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MC-ICP-MS测定铀系定年标样的^230Th年龄 被引量:18
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作者 王立胜 马志邦 +2 位作者 程海 段武辉 肖举乐 《质谱学报》 EI CAS CSCD 北大核心 2016年第3期262-272,共11页
本研究利用Neptune Plus型多接收电感耦合等离子体质谱仪(MC-ICP-MS)测定了U和Th标准溶液的同位素比值及U系定年标样的^(230)Th年龄。结果显示:CRM 112A和Harwell Uraninite-1(HU-1)的234 U/238 U原子比值分别为(52.860±0.042)... 本研究利用Neptune Plus型多接收电感耦合等离子体质谱仪(MC-ICP-MS)测定了U和Th标准溶液的同位素比值及U系定年标样的^(230)Th年龄。结果显示:CRM 112A和Harwell Uraninite-1(HU-1)的234 U/238 U原子比值分别为(52.860±0.042)×10^(-6)(δ234 U=(-38.36±0.77)‰,n=17)和(54.911±0.007)×10-6(δ234 U=(-1.04±0.13)‰,n=27),实验数据在2σ不确定范围内与国际同类实验室一致;NBS Th标准,0.6pg ^(230)Th测试精度优于3‰;5个碳酸盐标准样品76001、GBW04412、RKM-6、RKM-5和RKM-4的230 Th年龄分别为(47 520±220)y、(86 880±340)y、(130 830±550)y、(129 380±480)y和(197 970±1 590)y,与美国明尼苏达大学、西安交通大学同类实验室测定的数据具有良好的重复性。上述数据表明,本实验建立的MC-ICP-MS法230 Th定年技术可应用于中晚更新世以来碳酸盐的U-Th定年与示踪研究。 展开更多
关键词 多接收电感耦合等离子体质谱(MC-ICP-MS) U-Th同位素比值 ^230th测年 U系定年标样
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高分辨电感耦合等离子体质谱法测定铀矿石样品中^234U/^238U、^230Th/^232Th和^228Ra/^226Ra同位素比值 被引量:8
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作者 郭冬发 张彦辉 +4 位作者 武朝晖 朱明燕 王玉学 崔建勇 谭靖 《岩矿测试》 CAS CSCD 北大核心 2009年第2期101-107,共7页
采用氢氟酸-硝酸-盐酸混合酸密闭消解含铀矿石样品,用阴离子交换树脂、阳离子交换树脂和锶特效树脂逐级分离富集铀、钍和镭。使用高分辨电感耦合等离子体质谱(HR-ICPMS)测定分离纯化液中234U/238U2、30Th/232Th和228Ra/226Ra同位素。比... 采用氢氟酸-硝酸-盐酸混合酸密闭消解含铀矿石样品,用阴离子交换树脂、阳离子交换树脂和锶特效树脂逐级分离富集铀、钍和镭。使用高分辨电感耦合等离子体质谱(HR-ICPMS)测定分离纯化液中234U/238U2、30Th/232Th和228Ra/226Ra同位素。比值的测量精密度取决于比值的大小和对应核素浓度的大小。对质量浓度为10 ng/mL天然铀测量液,234U/238U的测量精密度优于1.2%;对230Th质量浓度为0.6ng/mL且230Th和232Th质量浓度接近的测量液,230Th/232Th的测量精密度为1.2%;对228Ra质量浓度为0.48 pg/mL且228Ra和226Ra质量浓度接近的测量液,228Ra/226Ra的测量精密度为4.0%。 展开更多
关键词 ^234U/^238U ^230th/^232Th ^228Ra/^226Ra 铀矿石 高分辨电感耦合等离子体质谱法
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山东省微山县郗山稀土矿床成矿年代学新进展
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作者 张鹏 刘珊珊 +6 位作者 兰君 李衣鑫 邢楠 刘敬杰 刘袁坤 康志强 杨锋 《地质科技通报》 CAS CSCD 北大核心 2024年第1期51-62,共12页
山东省微山县郗山稀土矿床位于华北板块东南缘,是一个以轻稀土为主的岩浆热液型稀土矿床,目前为我国第三大轻稀土矿床,对其成矿年龄还存在争议。为此,以郗山稀土矿最新勘探钻孔矿石样品为研究对象,通过野外调查、矿物学和年代学研究,采... 山东省微山县郗山稀土矿床位于华北板块东南缘,是一个以轻稀土为主的岩浆热液型稀土矿床,目前为我国第三大轻稀土矿床,对其成矿年龄还存在争议。为此,以郗山稀土矿最新勘探钻孔矿石样品为研究对象,通过野外调查、矿物学和年代学研究,采用氟碳铈矿Th-Pb同位素定年精确厘定了郗山稀土矿的成矿年代。5件氟碳铈矿Th-Pb同位素定年结果表明,郗山稀土矿床成矿时代可分为2期:早期为(125.5±0.5)~(122.2±0.5)Ma,晚期为(112.3±0.6)Ma,其中早期年龄与前人得出的矿床成矿年龄基本一致,而晚期成矿年龄则是首次报道,表明郗山稀土矿床可能存在2期成矿活动,值得关注并开展进一步工作。 展开更多
关键词 郗山稀土矿床 Th-Pb同位素定年 氟碳铈矿 微山县 山东省
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川北米仓山隆起构造-热演化特征
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作者 张建勇 常健 +3 位作者 李文正 付小东 杨磊 和源 《沉积与特提斯地质》 CAS CSCD 北大核心 2024年第1期58-70,共13页
本文基于实测锆石(U-Th)/He和磷灰石裂变径迹年龄的联合热史模拟明确了米仓山隆起自新元古代以来的构造-热演化史。米仓山隆起前寒武系样品锆石(U-Th)/He年龄和磷灰石裂变径迹年龄分别为190~138 Ma和106.1~120.6 Ma,均小于地层年龄或成... 本文基于实测锆石(U-Th)/He和磷灰石裂变径迹年龄的联合热史模拟明确了米仓山隆起自新元古代以来的构造-热演化史。米仓山隆起前寒武系样品锆石(U-Th)/He年龄和磷灰石裂变径迹年龄分别为190~138 Ma和106.1~120.6 Ma,均小于地层年龄或成岩结晶年龄,有效地记录了早期热信息。热史模拟结果表明米仓山隆起自新元古代以来主要经历了早侏罗世—早白垩世和晚中新世至今两期快速冷却事件,分别与扬子-华北板块碰撞和印度-欧亚板块碰撞的东扩作用有关,而白垩纪—早中新世的缓慢冷却过程则与当时的古夷平面发育有关。本文不仅丰富完善了川北地区构造-热演化成果,而且对于该地区下一步油气勘探具有重要的指导意义。 展开更多
关键词 四川盆地 米仓山隆起 锆石(U-Th)/He 磷灰石裂变径迹 热史模拟 构造-热演化
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印度-欧亚板块碰撞带中下地壳分层流动与减薄:来自希夏邦马峰地区藏南拆离系构造解析的证据
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作者 闫佳鑫 刘俊来 +1 位作者 周保军 闻俊豪 《岩石学报》 SCIE EI CAS CSCD 北大核心 2024年第5期1475-1488,共14页
造山带中下地壳物质流动是造山带地壳变形的重要表现,它制约着造山作用过程。印度-欧亚板块碰撞带内藏南拆离系为理解陆-陆板块会聚过程中中下地壳物质流动提供了范例。本项研究围绕喜马拉雅造山带中段希夏邦马峰地区藏南拆离系开展构... 造山带中下地壳物质流动是造山带地壳变形的重要表现,它制约着造山作用过程。印度-欧亚板块碰撞带内藏南拆离系为理解陆-陆板块会聚过程中中下地壳物质流动提供了范例。本项研究围绕喜马拉雅造山带中段希夏邦马峰地区藏南拆离系开展构造解析、显微构造观察和淡色花岗岩独居石U-Th-Pb年代学分析。结果表明希夏邦马峰地区藏南拆离系为一宽约2km的韧性剪切带,剪切变形岩石具有显著的分层流动特征。藏南拆离系新生代时期经历了两阶段塑性变形:D 1期变形表现为面理S 1、对称状透镜体和层间褶皱F 1的发育;D 2期变形表现为糜棱面理S 2、近E-W向拉伸线理L 2、不对称旋转碎斑和透镜体及褶皱的发育。运动学标志表明D 2期变形为上盘向东的运动学特征。淡色花岗岩独居石U-Th-Pb测年分析获得三组年龄:32.26±0.29Ma、22.31±0.18Ma和15.54±0.11Ma,这三组年龄的淡色花岗岩分别表现出D 1期变形、D 2期变形和未变形特征。结合前人已发表数据,本文得出藏南拆离系ca.35~26Ma发生以纯剪为主的剪切变形(D 1期),ca.26~15Ma发生以单剪为主的剪切变形(D 2期)。D 1-D 2期变形为一递进剪切变形,二者可能归咎于印度-欧亚板块碰撞过程中中下地壳固态分层流动。 展开更多
关键词 构造解析 独居石U-Th-Pb测年 希夏邦马峰地区 藏南拆离系 中下地壳分层流动
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Magnetostratigraphy and ^(230)Th dating of a drill core from the southeastern Qaidam Basin:Salt lake evolution and tectonic implications 被引量:6
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作者 An-Dong Chen Mian-Ping Zheng +2 位作者 Hai-Tao Yao Kui Su Jian-Ming Xu 《Geoscience Frontiers》 SCIE CAS CSCD 2018年第3期943-953,共11页
The Qarhan Salt Lake area is the Quaternary depocenter of the Qaidam Basin, and carries thick lacustrine sediments, as well as rich potassium and magnesium salt deposits. The abundant resources and thick sediments in ... The Qarhan Salt Lake area is the Quaternary depocenter of the Qaidam Basin, and carries thick lacustrine sediments, as well as rich potassium and magnesium salt deposits. The abundant resources and thick sediments in this lake provide an ideal place for the study of biogas formation and preservation, salt lake evolution, and the uplift of the Tibetan Plateau. In this study, we attempt to construct a paleomagnetic and ^(230)Th age model and to obtain information on tectonic activity and salt lake evolution through detailed studies on a 1300-m-long drill core(15DZK01) from the northwestern margin of the Qarhan Salt Lake area(Dongling Lake). Based on gypsum ^(230)Th dating, the age of the uppermost clastic deposit was calculated to be around 0.052 Ma. The polarity sequence consist of 13 pairs of normal and reversed zones,which can be correlated with subchrons C2r.1r-C1n of the geomagnetic polarity timescale(GPTS 2012)(from ~2.070 Ma to ~0.052 Ma). Sedimentary characteristics indicate that Dongling Lake witnessed freshwater environment between ~ 2.070 Ma and 1.546 Ma. During this period, the sedimentary record reflects primarily lakeshore, shallow-water and swamp environments, representing favourable conditions for the formation of hydrocarbon source rocks. Between 1.546 Ma and ~ 0.052 Ma, the Dongling Lake was in sulphate deposition stage, which contrasts with the central Qarhan Salt Lake area, where this stage did not occur in the meantime. During this stage, Dongling Lake was in a shallow saltwater lake environment, but several periods of reduced salinity occurred during this stage. During the late Pleistocene at ~0.052 Ma, the Dongling Lake experienced uplift due to tectonic activity, and saltwater migrated through the Sanhu Fault to the central Qarhan Salt Lake area, resulting in the absence of halite deposition stage. The residual saline water was concentrated into magnesium-rich brine due to the lack of freshwater, and few potassium salt deposits occur in the Dongling Lake area. 展开更多
关键词 Qaidam Basin MAGNETOSTRATIGRAPHY 230th dating Salt lake EVOLUTION TECTONIC activity
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U-Th-Pb behavior of zircons under high-grade metamorphic conditions:A case study of zircon dating of meta-diorite near Qixia,eastern Shandong 被引量:27
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作者 Yusheng Wan Dunyi Liu +2 位作者 Chunyan Dong Shoujie Liu Shijin Wang 《Geoscience Frontiers》 SCIE CAS 2011年第2期137-146,共10页
This paper carried out a study on U—Th—Pb behavior of zircons in a'dry'rock system during high-grade metamorphism in the Archean basement of eastern Shandong.The studied sample has a mineral assemblage of pl... This paper carried out a study on U—Th—Pb behavior of zircons in a'dry'rock system during high-grade metamorphism in the Archean basement of eastern Shandong.The studied sample has a mineral assemblage of plagioclase + K-feldspar + clinopyroxene + biotite + quartz and its protolith is considered to be diorite.The zircons are stubby,equant or irregular in shape and show fir-leaf, sectorial,banded or oscillatory zoning.They contain inclusions,including mineral assemblages of clinopyroxene + orthopyroxene + hornblende + quartz and plagioclase + K-feldspar + biotite + quartz. Fifty SHRIMP analyses were performed on 34 zircon grains,which commonly yielded high Th/U ratios (mostly>0.5).Most analyses are distributed along concordia from 2.54 to 2.25 Ga,with the youngest age being~1.95 Ga.Compositions and ages show large variations even in a same zircon grain.Combined with early studies,conclusions can be drawn as follows:1) the diorite underwent two episodes of high-grade metamorphism.at the end of the Neoarchean and the Paleoproterozoic(~2.50 Ga and~1.95 Ga or slightly later):2) high-grade metamorphism in a'dry'rock system may partially reset the U—Th—Pb system of zircons and.in this case,the ages between the oldest and youngest 展开更多
关键词 变质条件 闪长岩 锆石 行为 Pb 案例 山东 SHRIMP
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Accessary Minerals SIMS U-Th-Pb Dating for Kimberlite and Lamproite 被引量:1
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作者 LI Qiuli LI Xianhua +2 位作者 WU Fuyuan LIU Yu TANG Guoqiang 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2016年第S1期74-75,共2页
Kimberlite and lamproite,the major source of diamonds,are volatile-rich potassic ultramafic rocks that originate from the deep lithospheric mantle.These rocks are important for deciphering the composition
关键词 SIMS Pb Accessary Minerals SIMS U-Th-Pb dating for Kimberlite and Lamproite Th
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LOW TEMPERATURE DATING OF HIGH MOUNTAIN ROCKS:(U-Th)/He AGES FROM HIGHER HIMALAYAN SAMPLES, EASTERN NEPAL
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作者 Mary Hubbard 1, Martha House 2(1 Dept. of Geology, Thompson Hall, Kansas State University, Manhattan, KS 66506 USA 2 Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125 USA) 《地学前缘》 EI CAS CSCD 2000年第S1期16-17,共2页
Recently the (U\|Th)/He method on apatite has been applied to studies of cooling and exhumation in mountain belts in order to place constraints on the low temperature cooling history (Wolf et al., 1997; House et al., ... Recently the (U\|Th)/He method on apatite has been applied to studies of cooling and exhumation in mountain belts in order to place constraints on the low temperature cooling history (Wolf et al., 1997; House et al., 1998). Because the closure temperature of the method is 65~75℃, it provides useful information regarding the exhumation of rocks through the upper few kilometers of the earth’s crust. When the (U\|Th)/He method is coupled with methods such as 40 Ar/ 39 Ar with higher closure temperatures (210~500℃), a cooling history can be reconstructed over a wide range of temperatures. In eastern Nepal, in the Dudh Kosi valley a suite of samples from the Main Central Thrust (MCT) to the middle of the Higher Himalayan section was previously dated using 40 Ar/ 39 Ar on K\|feldspar, biotite, muscovite, and hornblende (Hubbard and Harrison,1989). We have applied the (U\|Th)/He method to apatite from these same samples. The structurally highest site, Ngozumba, is in the middle to upper part of the Higher Himalaya in the Gokyo valley. At Ngozumba previous 40 Ar/ 39 Ar ages include: muscovite at (16 6±0 4)Ma (closure temperature (CT)350℃), biotite at (16 8±1 4)Ma (CT 300℃), and K\|feldspar at (15 5±1 8)Ma (CT 250℃).The apatite age for an augen gneiss from this location was (6 3±3 8)Ma suggesting slower cooling for that part of the range during the last 15Ma. Structurally below Ngozumba, in the MCT zone, 40 Ar/ 39 Ar ages include:(20 9±0 2)Ma for hornblende (CT 500℃), (12 0±0 2)Ma for muscovite, and (8 0±0 2)Ma for K\|feldspar (CT 220℃). The apatite age obtained for a biotite schist at this location was (4 6±0 2)Ma and is consistent with relatively constant cooling since 12Ma. In between the MCT and the Ngozumba site samples were collected near the settlement of Ghat that yielded anomalously young 40 Ar/ 39 Ar ages:(7 7±0 4)Ma for muscovite, (7 5±0 6)Ma for biotite, and (3 6±0 2)Ma for K\|feldspar (CT 210℃). The apatite age is consistent with these young ages at (0 8±0 1)Ma. Plausible explanations for the young ages at this site include: post\|MCT age movement on a small\|scale shear zone or late\|stage movement of hydro\|thermal fluids through this localized zone. The MCT zone 40 Ar/ 39 Ar ages were used to constrain a one\|dimensional thermal model aimed at understanding rates of exhumation (Hubbard et al., 1991). The model yielded exhumation rates of 0 7~1 9km/Ma for the MCT zone region. The (U\|Th)/He age for apatite from this region is consistent with the model results. By coupling the (U\|Th)/He ages with the 40 Ar/ 39 Ar ages in this region we can determine that exhumation processes have acted at a relatively constant rate during the last 15~20 million years (with the possible exception of the Ghat location). Major fault activity likely pre\|dates this time period, or has had little affect on the cooling history. 展开更多
关键词 U\|Th)/He dating EXHUMATION Himalaya Nepal cooling history
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Zircon Trace Element Constraints on U-Pb Dating:A Case Study of the Huayuangong A-type Granite in the Lower Yangtze Region,Eastern China
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作者 QI Fei YAN Jun 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2021年第4期1171-1182,共12页
For magmatic rocks,it is often found that zircon 206 Pb/238 U and 207 Pb/235 U ratios continuously plot on the concordia line with a relatively large age span for the same sample,which gives rise to large dating error... For magmatic rocks,it is often found that zircon 206 Pb/238 U and 207 Pb/235 U ratios continuously plot on the concordia line with a relatively large age span for the same sample,which gives rise to large dating errors or even unrealistic dating results.As the trace element concentrations of zircon can reflect its equilibrated magma characteristics,they can be used to determine whether all the analytical spots on the zircons selected to calculate the weighted mean age are cogenetic and formed in a single magma chamber.This work utilizes the results of zircon trace element concentrations and U-Pb isotopic analyses to explore the screening of reasonable U-Pb ages,which can be used to determine a more accurate intrusion crystallization age.The late Mesozoic Huayuangong granitic pluton complex,which is located in the Lower Yangtze region,eastern China,was selected for a case study.The Huayuangong pluton comprises the central intrusion and the marginal intrusion.Two samples from the marginal intrusion yielded consistent zircon weighted mean 206 Pb/238 U ages of 124.6±2.0 Ma and 125.9±1.6 Ma.These analytical spots also exhibit Zr/Hf and Th/U ratios concordant with the evolution of a single magma,from which the dated zircons crystallized.However,for the central intrusion,the analytical spots on zircons from two samples all show a continuous distribution on the concordia line with a relatively large age span.For each sample from the central intrusion,the zircon Zr/Hf ratios do not conform to a single magma evolutionary trend,but rather can be divided into two groups.We propose that zircon Zr/Hf ratios can provide a new constraint on U-Pb zircon dating and zircon Th/U ratios can also be used as a supplementary indicator to constrain zircon dating and determine the origins of the zircons and whether magma mixing has occurred.By screening zircon analytical spots using these two indicators,the two samples from the central intrusion of the Huayuangong pluton produce results of 122.8±4.3 Ma and 122.9±2.2 Ma,which are consistent with the field observations that the central intrusion is slightly younger than the marginal intrusion. 展开更多
关键词 U-Pb zircon dating zircon Zr/Hf ratios zircon Th/U ratios magma mixing trace elements YANGTZE
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SYSTEMATIC ERROR FROM Th/U RATIO IN LUMINESCENCE AND ESR DATING
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作者 Li Shenghua and Man-Yin Wong Tso(Radioisotope Unit,University of Hong Kong,Hong Kong) 《Nuclear Science and Techniques》 SCIE CAS CSCD 1995年第2期113-116,共4页
SYSTEMATICERRORFROMTh/URATIOINLUMINESCENCEANDESRDATINGLiShenghuaandMan-YinWongTso(RadioisotopeUnit,Universit... SYSTEMATICERRORFROMTh/URATIOINLUMINESCENCEANDESRDATINGLiShenghuaandMan-YinWongTso(RadioisotopeUnit,UniversityofHongKong,HongK... 展开更多
关键词 考古学 荧光 ESR 年代断定 综合误差
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U-Th-Pb monazite and Sm-Nd dating of high-grade rocks from the Grove Mountains, East Antarctica: further evidence for a Pan-African-aged monometamorphic terrane
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作者 LIU Xiaochun LING Xiaoxiao JAHN Bor-ming 《Advances in Polar Science》 2018年第2期108-117,共10页
The Grove Mountains, 400 km south of the Chinese Antarctic Zhongshan Station, are an inland continuation of the Pan-African-aged (i.e., Late Neoproterozoic/Cambrian) Prydz Belt, East Antarctica. In this paper we carri... The Grove Mountains, 400 km south of the Chinese Antarctic Zhongshan Station, are an inland continuation of the Pan-African-aged (i.e., Late Neoproterozoic/Cambrian) Prydz Belt, East Antarctica. In this paper we carried out a combined U-Th-Pb monazite and Sm-Nd mineral-whole-rock dating on para-and orthogneisses from bedrock in the Grove Mountains. U-Th-Pb monazite dating of a cordierite-bearing pelitic paragneiss yields ages of 523 ± 4 Ma for the cores and 508 ± 6 Ma for the rims. Sm-Nd mineral-whole-rock isotopic analyses yield isochron ages of 536 ± 3 Ma for a coarse-grained felsic orthogneiss and 507 ± 30 Ma for a fine-grained quartzofeldspathic paragneiss. Combined with previously published age data in the Grove Mountains and adjacent areas, the older age of ~530 Ma is interpreted as the time of regional medium-to low-pressure granulite-facies metamorphism, and the younger age of ~510 Ma as the cooling age of the granulite terrane. The absence of evidence for a Grenville-aged (i.e., Late Mesoproterozoic/Early Neoproterozoic) metamorphic event indicates that the Grove Mountains have experienced only a single metamorphic cycle, i.e., Pan-African-aged, which distinguishes them from other polymetamorphic terranes in the Prydz Belt. This will provide important constraints on the controversial nature of the Prydz Belt. 展开更多
关键词 Sm-Nd 独居石 南极洲 岩层 东方 证据 岩石 年龄数据
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Geochemical Characteristics and Chemical Electron Microprobe U-Pb-Th Dating of Pitchblende Mineralization from Gabal Gattar Younger Granite, North Eastern Desert, Egypt
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作者 Hassan A. A. Shahin 《Open Journal of Geology》 2014年第1期24-32,共9页
Pitchblende mineralization was studied in the younger granite samples collected from Gabal Gattar, north Eastern Desert, Egypt using electron scanning microscope (ESM) and electron probe microanalyses (EPMA). This stu... Pitchblende mineralization was studied in the younger granite samples collected from Gabal Gattar, north Eastern Desert, Egypt using electron scanning microscope (ESM) and electron probe microanalyses (EPMA). This study revealed that this pitchblende contains significant Zr content reaching up to (66.80% ZrO2), which suggests that volcanic rocks were probably the source of such a deposit. High level emplaced high-K Calc-alkaline plutons as Qattar granite may have been associated with their volcanic equivalent emplaced in the surrounding area or now eroded. Lead content of the pitchblende mineralization is high and with moderate volcanics (up to 7.71% PbO). In contrast, it is low in ThO2, Y2O3 and REE2O3. High Zr and Pb content associated with pitchblende mineralization from Gattar granite indicates that the source of this mineralization derived from volcanic magma not from granitic magma. According to the calculation of U-Pb chemical ages using U, Th and Pb content measured with an electron microprobe for this pitchblende yielded ages within 543 - 657 Ma indicating a Pan-African age for this mineralization. This is the first time that a Pan-African age (543 to 657 Ma) is recorded for a U-mineralization in Gabal Gattar younger granite in the north Eastern Desert, Egypt. 展开更多
关键词 PITCHBLENDE MINERALIZATION Gabal Gattar GRANITE CHEMICAL U-Pb-Th dating
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Dating with the 9^(th) China International Woolen Knitwear Fair in October
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作者 Wang Ting 《China Textile》 2010年第7期19-19,共1页
On July 7th,the press conference of the 9th China (Dalang) International Woolen Knitwear Fair(WKF)was held at the Great Hall of the People in Beijing.Chen Shujin,Vice President of China National Textile and Apparel Co... On July 7th,the press conference of the 9th China (Dalang) International Woolen Knitwear Fair(WKF)was held at the Great Hall of the People in Beijing.Chen Shujin,Vice President of China National Textile and Apparel Council。 展开更多
关键词 China International Woolen Knitwear Fair in October dating with the 9 TH HALL
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东秦岭大石沟钼矿床中晶质铀矿年代学研究及其地质意义
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作者 黄广文 潘春蓉 +7 位作者 潘家永 钟福军 严杰 夏菲 杜后发 张涛 万建军 康清清 《地质学报》 EI CAS CSCD 北大核心 2023年第6期1917-1937,共21页
东秦岭地区是全球最大的钼成矿带,也是我国最重要的钼矿集区。大石沟矿床是东秦岭地区最为典型的碳酸岩型钼矿床之一。该矿床主体发育钼矿化,并伴生有一定规模的铀、稀土、铅等多金属矿化。前人对该矿床中钼和稀土矿化关注较多,但对铀... 东秦岭地区是全球最大的钼成矿带,也是我国最重要的钼矿集区。大石沟矿床是东秦岭地区最为典型的碳酸岩型钼矿床之一。该矿床主体发育钼矿化,并伴生有一定规模的铀、稀土、铅等多金属矿化。前人对该矿床中钼和稀土矿化关注较多,但对铀矿化的报道甚少。鉴于此,本文在野外地质调查的基础上,采集典型的铀矿化样品,综合利用TIMA、扫描电镜、电子探针和LA-ICP-MS等测试方法,对矿床内发育的铀矿化开展了详细的矿相学、矿物化学和同位素年代学研究。结果表明,大石沟矿床中铀矿化的主要含铀矿物为钛铀矿、晶质铀矿和铌钛铀矿。晶质铀矿多呈半自形—他形粒状展布,具有高Y、Ce和低Si、Ti、Na、Mg的地球化学组成。晶质铀矿的U/Th、ΣREE、LREE/HREE等参数表明其为岩浆成因,形成于高温高盐度、相对还原环境。晶质铀矿EPMA U-Th-Pb_(Total)化学定年与LA-ICP-MS原位U-Pb定年,结果显示铀矿化年龄为~223 Ma,即晚三叠世,表明大石沟碳酸岩中铀矿化形成于秦岭造山带印支期造山后伸展环境。综合前人和本文研究后认为,大石沟矿床中铀矿化年龄与秦岭造山带内碳酸岩型钼矿床的主体形成时代一致,为同时期岩浆活动的产物,可能形成于同一地质事件。 展开更多
关键词 晶质铀矿 EPMA U-Th-Pb_(Total)化学定年 LA-ICP-MS U-Pb定年 大石沟矿床 东秦岭
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石榴子石的LA-ICP-MS面扫描U-Th-Pb定年——以铜绿山大型Cu-Fe-Au矽卡岩矿床为例
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作者 葛粲 汤笑伟 +5 位作者 汪方跃 李修钰 孙贺 顾海欧 袁峰 郑辉 《岩石学报》 SCIE EI CAS CSCD 北大核心 2023年第10期2879-2894,共16页
矽卡岩矿床的年代学信息对研究矽卡岩矿床的矿床成因、演变过程、成矿规律和找矿勘查具有重要的指示意义。石榴子石是矽卡岩矿床中的常见矿物,它具有一定的U含量,但是由于其普通铅高以及铀分布不均一的原因,导致激光剥蚀电感耦合等离子... 矽卡岩矿床的年代学信息对研究矽卡岩矿床的矿床成因、演变过程、成矿规律和找矿勘查具有重要的指示意义。石榴子石是矽卡岩矿床中的常见矿物,它具有一定的U含量,但是由于其普通铅高以及铀分布不均一的原因,导致激光剥蚀电感耦合等离子体质谱仪(LA-ICP-MS)点分析获得年龄成功率不高。针对点分析定年遇到的深度分馏和剥蚀点选取、普通铅校正等问题,本文提出一种利用LA-ICP-MS面扫描分析数据的虚拟点构建技术,在Tera-Wasserburg(TW)图中实现普通铅校正来确定含普通铅石榴子石年龄。通过理论推导、数值模拟和实验分析研究发现,利用相关联的^(208)Pb、^(232)Th、^(238)U测量数据校正生成^(208)Pb_(c)/^(238)U指标并据此对TW图中的数据进行数据分组抽样构造虚拟测量点,可以有效地把面扫描测量数据转换为与点分析测量类似但放射母子比例展布更优的数据。利用此方法对长江中下游成矿带鄂东矿区铜绿山大型Cu-Fe-Au矽卡岩矿床石榴子石进行面扫描分析。仅使用15min的样品面扫描数据,在获得了微量元素含量分布的同时,也获得了同位素比值虚拟点,交点年龄为139.2±2.9Ma(MSWD=0.7,n=126),与前人矿床研究结果相一致,验证了此方法的可行性。利用LA-ICP-MS面扫描定年技术不仅可以获得样品元素含量的二维分布图,有利于对样品期次的筛选,剔除包裹体等异常数据;还可以避免点分析中深度分馏和繁复的选点流程及二次分析等步骤,在获得样品元素含量分布的同时获得矿物年龄,为当前矽卡岩型矿床相关的关键金属研究提供了更为便捷的方法。 展开更多
关键词 含普通铅矿物U-Th-Pb定年 LA-ICP-MS面扫描技术 关键金属 石榴子石年代学 矽卡岩 铜绿山
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电感耦合等离子体质谱法快速准确表征浓缩铀材料
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作者 汪伟 徐江 +9 位作者 席瑞阳 王亚龙 郭思琪 方随 李志明 林剑锋 张海涛 张小林 王春杰 何亚姣 《质谱学报》 EI CAS CSCD 北大核心 2023年第6期797-806,I0003,共11页
本研究联合三重四极杆电感耦合等离子体质谱(ICP-QQQ-MS)和多接收电感耦合等离子体质谱(MC-ICP-MS),快速准确地测量浓缩铀材料中铀同位素丰度比值、^(230)Th/^(234)U和^(231)Pa/^(235)U原子物质的量比值,并诊断铀年龄。结果表明,Neptune... 本研究联合三重四极杆电感耦合等离子体质谱(ICP-QQQ-MS)和多接收电感耦合等离子体质谱(MC-ICP-MS),快速准确地测量浓缩铀材料中铀同位素丰度比值、^(230)Th/^(234)U和^(231)Pa/^(235)U原子物质的量比值,并诊断铀年龄。结果表明,Neptune XT型MC-ICP-MS和Agilent 8800型ICP-QQQ-MS对^(233)U丰度的有效检测限分别为3×10^(-9)和6×10^(-10),适用于^(233)U丰度高于6×10^(-8)和样品量充足的样品,对10^(-7)量级^(233)U/^(235)U同位素丰度比的测量精密度达到1.0%(2σ)和4.8%(2σ)。采用GBW04240作为外标校正质量分馏效应,建立了基于ICP-QQQ-MS的10-5量级原子物质的量比值的230Th/234U和10-8量级原子物质的量比值的231Pa/^(235)U的同时测量方法,对230Th-234U和231Pa-^(235)U模式年龄的检测限分别达到0.2 a和0.5 a,定年不确定度为0.65 a(2σ)和0.67 a(2σ)。结合MC-ICP-MS测量的234U/^(235)U、^(235)U/238U和236U/^(235)U等同位素丰度比值,判断某批次浓缩铀样品可能用于实验堆,最后一次分离纯化时间在2009年左右,且均已经历反应堆辐照。该技术将铀年龄诊断由经典系统分离定量方法的1个月左右缩短至1周以内,分析速度快、结果准确,可为核取证、核标准物质研制定值和核保障监督等提供技术支持。 展开更多
关键词 浓缩铀材料 铀同位素比值 铀年龄 ^(230)Th/^(234)U原子物质的量比值 ^(231)Pa/^(235)U原子物质的量比值
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东秦岭黄水庵碳酸岩型Mo-REE矿床方解石地球化学特征和氟碳铈矿U-Th-Pb年龄及其意义 被引量:2
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作者 王汉辉 唐利 +5 位作者 杨勃畅 唐吉根 张彦生 郭俊 冯嘉颖 盛渊明 《西北地质》 CAS CSCD 北大核心 2023年第1期48-62,共15页
黄水庵矿床位于华北克拉通南缘熊耳山矿集区,是东秦岭钼矿带典型的碳酸岩型Mo-REE矿床之一。黄水庵矿床的Mo-REE矿体主要产于碳酸岩中,碳酸岩呈脉状和隐爆角砾岩体侵入太华群。笔者通过碳酸岩方解石微量元素、C-O同位素以及氟碳铈矿U-Th... 黄水庵矿床位于华北克拉通南缘熊耳山矿集区,是东秦岭钼矿带典型的碳酸岩型Mo-REE矿床之一。黄水庵矿床的Mo-REE矿体主要产于碳酸岩中,碳酸岩呈脉状和隐爆角砾岩体侵入太华群。笔者通过碳酸岩方解石微量元素、C-O同位素以及氟碳铈矿U-Th-Pb年龄的研究,探讨了碳酸岩岩浆的来源、成岩成矿年龄和构造地质背景,对东秦岭地区的构造演化和成矿作用提供约束。方解石的微量元素具有富集大离子亲石元素、亏损高场强元素的特征,稀土配分模式为轻稀土元素富集的右倾型(LREE/HREE=3.08~10.33)。方解石δ13 CV-PDB值为−4.11‰~−5.62‰、δ18OV-SMOW值为6.40‰~7.62‰,指示初始火成碳酸岩特征。氟碳铈矿U-Th-Pb定年的加权平均年龄为(213.5±2.9)Ma,代表了黄水庵REE矿化的时限。综合已有成岩成矿年龄和同位素研究结果,认为黄水庵矿床的成矿时代为晚三叠世,形成于秦岭造山带碰撞后的伸展背景。富Mo下地壳与富集地幔的部分熔融形成碳酸岩岩浆,其中地壳物质的再循环是形成碳酸岩型Mo-REE矿化的关键因素之一。 展开更多
关键词 碳酸岩 方解石微量元素 碳氧同位素 氟碳铈矿U-Th-Pb定年 黄水庵矿床
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新疆波孜果尔超大型稀有-稀土金属矿床的成矿时代和成矿动力学背景:来自独居石U-Th-Pb定年和石墨激光拉曼光谱的指示
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作者 谢明材 韩春明 +4 位作者 范宏瑞 杨奎锋 李兴辉 佘海东 梁改忠 《岩石学报》 SCIE EI CAS CSCD 北大核心 2023年第10期2927-2950,共24页
波孜果尔碱性岩型Nb-Ta-Rb-Zr-REE矿床位于塔里木克拉通北缘与南天山造山带的接合地段,是近年来在塔里木北缘碱性岩带中发现的规模最大的稀有-稀土综合性矿床。本文通过对含矿岩体中的独居石和晶质石墨包体开展成矿年代学和岩浆形成条... 波孜果尔碱性岩型Nb-Ta-Rb-Zr-REE矿床位于塔里木克拉通北缘与南天山造山带的接合地段,是近年来在塔里木北缘碱性岩带中发现的规模最大的稀有-稀土综合性矿床。本文通过对含矿岩体中的独居石和晶质石墨包体开展成矿年代学和岩浆形成条件研究,结合含矿碱性岩全岩成分,揭示波孜果尔碱性岩型稀有-稀土金属矿床的岩石地球化学特征、晶质石墨对成岩/成矿的指示、稀土成矿时代和成矿动力学背景,并进一步总结区域成矿指示意义。研究发现,波孜果尔碱性岩以富含碱性暗色矿物(钠铁闪石和霓石)为特征,岩性以正长岩为主,有较高的稀土总量,富集轻稀土元素和高场强元素(Nb、Ta、Zr、Hf、Th、U等),亏损重稀土元素和Ba、Sr等大离子亲石元素,显示强烈的负Eu异常。通过对晶质石墨的研究发现,不同岩相组中石墨的拉曼谱峰相似,显示具有较高的结晶程度,岩浆演化从细晶到伟晶阶段,石墨的无序度增大,可能与烧绿石和锆石等含放射性元素矿物增多使得辐射加强的影响有关。估算石墨的结晶温度介于700~800℃之间,其形成早于碱性岩浆,指示碱性岩浆早期为还原环境,晚期趋于氧化。独居石LA-ICP-MS U-Th-Pb结果显示波孜果尔稀土矿化时代约为280Ma,结合前人已获得的锆石U-Pb年龄,表明波孜果尔碱性岩浆活动时间从~290Ma到280Ma,持续了至少10Myr。进一步研究发现,从时间和空间上,波孜果尔含矿碱性岩所在的碱性岩带形成与塔里木地幔柱有关。地幔柱就位诱发被先前俯冲物质交代富集稀有-稀土元素和挥发性成分的岩石圈地幔低程度部分熔融形成富成矿元素的碱性岩母岩浆,随后在岩浆演化晚期富集成矿。 展开更多
关键词 波孜果尔 碱性岩 独居石U-Th-Pb定年 石墨拉曼光谱 地幔柱 塔里木北缘
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Record of hydrothermal activity in the Yuhuang hydrothermal field and its implications for the Southwest Indian Ridge:evidence from sulfide chronology
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作者 Weifang Yang Chunhui Tao +6 位作者 Shili Liao Jin Liang Wei Li Teng Ding Ágata Alveirinho Dias Xuefeng Wang Lisheng Wang 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2023年第11期59-68,共10页
The Yuhuang hydrothermal field(YHF)is located between the Indomed and Gallieni fracture zones near the top of the off-axis slope on the south rift wall of Segment 29 on the ultraslow Southwest Indian Ridge(SWIR).Previ... The Yuhuang hydrothermal field(YHF)is located between the Indomed and Gallieni fracture zones near the top of the off-axis slope on the south rift wall of Segment 29 on the ultraslow Southwest Indian Ridge(SWIR).Previous studies have shown that sulfides in the YHF formed during different mineralization episodes and the YHF has the greatest potential for the formation of large-scale seafloor massive sulfide deposits.However,the sulfide chronology and hydrothermal activity of the YHF remain poorly constrained.In this study,mineralogical analyses and 230Th/U dating were performed.Hydrothermal activity may start about(35.9±2.3)ka from the southwest part of the YHF and may cease about(708±81)a ago from the northeast part of the YHF.The 74 nonzero chronological data from hydrothermal sulfide samples provide the first quantitative characterization of the spatial and temporal history along the SWIR.Hydrothermal activity in the SWIR has been relatively active over the past20 ka.In contrast,between 40 ka and 100 ka,hydrothermal activity was relatively infrequently and short in duration.The maximum activity occurred at 15–11 ka,9–7 ka,6–0.2 ka.There was a slight positive correlation between the maximal age and estimated surface area or estimated tonnage.The minimum mass accumulation rate of YHF is about 278 t/a,which is higher than most HFs related to ultramafic systems.The ultraslow spreading SWIR has the greatest potential to form large-scale seafloor massive sulfides(SMS)deposits.The results of this study provide new insights into the metallogenic mechanism of hydrothermal sulfides along ultraslow-spreading ridges. 展开更多
关键词 Southwest Indian Ridge seafloor massive sulfides 230th/U dating hydrothermal activity mass accumulation
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