porosity percentage under tree crown is high and decreasing with distances. Soil bulk density was increased with distances in both locations, as a result of decreasing organic matter content with distances. This study aims to explain the effect of tree distances and species on the mollic horizon properties.
基金the National Natural Science Foundation of China(51873037 and 51503038)。
文摘The cationic group distribution along the polymeric backbones of anion exchange membranes(AEMs)has significant influence on their microscopic morphology and anion conductivity.To develop high-performance AEMs for vanadium redox flow batteries(VRFBs),a series of poly(fluorenyl ether)samples bearing di-and tri-quaternary ammonium side chains with similar ion exchange capacities(IECs)were synthesized by grafting cationic alkyl chains with tertiary amine-containing poly(fluorenyl ether)precursors.The experimental results indicate that the introduction of the multi-cationic side chains facilitates the formation of micro-phase-separated morphologies and enhances anion conductivity.Moreover,the number of spacer atoms between the quaternary ammonium groups on the side chains affects the water uptake of the membranes,thus complicating the relationship between the density of cationic group distribution and anion conductivity.The poly(fluorenyl ether)s with dicationic side chains and six spacing atoms(DQA-PFE-C6)showed the highest anion conductivity.A VRFB assembled with DQA-PFE-C6 exhibited a maximum power density of 239.80 mW cm^−2 at 250 mA cm^−2,which is significantly higher than a VRFB assembled with Nafion 212.Therefore,side chain engineering is an effective chemical approach to enhance the properties of AEMs for VRFB applications.
基金supported by the National Natural Science Foundation of China(51722105)National Key Research and Development Program(2016YFB0901600)+1 种基金Zhejiang Provincial Natural Science Foundation(LR18B030001)Ten Thousand Talent Program of Zhejiang Province。
文摘Sodium metal anode holds great promise in pursuing high-energy and sustainable rechargeable batteries,but severely suffers from fatal dendrite growth accompanied with huge volume change.Herein,a robust mixed conducting sodium metal anode is designed through incorporating Na SICON-type solid Na-ion conductor into bulk Na.A fast and continuous pathway for simultaneous transportation of electrons and Na+is established throughout the composite anode.The intimate contact between Na-ion conducting phase and Na metallic phase constructs abundant two-phase boundaries for fast redox reactions.Further,the compact configuration of the composite anode substantially protects Na metal from being corroded by liquid organic electrolyte for the minimization of side reactions.Benefiting from the unique configuration,the composite anode shows highly reversible and durable Na plating/stripping behavior.The symmetric cells exhibit ultralong lifespan for over 700 h at 1 mA cm^(-2)with a high capacity of 5 m Ah cm^(-2)and outstanding rate capability up to 8 m A cm^(-2)in the carbonate electrolyte.Full cells with Na_(3)V_(2)(PO_(4))_(3)/C cathode demonstrate impressive cycling stability(capacity decay of 0.012%per cycle)and low charge/discharge polarization as well.This work provides new insights into rational design and development of robust sodium metal anode through an architecture engineering strategy for advanced rechargeable sodium batteries.
基金financially supported by the National Natural Science Foundation of China (51664012)Guangxi Natural Science Foundation (2017GXNSFAA198117 and2015GXNSFGA139006)the Technology Major Project of Guangxi(AA19046001)
文摘A fundamental understanding of the electrochemical reaction process and mechanism of electrodes is very crucial for developing high-performance electrode materials.In this study,we report the sodium ion storage behavior and mechanism of orthorhombic V_(2)O_(5) single-crystalline nanowires in the voltage window of 1.0–4.0 V(vs.Na/Na+).The single-crystalline nanowires exhibit a large irreversible capacity loss during the first discharge/charge cycle,and then show excellent cycling stability in the following cycles.At a current density of 100 mA g^(−1),the nanowires electrode delivers initial discharge/charge capacity of 217/88 mA h g^(−1),corresponding to a Coulombic efficiency of only 40.5%;after 100 cycles,the electrode remains a reversible discharge capacity of 78 mA h g^(−1) with a fading rate of only 0.09%per cycle compared with the 2nd cycle discharge capacity.The sodium ion storage mechanism was investigated,illustrating that the large irreversible capacity loss in the first cycle can be attributed to the initially formed single-crystalline α′-Nax V_(2)O_(5)(0.02<x<0.88),in which sodium ions cannot be electrochemically extracted and the α′-Na0.88 V_(2)O_(5) can reversibly host and release sodium ions via a single-phase(solid solution)reaction,leading to excellent cycling stability.The Na^(+) diffusion coefficient in α′-Nax V_(2)O_(5) ranges from 10^(−12) to 10^(−11.5) cm^(2) s^(−1) as evaluated by galvanostatic intermittent titration technique(GITT).
基金Supported by the National Natural Science Foundation of China under Grant Nos. 11105001,11004001,and 10975125
文摘We investigate the effect of decoherence from a spin environment on the quantum channel capacity.Our results imply that the time evolution of the quantum channel capacity depends on the number of freedom degrees of the environment,the tunneling element,the initial state of the environment,and the system-environment coupling strength.From the analysis,we find that the strong tunneling elements and the weak coupling strength can enhance the quantum channel capacity while the environment with a large number of freedom degrees and the strong coupling strength will shrink it.
基金supported by the National Science Council, Taiwan, China (Grant No. NSC98-2221-E-006-097-MY3)
文摘This work proposes two fault tolerant quantum secure direct communication （QSDC） protocols which are robust against two kinds of collective noises： the collective-dephasing noises and the collective-rotation noises, respectively. The two QSDC protocols are constructed from four-qubit DF states which consist of two logical qubits. The receiver simply performs two Bell state measurements （rather than four-qubit joint measurements） to obtain the secret message. The protocols have qubit efficiency twice that of the other corresponding fault tolerant QSDC protocols. Furthermore, the proposed protocols are free from Trojan horse attacks.
基金supported by the National Natural Science Foundation of China(51904059)Fundamental Research Funds for the Central Universities(N2002005,N2125004,and N2225044)+1 种基金Applied Basic Research Program of Liaoning(2022JH2/101300200)。
文摘As a star representative of transition metal sulfides, Sn S is viewed as a promising anode-material candidate for sodium ion batteries due to its high theoretical capacity and unique layered structure. However,the extremely poor electrical conductivity and severe volume expansion strongly hinder its practical application while achieving a high reversible capacity with long-cyclic stability still remains a grand challenge. Herein, different from the conventional enhancement method of elemental doping, we report a rational strategy to introduce PO_(4)^(3-)into the Sn S layers using phytic acid as the special phosphorus source.Intriguingly, the presence of PO_(4)^(3-)in the form of Sn–O–P covalent bonds can act as a conductive pillar to buffer the volume expansion of Sn S while expanding its interlay spacing to allow more Na+storage, supported by both experimental and theoretical evidences. Profiting from this effect combined with microstructural metrics by loading on high pyridine N-doped reduced graphene oxide, the as-prepared material presented an unprecedented ultra-long cyclic stability even after 10,000 cycles along with high reversible capacity and excellent full-cell performances. The findings herein open up new opportunities for elevating electrochemical performances of metal sulfides and provide inspirations for the fabrication of advanced electrode materials for broad energy use.
基金Supported by the National Natural Science Foundation of China under Grant No.60902044the Program for New Century Excellent Talents in University of Ministry of Education of China(NCET-11-0510)+5 种基金the Hunan Provincial Innovation Foundation For Postgraduate under Grant No.CX2011B087the State Scholarship Fund organized by the China Scholarship Council under Grant No.2011637096Excellent Doctoral Dissertation Fund of Central South University under Grant No.2011ybjz030WCU R32-2010-000-20014-0(Korea)FR 2010-0020942(Korea)MEST 2012-002521(NRF Korea)
文摘Three kinds of quantum relay communication models are proposed,i.e.,the quantum single relay model,quantum serial multi-relay model and quantum parallel multi-relay model.The channel capacities of those three kinds of systems are analyzed with the theory of quantum Markov trace-preserving process and the generalized theory of simple multi-hop channel in quantum system.Motivated by the quantum Fano inequality,the lower bounds of that channel capacities are derived.The illustration and simulation present the trends of the lower bounds on the channel capacities of different quantum relay systems based on the depolarizing noisy channel.
