This paper has demonstrated that there is great variation in the size range and chemical composition of metalliferous PM （particulate matter） present within Comarca Lagunera, M6xico due to the physiography of the te...This paper has demonstrated that there is great variation in the size range and chemical composition of metalliferous PM （particulate matter） present within Comarca Lagunera, M6xico due to the physiography of the terrain together the intense vehicular traffic, unpaved roads, cement and lime plants, marble quarries, brick plants, and the largest smelter of non-ferrous material in Latin America. Cascade impactor PM samples from six size ranges： 〈 0.49 μm, 0.49-0.9 μm, 0.9-1.5μm, 1.5-3.0 p.m, 3.0-7.2 μm and 7.2-10 μm were collected from inside two stacks within G6mez Palacios and Torreon cities. ICP-AES （inductively coupled plasma-atomic emission spectrometry） analysis on collected Whatman fiberglass filters demonstrates that the PM are matrices mostly constituted of carbonates and silicates with abundant fine metalliferous particles. The metals with the most concentrations averaged over all size ranges were Cu, Fe, Mn, Ni, Pb and Ti. The size distributions of metals detected in this work have been plotted as normalized histogram concentration of each size fraction, the total concentration, and the aerodynamic particle diameter, which is a useful method for comparing the contributions of coarse and fine particles to pollutant concentrations.展开更多
Aerosol samples were collected at two coastal suburban stations, Qingdao （China） in 1995-1996 and Liverpool （U.K.） in 1995, respectively. The samples were analyzed to determine the concentrations of trace metals ...Aerosol samples were collected at two coastal suburban stations, Qingdao （China） in 1995-1996 and Liverpool （U.K.） in 1995, respectively. The samples were analyzed to determine the concentrations of trace metals （Cr, Zn, Cu, Co, Ni, Pb, V, and Cd） as well as A1, Fe and Mn. Data were examined to understand the difference of trace metals in aerosols between coastal zones downwind the developing area （near the Yellow Sea） and developed region （near the Irish Sea）. The results show that most elements at Qingdao have levels 4-5 times higher than those at Liverpool, particularly for the crust-dominated elements （e.g. Al, Fe and Mn）. Moreover, the aerosol composition at Qingdao is higher in spring than in summer, underlying the influence of westerlies and local emissions in combination, whereas seasonal change of aerosol composition is not significant at Liverpool. The enrichment factors for the crustal source elements （EFcrust） at Liverpool are much higher than those at Qingdao. The contributions from the pollutant source （Rp） for some trace metals like Cu, Pb, Zn and Cd are 〉90% at Qingdao and Liverpool, suggesting overwhelming anthropogenic contributions to these metals. The contributions from crustal source （Re） for trace metals tend to increase with higher aerosol levels and Al concentration at Qingdao, indicating a good correlation between the crust-dominated component and the air mass. At Liverpool, the Rc values for trace metals are positively correlated with Al concentrations instead of with aerosol mass, suggesting that Al in aerosols represents the crustal component even though the aerosols come from different sources.展开更多
文摘This paper has demonstrated that there is great variation in the size range and chemical composition of metalliferous PM （particulate matter） present within Comarca Lagunera, M6xico due to the physiography of the terrain together the intense vehicular traffic, unpaved roads, cement and lime plants, marble quarries, brick plants, and the largest smelter of non-ferrous material in Latin America. Cascade impactor PM samples from six size ranges： 〈 0.49 μm, 0.49-0.9 μm, 0.9-1.5μm, 1.5-3.0 p.m, 3.0-7.2 μm and 7.2-10 μm were collected from inside two stacks within G6mez Palacios and Torreon cities. ICP-AES （inductively coupled plasma-atomic emission spectrometry） analysis on collected Whatman fiberglass filters demonstrates that the PM are matrices mostly constituted of carbonates and silicates with abundant fine metalliferous particles. The metals with the most concentrations averaged over all size ranges were Cu, Fe, Mn, Ni, Pb and Ti. The size distributions of metals detected in this work have been plotted as normalized histogram concentration of each size fraction, the total concentration, and the aerodynamic particle diameter, which is a useful method for comparing the contributions of coarse and fine particles to pollutant concentrations.
基金the Ministry of Science and Technology of China (No.G1999043705 and 2001CB-409703)the Natural Sciences Foundation of Shandong Province (No.2000E02)
文摘Aerosol samples were collected at two coastal suburban stations, Qingdao （China） in 1995-1996 and Liverpool （U.K.） in 1995, respectively. The samples were analyzed to determine the concentrations of trace metals （Cr, Zn, Cu, Co, Ni, Pb, V, and Cd） as well as A1, Fe and Mn. Data were examined to understand the difference of trace metals in aerosols between coastal zones downwind the developing area （near the Yellow Sea） and developed region （near the Irish Sea）. The results show that most elements at Qingdao have levels 4-5 times higher than those at Liverpool, particularly for the crust-dominated elements （e.g. Al, Fe and Mn）. Moreover, the aerosol composition at Qingdao is higher in spring than in summer, underlying the influence of westerlies and local emissions in combination, whereas seasonal change of aerosol composition is not significant at Liverpool. The enrichment factors for the crustal source elements （EFcrust） at Liverpool are much higher than those at Qingdao. The contributions from the pollutant source （Rp） for some trace metals like Cu, Pb, Zn and Cd are 〉90% at Qingdao and Liverpool, suggesting overwhelming anthropogenic contributions to these metals. The contributions from crustal source （Re） for trace metals tend to increase with higher aerosol levels and Al concentration at Qingdao, indicating a good correlation between the crust-dominated component and the air mass. At Liverpool, the Rc values for trace metals are positively correlated with Al concentrations instead of with aerosol mass, suggesting that Al in aerosols represents the crustal component even though the aerosols come from different sources.
