Static mechanical experiments were carried out on granite after and under different temperatures using an electro-hydraulic and servo-controlled material testing machine with a heating device. Variations in obvious fo...Static mechanical experiments were carried out on granite after and under different temperatures using an electro-hydraulic and servo-controlled material testing machine with a heating device. Variations in obvious form, stress-strain curve, peak strength, peak strain and elastic modulus with temperature were analyzed and the essence of rock failure modes was explored. The results indicate that, compared with granite after the high temperature treatment, the brittle-ductile transition critical temperature is lower, the densification stage is longer, the elastic modulus is smaller and the damage is larger under high temperature. In addition, the peak stress is lower and the peak strain is greater, but both of them change more obviously with the increase of temperature compared with that of granite after the high temperature treatment. Furthermore, the failure modes of granite after the high temperature treatment and under high temperature show a remarkable difference. Below 100 ℃, the failure modes of granite under both conditions are the same, presenting splitting failure. However, after 100 ℃, the failure modes of granite after the high temperature treatment and under high temperature present splitting failure and shear failure, respectively.展开更多
The isothermal oxidation behaviors of three kinds of Ni3Al-Mo based alloys at 1150 ℃ were studied.The morphology,structure and element distribution of oxide scales of the alloys were researched by scanning electron m...The isothermal oxidation behaviors of three kinds of Ni3Al-Mo based alloys at 1150 ℃ were studied.The morphology,structure and element distribution of oxide scales of the alloys were researched by scanning electron microscopy,X-ray diffraction and electron probe microanalysis.The research results show that there are three oxide layers,an outer layer of NiO,an intermediate layer mainly composed of NiO,NiAl2O4 and a small amount of NiMoO4,and an inner layer of NiAl2O4 and Al2O3.Re element was mainly distributed in the intermediate layer,which plays a role as ＂diffusion barrier＂ in the process of oxidation,and effectively reduces the diffusion rate of Al and Mo elements outward and diffusion rate of O element inward.As a result,a Al-rich oxide layer formed in the inner layer inhibits the growth of oxide layer and improves the oxidation resistance of the alloy.展开更多
In order to realize cold forging of magnesium alloys in practical application,some methods for ductility improvement of a commercial wrought AZ31B magnesium alloy(Mg-3%Al-1%Zn,mass fraction) at room temperature were s...In order to realize cold forging of magnesium alloys in practical application,some methods for ductility improvement of a commercial wrought AZ31B magnesium alloy(Mg-3%Al-1%Zn,mass fraction) at room temperature were suggested.The effects of heat treatment before forging and hydrostatic pressure during forging on the ductility were investigated in cold upsetting and cup forging.High-temperature annealing was effective to reduce the degree of the texture anisotropy of the specimen,and it was found that the forging limit of the annealed specimen was improved in cold forging.On the other hand,cold cup forging of the annealed specimen was carried out with applying counter pressure.By applying counter pressures of 100-200 MPa during forging,the critical punch stroke for forging limit of the specimen without crack was improved by 25%in punch stroke.展开更多
A computational fluid dynamics （CFD） model is carried out to describe the wire-plate electrostatic precipitator （ESP） in high temperature conditions, aiming to study the effects of high temperature on the electro-...A computational fluid dynamics （CFD） model is carried out to describe the wire-plate electrostatic precipitator （ESP） in high temperature conditions, aiming to study the effects of high temperature on the electro- hydrodynamic （EHD） characteristics. In the model, the complex interactions at high temperatures between the electric field, fluid dynamics and the particulate flow are taken into account. We apply different numerical methods for different fields, including an electric field model, Euler-Lagrange particle-laden flows model, and particle charging model. The effects of high temperature on ionic wind, EHD characteristics and collection effi- ciency are investigated. The numerical results show high temperature causes more significant effects of the ionic wind on the gas secondary flow. High viscosity of gas at high temperature makes particles follow the gas flow pattern more closely. High temperature reduces the surface electric strength, so that the mean electric strength weakens the space charging. On the contrary, there is an increase in the diffusion charging at high tem- perature compared with at low temperature. High temperature increases the ratio of mean drag force over mean electrostatic force actin~ on the ~atticles which mav contribute to a decline of collection efficiencv.展开更多
The static recrystallization of hot-deformed magnesium alloy AZ31 during isothermal annealing was studied at temperature of 503 K by optical and SEM/EBSD metallographic observation.The grain size change during isother...The static recrystallization of hot-deformed magnesium alloy AZ31 during isothermal annealing was studied at temperature of 503 K by optical and SEM/EBSD metallographic observation.The grain size change during isothermal annealing is categorized into three regions,i.e.an incubation period for grain growth,rapid grain coarsening,and normal grain growth.The number of fine grains per unit area,however,decreases remarkably even in incubation period.This leads to grain coarsening taking place continuously in the whole period of annealing.In contrast,the deformation texture scarcely changes even after full annealing at high temperatures.It is concluded that the annealing processes operating in hot-deformed magnesium alloy with continuous dynamic recrystallized grain structures can be mainly controlled by grain coarsening without texture change,that is,continuous static recrystallization.展开更多
The hot isostatic pressing-diffusion bonding(HIP-DB)was proposed to achieve the joining of CuAgZn and GH909 directly without an interlayer.The microstructure of joint was characterized by scanning electron microscope(...The hot isostatic pressing-diffusion bonding(HIP-DB)was proposed to achieve the joining of CuAgZn and GH909 directly without an interlayer.The microstructure of joint was characterized by scanning electron microscope(SEM),energy dispersive spectrometer(EDS)and X-ray diffraction(XRD).The microhardness and shear strength were tested to investigate the mechanical properties of joint.The results showed that the interface was complete,and the joint was compact,uniform and free of unbonded defects.The maximum microhardness of joint was HV 443,higher than that of two base alloys,and the average shear strength of joint reached 172 MPa.It is concluded that a good metallurgical bonding between CuAgZn and GH909 can be obtained by HIP-DB with the process parameters of 700℃,150 MPa and 3 h.展开更多
Pure hydroxyapatite（HAP）ceramic and HAP composite ceramic with B2O3 were prepared by isostatic press forming and pressureless sintering.The relationships between thermal decomposition ratio and mechanical properties...Pure hydroxyapatite（HAP）ceramic and HAP composite ceramic with B2O3 were prepared by isostatic press forming and pressureless sintering.The relationships between thermal decomposition ratio and mechanical properties for pure HAP ceramic and the composite ceramic were investigated by means of FTIR,X-ray diffraction and three-point bending method.The results indicate that the decomposition ratio of pure HAP ceramic increases with ascending the sintering temperature and nearly reaches 80%at 1 350？殆or the HAP composite ceramic,the thermal decomposition is inhibited obviously due to the addition of B2O3.The added B atoms incorporate into the crystal lattice of HAP to form solid solution,resulting in an enlargement in the crystal spacing and an improvement in the binding strength of HAP crystal cell.Thermal decomposition ratio of HAP decreases but bending strength and fracture toughness are enhanced for HAP composite ceramics.However,when the added B2O3 is more than 5%（mass fraction）,HAP decomposition is promoted and a steady？-TCP is formed due to the fact that when B atoms with higher negative electricity are combined with O,sp2 and a full-air p are formed,and those voids have a strong trend to intake of the outer electrons.So,it is very possible to occupy the place where HAP loses OH - or PO4 3- .展开更多
The thermal decomposition of abietic acid in air was investigated under non-isothermal condition using thermogravimetric analysis-differential thermal analysis （TGA-DTA） technique with heating rates of 5, 10, 15 and...The thermal decomposition of abietic acid in air was investigated under non-isothermal condition using thermogravimetric analysis-differential thermal analysis （TGA-DTA） technique with heating rates of 5, 10, 15 and 25 K.min-~. The non-isothermal kinetic parameters were obtained via the analysis of the thermogravimetric and differential thermogravimetric （TG-DTG） curves by using Flynn-Wall-Ozawa method and Kissinger method. The thermal decomposition mechanism of abietic acid was studied with four integral methods （Satava-Sestak, MacCallum-Tanner, ordinary integral and Agrawal）. The results show that the thermal decomposition mechanism is nu- cleation and growth, and the mechanism function is Avrami-Erofeev equation with n equates 1/2. The activation energy and the pre-exponential factor are 64.04 kJ.mol^-1 and 5.89×10^5 s^-1, respectively.展开更多
基金Projects(51304241,11472311,51322403)supported by the National Natural Science Foundation of ChinaProject(2015CX005)supported by Innovation Driven Plan of Central South University,China+1 种基金Project(2016zzts456)supported by Independent Exploration and Innovation Foundation of Central South University,ChinaProject(2015CB060200)supported by the National Basic Research Program of China
文摘Static mechanical experiments were carried out on granite after and under different temperatures using an electro-hydraulic and servo-controlled material testing machine with a heating device. Variations in obvious form, stress-strain curve, peak strength, peak strain and elastic modulus with temperature were analyzed and the essence of rock failure modes was explored. The results indicate that, compared with granite after the high temperature treatment, the brittle-ductile transition critical temperature is lower, the densification stage is longer, the elastic modulus is smaller and the damage is larger under high temperature. In addition, the peak stress is lower and the peak strain is greater, but both of them change more obviously with the increase of temperature compared with that of granite after the high temperature treatment. Furthermore, the failure modes of granite after the high temperature treatment and under high temperature show a remarkable difference. Below 100 ℃, the failure modes of granite under both conditions are the same, presenting splitting failure. However, after 100 ℃, the failure modes of granite after the high temperature treatment and under high temperature present splitting failure and shear failure, respectively.
基金Project(50971012) supported by the National Natural Science Foundation of China
文摘The isothermal oxidation behaviors of three kinds of Ni3Al-Mo based alloys at 1150 ℃ were studied.The morphology,structure and element distribution of oxide scales of the alloys were researched by scanning electron microscopy,X-ray diffraction and electron probe microanalysis.The research results show that there are three oxide layers,an outer layer of NiO,an intermediate layer mainly composed of NiO,NiAl2O4 and a small amount of NiMoO4,and an inner layer of NiAl2O4 and Al2O3.Re element was mainly distributed in the intermediate layer,which plays a role as ＂diffusion barrier＂ in the process of oxidation,and effectively reduces the diffusion rate of Al and Mo elements outward and diffusion rate of O element inward.As a result,a Al-rich oxide layer formed in the inner layer inhibits the growth of oxide layer and improves the oxidation resistance of the alloy.
基金supported in part by the Japan Ministry of Education,Culture,Sports,Science and Technology,with Grant-in-Aid for Young Scientists(B)
文摘In order to realize cold forging of magnesium alloys in practical application,some methods for ductility improvement of a commercial wrought AZ31B magnesium alloy(Mg-3%Al-1%Zn,mass fraction) at room temperature were suggested.The effects of heat treatment before forging and hydrostatic pressure during forging on the ductility were investigated in cold upsetting and cup forging.High-temperature annealing was effective to reduce the degree of the texture anisotropy of the specimen,and it was found that the forging limit of the annealed specimen was improved in cold forging.On the other hand,cold cup forging of the annealed specimen was carried out with applying counter pressure.By applying counter pressures of 100-200 MPa during forging,the critical punch stroke for forging limit of the specimen without crack was improved by 25%in punch stroke.
基金Supported by the National Natural Science Foundation of China(51176170,51390490,51125025)the Natural Science Foundation of Zhejiang Province(LR12E06001)partially supported by the Fundamental Research Funds for the Central Universities
文摘A computational fluid dynamics （CFD） model is carried out to describe the wire-plate electrostatic precipitator （ESP） in high temperature conditions, aiming to study the effects of high temperature on the electro- hydrodynamic （EHD） characteristics. In the model, the complex interactions at high temperatures between the electric field, fluid dynamics and the particulate flow are taken into account. We apply different numerical methods for different fields, including an electric field model, Euler-Lagrange particle-laden flows model, and particle charging model. The effects of high temperature on ionic wind, EHD characteristics and collection effi- ciency are investigated. The numerical results show high temperature causes more significant effects of the ionic wind on the gas secondary flow. High viscosity of gas at high temperature makes particles follow the gas flow pattern more closely. High temperature reduces the surface electric strength, so that the mean electric strength weakens the space charging. On the contrary, there is an increase in the diffusion charging at high tem- perature compared with at low temperature. High temperature increases the ratio of mean drag force over mean electrostatic force actin~ on the ~atticles which mav contribute to a decline of collection efficiencv.
文摘The static recrystallization of hot-deformed magnesium alloy AZ31 during isothermal annealing was studied at temperature of 503 K by optical and SEM/EBSD metallographic observation.The grain size change during isothermal annealing is categorized into three regions,i.e.an incubation period for grain growth,rapid grain coarsening,and normal grain growth.The number of fine grains per unit area,however,decreases remarkably even in incubation period.This leads to grain coarsening taking place continuously in the whole period of annealing.In contrast,the deformation texture scarcely changes even after full annealing at high temperatures.It is concluded that the annealing processes operating in hot-deformed magnesium alloy with continuous dynamic recrystallized grain structures can be mainly controlled by grain coarsening without texture change,that is,continuous static recrystallization.
基金The authors are grateful for the financial support from the Advanced Space Propulsion Technology Laboratory Open Fund,China(LabASP-2018-16).
文摘The hot isostatic pressing-diffusion bonding(HIP-DB)was proposed to achieve the joining of CuAgZn and GH909 directly without an interlayer.The microstructure of joint was characterized by scanning electron microscope(SEM),energy dispersive spectrometer(EDS)and X-ray diffraction(XRD).The microhardness and shear strength were tested to investigate the mechanical properties of joint.The results showed that the interface was complete,and the joint was compact,uniform and free of unbonded defects.The maximum microhardness of joint was HV 443,higher than that of two base alloys,and the average shear strength of joint reached 172 MPa.It is concluded that a good metallurgical bonding between CuAgZn and GH909 can be obtained by HIP-DB with the process parameters of 700℃,150 MPa and 3 h.
文摘Pure hydroxyapatite（HAP）ceramic and HAP composite ceramic with B2O3 were prepared by isostatic press forming and pressureless sintering.The relationships between thermal decomposition ratio and mechanical properties for pure HAP ceramic and the composite ceramic were investigated by means of FTIR,X-ray diffraction and three-point bending method.The results indicate that the decomposition ratio of pure HAP ceramic increases with ascending the sintering temperature and nearly reaches 80%at 1 350？殆or the HAP composite ceramic,the thermal decomposition is inhibited obviously due to the addition of B2O3.The added B atoms incorporate into the crystal lattice of HAP to form solid solution,resulting in an enlargement in the crystal spacing and an improvement in the binding strength of HAP crystal cell.Thermal decomposition ratio of HAP decreases but bending strength and fracture toughness are enhanced for HAP composite ceramics.However,when the added B2O3 is more than 5%（mass fraction）,HAP decomposition is promoted and a steady？-TCP is formed due to the fact that when B atoms with higher negative electricity are combined with O,sp2 and a full-air p are formed,and those voids have a strong trend to intake of the outer electrons.So,it is very possible to occupy the place where HAP loses OH - or PO4 3- .
基金Supported by the National＇Natural Science Foundation of China （20976031, 31060102）, the Natural Science Foundation of Guangxi Autonomous Region （2011GXNSFD018011,0991030, 2010GXNSFA013042）, the Science and Technology Program Foundation of Wuzhou City （200901011）, the Scientific and Technological Project of Guangxi （1099060-2）, the Scientific Research Innovative Foundation of Doctor Candidate （105930901008）.
文摘The thermal decomposition of abietic acid in air was investigated under non-isothermal condition using thermogravimetric analysis-differential thermal analysis （TGA-DTA） technique with heating rates of 5, 10, 15 and 25 K.min-~. The non-isothermal kinetic parameters were obtained via the analysis of the thermogravimetric and differential thermogravimetric （TG-DTG） curves by using Flynn-Wall-Ozawa method and Kissinger method. The thermal decomposition mechanism of abietic acid was studied with four integral methods （Satava-Sestak, MacCallum-Tanner, ordinary integral and Agrawal）. The results show that the thermal decomposition mechanism is nu- cleation and growth, and the mechanism function is Avrami-Erofeev equation with n equates 1/2. The activation energy and the pre-exponential factor are 64.04 kJ.mol^-1 and 5.89×10^5 s^-1, respectively.
