The authors have studied the effect of a magnetic field on Baldwin's rules. The authors have proposed a new mechanism that takes into account the effect of the angle and energy endo- or exo-cyclization. The authors p...The authors have studied the effect of a magnetic field on Baldwin's rules. The authors have proposed a new mechanism that takes into account the effect of the angle and energy endo- or exo-cyclization. The authors propose to extend the rule Bouldwin not only for sp^3-, sp^2- and sp- orbits, but and for d^1 - d^10 and f^1 - f^14 elements of I-VIII of the Periodic table.展开更多
文摘The authors have studied the effect of a magnetic field on Baldwin's rules. The authors have proposed a new mechanism that takes into account the effect of the angle and energy endo- or exo-cyclization. The authors propose to extend the rule Bouldwin not only for sp^3-, sp^2- and sp- orbits, but and for d^1 - d^10 and f^1 - f^14 elements of I-VIII of the Periodic table.