In this paper, we have studied tunneling dynamics of the halves of a double-well trap containing a Bose-Einstein condensate. It is found that there exist step structure and macroscopic quantum self-trapping of populat...In this paper, we have studied tunneling dynamics of the halves of a double-well trap containing a Bose-Einstein condensate. It is found that there exist step structure and macroscopic quantum self-trapping of population difference of atoms, and exist Shapiro-like steps of atomic tunneling current. Both the population difference and the atomic tunneling current depend strongly on the total number of atoms and the initial phase difference.展开更多
We investigate tunneling dynamics of atomic group consisting of three atoms in Bose-Einstein condensates with Feshbach resonance. It is shown that the tunneling of the atom group depends not only on the inter-atomic n...We investigate tunneling dynamics of atomic group consisting of three atoms in Bose-Einstein condensates with Feshbach resonance. It is shown that the tunneling of the atom group depends not only on the inter-atomic nonlinear interactions and the initial number of atoms in these condensates, but also on the tunneling coupling between the atomic condensate and the three-atomic molecular condensate. It is found that besides oscillating tunneling current between the atomic condensate and the molecular condensate, the nonlinear atomic group tunneling dynamics sustains a self-maintained population imbalance: a macroscopic quantum self-trapping effect. The influence of de-coherence caused by non-condensate atoms on the tunneling dynamics is studied. It is indicated that de-coherence suppresses the atomic group tunneling.展开更多
The prototype tetra-atomic reaction F+H2O→HF+OH plays a significant role in both atmospheric and astronomical chemistry.In this work,thermal rate coefficients of this reaction are determined with the ring polymer mol...The prototype tetra-atomic reaction F+H2O→HF+OH plays a significant role in both atmospheric and astronomical chemistry.In this work,thermal rate coefficients of this reaction are determined with the ring polymer molecular dynamics(RPMD)method on a full-dimensional potential energy surface(PES).This PES is the most accurate one for the title reaction,as demonstrated by the correct barrier height and reaction energy,compared to the benchmark calculations by the focal point analysis and the high accuracy extrapolated ab initio thermochemistry methods.The RPMD rate coefficients are in excellent agreement with those calculated by the semiclassical transition state theory and a two-dimensional master equation technique,and some experimental measurements.As has been found in many RPMD applications,quantum effects,including tunneling and zero-point energy effects,can be efficiently and effectively captured by the RPMD method.In addition,the convergence of the results with respect to the number of beads is rapid,which is also consistent with previous RPMD applications.展开更多
The tunneling dynamics of dilute boson gases with three-body interactions in a periodically driven double wells are investigated both theoretically and numerieally. In our findings, when the system is with only repuls...The tunneling dynamics of dilute boson gases with three-body interactions in a periodically driven double wells are investigated both theoretically and numerieally. In our findings, when the system is with only repulsive twobody interactions or only three-body interactions, the tunneling will be suppressed; while in the case of the coupling between two- and three-body interactions, the tunneling can be either suppressed or enhanced. Particularly, when attractive three-body interactions are twice large as repulsive two-body interactions, CDT occurs at isolated points of driving force, which is similar to the linear case. Considering different interaction, the system can experience different transformation from coherent tunneling to coherent destruction of tunneling （CDT）. The quasi-energy of the system as the function of the periodicaJ1y driving force shows a triangular structure, which provides a deep insight into the tunneling dynamics of the system.展开更多
文摘In this paper, we have studied tunneling dynamics of the halves of a double-well trap containing a Bose-Einstein condensate. It is found that there exist step structure and macroscopic quantum self-trapping of population difference of atoms, and exist Shapiro-like steps of atomic tunneling current. Both the population difference and the atomic tunneling current depend strongly on the total number of atoms and the initial phase difference.
文摘We investigate tunneling dynamics of atomic group consisting of three atoms in Bose-Einstein condensates with Feshbach resonance. It is shown that the tunneling of the atom group depends not only on the inter-atomic nonlinear interactions and the initial number of atoms in these condensates, but also on the tunneling coupling between the atomic condensate and the three-atomic molecular condensate. It is found that besides oscillating tunneling current between the atomic condensate and the molecular condensate, the nonlinear atomic group tunneling dynamics sustains a self-maintained population imbalance: a macroscopic quantum self-trapping effect. The influence of de-coherence caused by non-condensate atoms on the tunneling dynamics is studied. It is indicated that de-coherence suppresses the atomic group tunneling.
基金supported by the National Natural Science Foundation of China(No.21573027)
文摘The prototype tetra-atomic reaction F+H2O→HF+OH plays a significant role in both atmospheric and astronomical chemistry.In this work,thermal rate coefficients of this reaction are determined with the ring polymer molecular dynamics(RPMD)method on a full-dimensional potential energy surface(PES).This PES is the most accurate one for the title reaction,as demonstrated by the correct barrier height and reaction energy,compared to the benchmark calculations by the focal point analysis and the high accuracy extrapolated ab initio thermochemistry methods.The RPMD rate coefficients are in excellent agreement with those calculated by the semiclassical transition state theory and a two-dimensional master equation technique,and some experimental measurements.As has been found in many RPMD applications,quantum effects,including tunneling and zero-point energy effects,can be efficiently and effectively captured by the RPMD method.In addition,the convergence of the results with respect to the number of beads is rapid,which is also consistent with previous RPMD applications.
基金Supported by the National Natural Science Foundation of China under Grant Nos.11274255 and 11305132Specialized Research Fund for the Doctoral Program of Higher Education of China under Grant No.20136203110001+1 种基金the Natural Science Foundation of Gansu Province under Grant No.2011GS04358Creation of Science and Technology of Northwest Normal University under Grant Nos.NWNUKJCXGC-03-48,NWNU-LKQN-12-12
文摘The tunneling dynamics of dilute boson gases with three-body interactions in a periodically driven double wells are investigated both theoretically and numerieally. In our findings, when the system is with only repulsive twobody interactions or only three-body interactions, the tunneling will be suppressed; while in the case of the coupling between two- and three-body interactions, the tunneling can be either suppressed or enhanced. Particularly, when attractive three-body interactions are twice large as repulsive two-body interactions, CDT occurs at isolated points of driving force, which is similar to the linear case. Considering different interaction, the system can experience different transformation from coherent tunneling to coherent destruction of tunneling （CDT）. The quasi-energy of the system as the function of the periodicaJ1y driving force shows a triangular structure, which provides a deep insight into the tunneling dynamics of the system.
