The title compound has been synthesized and characterized crystallographicaUy. It is a co-crystal consisting of two different neutral zinc（H） complexes with Hbpbm （Hbpbm = 4- bromo-2-（benzimidazol-2-yl）phenol） a...The title compound has been synthesized and characterized crystallographicaUy. It is a co-crystal consisting of two different neutral zinc（H） complexes with Hbpbm （Hbpbm = 4- bromo-2-（benzimidazol-2-yl）phenol） and Hnpbm （Hnpbm = 2-（1-butylbenzimidazol-2-yl）phenol）. One is a monomeric mixed-ligand complex of [Zn（bpbm）（npbm）] 1 and the other a dimer of [Zn2（npbm）4] 2 with their ratio of 2：1. Thus the overall formula for the title compound is 21.2. Adjacent 1 and 2 are connected to each other by intermolecular hydrogen bonding interactions in the lattice. The crystal data： monoclinic, space group P21/c, a = 15.0141（12）, b = 20.9941（17）, c = 18.4686（15） A, β = 97.445（2）°, V = 5772.4（8） A^3, Mr= 2429.68, Z = 2, Dc = 1.398 g/cm^3,μ = 1.579 -1 mm , F（000） = 2504, R = 0.0637 and wR = 0.1771 for 6464 observed reflections （I 〉 2σ（I））. The geometrical structure for 1 has also been theoretically optimized and compared with the experimental one.展开更多
A novel two-dimensional Mn（II） coordination polymer, [Mn3（L）R（cis-chdc）fftrans- chdc）]n （L = 2-amino-4-（1H-imidazo[4,5-J][1,10]phenanthrolin-2-yl）phenol and chdc = 1,4-cyclo- hexanedicarboxylate）, has been ...A novel two-dimensional Mn（II） coordination polymer, [Mn3（L）R（cis-chdc）fftrans- chdc）]n （L = 2-amino-4-（1H-imidazo[4,5-J][1,10]phenanthrolin-2-yl）phenol and chdc = 1,4-cyclo- hexanedicarboxylate）, has been hydrothermally synthesized and characterized by elemental analysis, IR, TG PL and single-crystal X-ray diffraction. Crystallographic data for this compound： monoclinic space group P2/n with a = 11.0058（13）, b = 9.0179（11）, c = 28.431（3） A, β = 92.850（2）°, V = 2818.3（6） A3, Z = 2, C62Hs6Mn3N10O14, Mr = 1329.99, Dc = 1.567 g/cm3, F（000） = 1370, p（MoKa） = 0.742 mm-1, R = 0.0553 and wR = 0.1421. The chdc carboxylates bridge the Mn（II） atoms to form a trinuclear Mn（lI） cluster. The cis-chdc ligands are held together by the trinuclear Mn（II） clusters to result in a chain structure. Further, the trans-chdc ligands link adjacent chains to furnish a two-dimensional network. The π-π interactions between neighboring layers link the adjacent layers into a three-dimensional supramolecular architecture. Moreover, the N-H...O and O-H...O hydrogen bonds further stabilize the 3D supramolecular architecture.展开更多
基金This work was supported by the Natural Science Foundation of Guangdong Province (No. 06301028)
文摘The title compound has been synthesized and characterized crystallographicaUy. It is a co-crystal consisting of two different neutral zinc（H） complexes with Hbpbm （Hbpbm = 4- bromo-2-（benzimidazol-2-yl）phenol） and Hnpbm （Hnpbm = 2-（1-butylbenzimidazol-2-yl）phenol）. One is a monomeric mixed-ligand complex of [Zn（bpbm）（npbm）] 1 and the other a dimer of [Zn2（npbm）4] 2 with their ratio of 2：1. Thus the overall formula for the title compound is 21.2. Adjacent 1 and 2 are connected to each other by intermolecular hydrogen bonding interactions in the lattice. The crystal data： monoclinic, space group P21/c, a = 15.0141（12）, b = 20.9941（17）, c = 18.4686（15） A, β = 97.445（2）°, V = 5772.4（8） A^3, Mr= 2429.68, Z = 2, Dc = 1.398 g/cm^3,μ = 1.579 -1 mm , F（000） = 2504, R = 0.0637 and wR = 0.1771 for 6464 observed reflections （I 〉 2σ（I））. The geometrical structure for 1 has also been theoretically optimized and compared with the experimental one.
基金supported by the Education Office of Jilin Province(No.2013212)
文摘A novel two-dimensional Mn（II） coordination polymer, [Mn3（L）R（cis-chdc）fftrans- chdc）]n （L = 2-amino-4-（1H-imidazo[4,5-J][1,10]phenanthrolin-2-yl）phenol and chdc = 1,4-cyclo- hexanedicarboxylate）, has been hydrothermally synthesized and characterized by elemental analysis, IR, TG PL and single-crystal X-ray diffraction. Crystallographic data for this compound： monoclinic space group P2/n with a = 11.0058（13）, b = 9.0179（11）, c = 28.431（3） A, β = 92.850（2）°, V = 2818.3（6） A3, Z = 2, C62Hs6Mn3N10O14, Mr = 1329.99, Dc = 1.567 g/cm3, F（000） = 1370, p（MoKa） = 0.742 mm-1, R = 0.0553 and wR = 0.1421. The chdc carboxylates bridge the Mn（II） atoms to form a trinuclear Mn（lI） cluster. The cis-chdc ligands are held together by the trinuclear Mn（II） clusters to result in a chain structure. Further, the trans-chdc ligands link adjacent chains to furnish a two-dimensional network. The π-π interactions between neighboring layers link the adjacent layers into a three-dimensional supramolecular architecture. Moreover, the N-H...O and O-H...O hydrogen bonds further stabilize the 3D supramolecular architecture.
