The title compound [NdK（btec）（H2O）2]n 1 was synthesized via the hydrothermal reaction of Zn（OAc）E·H2O, Nd（NO3）3 and KOH with 1,2,4,5-benzenetetra-carboxylic acid （H4btec）, and characterized by elemental...The title compound [NdK（btec）（H2O）2]n 1 was synthesized via the hydrothermal reaction of Zn（OAc）E·H2O, Nd（NO3）3 and KOH with 1,2,4,5-benzenetetra-carboxylic acid （H4btec）, and characterized by elemental analysis and infrared spectra. The crystal of 1 crystallizes in monoclinic, space group P21/c with a = 8.9023（3）, b = 7.8954（1）, c = 17.6249（5）A,β= 91.857（1）°, V= 1238.16（6）A^3, Z = 4, C10H6KNdO10, Mr= 469.49, Dc = 2.519 g/cm^3, F（000） = 900 andμ（MoKa） = 4.585 mm^-1. The final R = 0.0404 and wR = 0.0832 for 2197 observed reflections with I 〉 2σ（I） and R = 0.0431 and wR = 0.0854 for all data. X-ray diffraction reveals that the btec ligand serves as a μ16-bridging ligand to link the Nd（Ⅲ） and K（Ⅰ） atoms into a three-dimensional coordination polymer. Photoluminescent investigation shows that the title compound displays strong emission in the blue region, which may be attributed to an intraligand emission state.展开更多
Accumulating evidence has demonstrated that the sodium-potassium-chloride co-transporter 1 and potassium-chloride co-transporter 2 have a role in the modulation of pain transmission at the spinal level through chlorid...Accumulating evidence has demonstrated that the sodium-potassium-chloride co-transporter 1 and potassium-chloride co-transporter 2 have a role in the modulation of pain transmission at the spinal level through chloride regulation in the pain pathway and by effecting neuronal excitability and pain sensitization. The present study aimed to investigate the analgesic effect of the speciifc sodium-potassium-chloride co-transporter 1 inhibitor bumetanide, and the change in spinal sodium-potassium-chloride co-transporter 1 and potassium-chloride co-transporter 2 expression in a rat model of incisional pain. Results showed that intrathecal bumetanide could decrease cumulative pain scores, and could increase thermal and mechanical pain thresholds in a rat model of incisional pain. Sodium-potassium-chloride co-transporter 1 expression in-creased in neurons from dorsal root ganglion and the deep laminae of the ipsilateral dorsal horn following incision. By contrast, potassium-chloride co-transporter 2 expression decreased in neurons of the deep laminae from the ipsilateral dorsal horn. These ifndings suggest that spinal sodium-potassium-chloride co-transporter 1 expression was up-regulated and spinal potassi-um-chloride co-transporter 2 expression was down-regulated following incision. Intrathecal bumetanide has analgesic effects on incisional pain through inhibition of sodium-potassi-um-chloride co-transporter 1.展开更多
A high sensitive flow-injection chemiluminescence （FI-CL） method for the determination of tryptophan has been developed. The method is based on the chemiluminescence reaction of galangin-potassium permanganate-trypt...A high sensitive flow-injection chemiluminescence （FI-CL） method for the determination of tryptophan has been developed. The method is based on the chemiluminescence reaction of galangin-potassium permanganate-tryptophan in polyphosphoric acid （PPA） media. Under the optimized conditions, tryptophan was determined in the range 0.05-10 μg/mL with the detection limit （3tr） of 5.0 × 10^-3 μg/mL. The relative standard deviation （RSD） was 1.0% for 11 replicate determinations of 1.0 μg/mL tryptophan. Three synthetic samples were determined selectively with recoveries in the range from 99.6% to 102.0% in the presence of other amino acids.展开更多
This study was undertaken to measure the impact of fertilizers (nitrogen-potassium) on the growth and the development of plantain banana. Different doses of fertilizers (T2, T3, T4, T5 and T6) were applied to two hybr...This study was undertaken to measure the impact of fertilizers (nitrogen-potassium) on the growth and the development of plantain banana. Different doses of fertilizers (T2, T3, T4, T5 and T6) were applied to two hybrid varieties (PITA 3 and FHIA 21) and a traditional variety (CORNE 1) on an experimental split plot plan with a planting density of 2500 plants per hectare. Results showed that fertilizers improve parameters of plantain than control (T1). T6 with high potassium content (240 kg<span style="white-space:nowrap;">·</span>ha<sup><span style="white-space:nowrap;">−</span>1</sup> N and 987 kg<span style="white-space:nowrap;">·</span>ha<sup><span style="white-space:nowrap;">−</span>1</sup> K) improved the growth (35.72 ± 0.95 cm<span style="white-space:nowrap;">·</span>month<sup><span style="white-space:nowrap;">−</span>1</sup>) and the widening (9.56 ± 0.17 cm<span style="white-space:nowrap;">·</span>month<sup><span style="white-space:nowrap;">−</span>1</sup>) of PITA 3, and performed FHIA 21 agronomic parameters by reducing the length of the production cycle and increased the length of fruits. T2 treatment improved FHIA 21 agronomic and yield parameters. Also, the weight of CORNE 1 regimens (9.00 ± 0.67 kg) and fruits (296.59 ± 4.50 g), the length (33.37 ± 0.31 cm) and the circumference (14.73 ± 0.31 cm) increased with T2. T4 induced shorter production cycle of PITA 3 (390.40 ± 0.67 cm<span style="white-space:nowrap;">·</span>month<sup><span style="white-space:nowrap;">−</span>1</sup>), improved PITA3 regimens weight (10.33 ± 0.44 kg) and the number of hands by regimen (6.00 ± 0.00) of FHIA 21. T3 with weak nitrogen content (120 kg<span style="white-space:nowrap;">·</span>ha<sup><span style="white-space:nowrap;">−</span>1</sup> N and 658 kg<span style="white-space:nowrap;">·</span>ha<sup><span style="white-space:nowrap;">−</span>1</sup> K) improved the characteristics of PITA 3 fruits notably, the weight (176.09 ± 2.96 g) and the circumference (13.87 ± 0.89 cm). T5 (240 kg<span style="white-space:nowrap;">·</span>ha<sup><span style="white-space:nowrap;">−</span>1</sup> N and 329 kg<span style="white-space:nowrap;">·</span>ha<sup><span style="white-space:nowrap;">−</span>1</sup> K) performed CORNE 1 trees number of sheets (3.85 ± 0.16). CORNE 1 cycle production with T6 treatment was 137.80 days longer than those of T2 treatment (483 ± 3.50 days). In conclusion, with T2 and T6, growth parameters were globally improved in FHIA 21 by the regimen largest and the higher number of fingers, and productivity parameters were improved in CORNE 1 by the heaviest, the longest and the thickest of the fruits.展开更多
An indirect, sensitive and accurate method for the determination of trace amounts of hydrazine is described. In this proposed the spectrophotometric method is based on its reduction properties of hydrazine with a know...An indirect, sensitive and accurate method for the determination of trace amounts of hydrazine is described. In this proposed the spectrophotometric method is based on its reduction properties of hydrazine with a known concentration of potassium permanganate to reduce the colour. The absorbance of unreduced permanganate is measured the colour difference at different wavelengths 546 and 526 nm which show an absorption spectrum with hydrazine. Hydrazine can be determined in the range of 100 - 700 μg/ml with correlation coefficient of 0.999 and relative standard deviation 1%. The method is successfully applied for the determination of hydrazine in water streams in nuclear reactors/purex process/boiler water and polluted water samples.展开更多
The crystal structure of K7Na3H2W12O426H2O was determined by Xray crystallography and refined to R=0.0864 based on 7024 observed reflections (I>2(I)). The crystallographic parameters are a=11.755(2), b=13.0493(3), ...The crystal structure of K7Na3H2W12O426H2O was determined by Xray crystallography and refined to R=0.0864 based on 7024 observed reflections (I>2(I)). The crystallographic parameters are a=11.755(2), b=13.0493(3), c=16.289(3); =77.13(3), =82.92(3), =89.65(3), triclinic, space group, P1 , V=2416.7(8)3, Z=2, Mr=3330.98, Dcal=4.578Mg/m3, F(000)=2904, (MoK)=29.170mm-1, T=293K. Two independent polyanions are centered respectively at 1,1,1/2 and 1/2, 1/2, 0, approximately perpendicular to each other with dihedral angle between the equatorial planes of the molecules at 96. K+ and Na+ respectively occupy the clefts of the two discrete polyanions.展开更多
基金the Youth Talent Foundation of Fujian Province(2006F3010330083)
文摘The title compound [NdK（btec）（H2O）2]n 1 was synthesized via the hydrothermal reaction of Zn（OAc）E·H2O, Nd（NO3）3 and KOH with 1,2,4,5-benzenetetra-carboxylic acid （H4btec）, and characterized by elemental analysis and infrared spectra. The crystal of 1 crystallizes in monoclinic, space group P21/c with a = 8.9023（3）, b = 7.8954（1）, c = 17.6249（5）A,β= 91.857（1）°, V= 1238.16（6）A^3, Z = 4, C10H6KNdO10, Mr= 469.49, Dc = 2.519 g/cm^3, F（000） = 900 andμ（MoKa） = 4.585 mm^-1. The final R = 0.0404 and wR = 0.0832 for 2197 observed reflections with I 〉 2σ（I） and R = 0.0431 and wR = 0.0854 for all data. X-ray diffraction reveals that the btec ligand serves as a μ16-bridging ligand to link the Nd（Ⅲ） and K（Ⅰ） atoms into a three-dimensional coordination polymer. Photoluminescent investigation shows that the title compound displays strong emission in the blue region, which may be attributed to an intraligand emission state.
基金supported by a grant from Guangzhou Medical University,No.2008C24
文摘Accumulating evidence has demonstrated that the sodium-potassium-chloride co-transporter 1 and potassium-chloride co-transporter 2 have a role in the modulation of pain transmission at the spinal level through chloride regulation in the pain pathway and by effecting neuronal excitability and pain sensitization. The present study aimed to investigate the analgesic effect of the speciifc sodium-potassium-chloride co-transporter 1 inhibitor bumetanide, and the change in spinal sodium-potassium-chloride co-transporter 1 and potassium-chloride co-transporter 2 expression in a rat model of incisional pain. Results showed that intrathecal bumetanide could decrease cumulative pain scores, and could increase thermal and mechanical pain thresholds in a rat model of incisional pain. Sodium-potassium-chloride co-transporter 1 expression in-creased in neurons from dorsal root ganglion and the deep laminae of the ipsilateral dorsal horn following incision. By contrast, potassium-chloride co-transporter 2 expression decreased in neurons of the deep laminae from the ipsilateral dorsal horn. These ifndings suggest that spinal sodium-potassium-chloride co-transporter 1 expression was up-regulated and spinal potassi-um-chloride co-transporter 2 expression was down-regulated following incision. Intrathecal bumetanide has analgesic effects on incisional pain through inhibition of sodium-potassi-um-chloride co-transporter 1.
文摘A high sensitive flow-injection chemiluminescence （FI-CL） method for the determination of tryptophan has been developed. The method is based on the chemiluminescence reaction of galangin-potassium permanganate-tryptophan in polyphosphoric acid （PPA） media. Under the optimized conditions, tryptophan was determined in the range 0.05-10 μg/mL with the detection limit （3tr） of 5.0 × 10^-3 μg/mL. The relative standard deviation （RSD） was 1.0% for 11 replicate determinations of 1.0 μg/mL tryptophan. Three synthetic samples were determined selectively with recoveries in the range from 99.6% to 102.0% in the presence of other amino acids.
文摘This study was undertaken to measure the impact of fertilizers (nitrogen-potassium) on the growth and the development of plantain banana. Different doses of fertilizers (T2, T3, T4, T5 and T6) were applied to two hybrid varieties (PITA 3 and FHIA 21) and a traditional variety (CORNE 1) on an experimental split plot plan with a planting density of 2500 plants per hectare. Results showed that fertilizers improve parameters of plantain than control (T1). T6 with high potassium content (240 kg<span style="white-space:nowrap;">·</span>ha<sup><span style="white-space:nowrap;">−</span>1</sup> N and 987 kg<span style="white-space:nowrap;">·</span>ha<sup><span style="white-space:nowrap;">−</span>1</sup> K) improved the growth (35.72 ± 0.95 cm<span style="white-space:nowrap;">·</span>month<sup><span style="white-space:nowrap;">−</span>1</sup>) and the widening (9.56 ± 0.17 cm<span style="white-space:nowrap;">·</span>month<sup><span style="white-space:nowrap;">−</span>1</sup>) of PITA 3, and performed FHIA 21 agronomic parameters by reducing the length of the production cycle and increased the length of fruits. T2 treatment improved FHIA 21 agronomic and yield parameters. Also, the weight of CORNE 1 regimens (9.00 ± 0.67 kg) and fruits (296.59 ± 4.50 g), the length (33.37 ± 0.31 cm) and the circumference (14.73 ± 0.31 cm) increased with T2. T4 induced shorter production cycle of PITA 3 (390.40 ± 0.67 cm<span style="white-space:nowrap;">·</span>month<sup><span style="white-space:nowrap;">−</span>1</sup>), improved PITA3 regimens weight (10.33 ± 0.44 kg) and the number of hands by regimen (6.00 ± 0.00) of FHIA 21. T3 with weak nitrogen content (120 kg<span style="white-space:nowrap;">·</span>ha<sup><span style="white-space:nowrap;">−</span>1</sup> N and 658 kg<span style="white-space:nowrap;">·</span>ha<sup><span style="white-space:nowrap;">−</span>1</sup> K) improved the characteristics of PITA 3 fruits notably, the weight (176.09 ± 2.96 g) and the circumference (13.87 ± 0.89 cm). T5 (240 kg<span style="white-space:nowrap;">·</span>ha<sup><span style="white-space:nowrap;">−</span>1</sup> N and 329 kg<span style="white-space:nowrap;">·</span>ha<sup><span style="white-space:nowrap;">−</span>1</sup> K) performed CORNE 1 trees number of sheets (3.85 ± 0.16). CORNE 1 cycle production with T6 treatment was 137.80 days longer than those of T2 treatment (483 ± 3.50 days). In conclusion, with T2 and T6, growth parameters were globally improved in FHIA 21 by the regimen largest and the higher number of fingers, and productivity parameters were improved in CORNE 1 by the heaviest, the longest and the thickest of the fruits.
文摘An indirect, sensitive and accurate method for the determination of trace amounts of hydrazine is described. In this proposed the spectrophotometric method is based on its reduction properties of hydrazine with a known concentration of potassium permanganate to reduce the colour. The absorbance of unreduced permanganate is measured the colour difference at different wavelengths 546 and 526 nm which show an absorption spectrum with hydrazine. Hydrazine can be determined in the range of 100 - 700 μg/ml with correlation coefficient of 0.999 and relative standard deviation 1%. The method is successfully applied for the determination of hydrazine in water streams in nuclear reactors/purex process/boiler water and polluted water samples.
文摘The crystal structure of K7Na3H2W12O426H2O was determined by Xray crystallography and refined to R=0.0864 based on 7024 observed reflections (I>2(I)). The crystallographic parameters are a=11.755(2), b=13.0493(3), c=16.289(3); =77.13(3), =82.92(3), =89.65(3), triclinic, space group, P1 , V=2416.7(8)3, Z=2, Mr=3330.98, Dcal=4.578Mg/m3, F(000)=2904, (MoK)=29.170mm-1, T=293K. Two independent polyanions are centered respectively at 1,1,1/2 and 1/2, 1/2, 0, approximately perpendicular to each other with dihedral angle between the equatorial planes of the molecules at 96. K+ and Na+ respectively occupy the clefts of the two discrete polyanions.
