模拟7B04铝合金表面涂层破损,采用电化学试验研究7B04铝合金在不同环境条件下的自腐蚀与点蚀行为,基于电偶腐蚀数学模型,通过有限元法分析7B04铝合金与TA15钛合金接触后发生点蚀的条件。结果表明:7B04铝合金点蚀电位受Cl^-浓度和pH值的...模拟7B04铝合金表面涂层破损,采用电化学试验研究7B04铝合金在不同环境条件下的自腐蚀与点蚀行为,基于电偶腐蚀数学模型,通过有限元法分析7B04铝合金与TA15钛合金接触后发生点蚀的条件。结果表明:7B04铝合金点蚀电位受Cl^-浓度和pH值的影响,在NaCl质量分数>10%的中性溶液及NaCl质量分数为3.5%的酸性溶液中,自腐蚀状态下7B04铝合金即可发生点蚀;7B04铝合金与TA15钛合金接触后,电位升高,增加了发生点蚀的可能性,在NaCl质量分数为3.5%的中性溶液中,当阴阳极面积比≥40时,7B04铝合金发生点蚀的萌生并进一步扩展;7B04铝合金电位随阴阳极距离的增大而下降,但幅度有限,在10 m的距离内下降不超过2 m V。展开更多
The effects of the direct current (DC) on the evolutions of hardness and morphology of the secondary phases in 7B04 aluminum alloy homogenized at 380?465 ℃ for 2 h were investigated in detail by electric conductiv...The effects of the direct current (DC) on the evolutions of hardness and morphology of the secondary phases in 7B04 aluminum alloy homogenized at 380?465 ℃ for 2 h were investigated in detail by electric conductivity measurement, hardness test, X-ray diffraction analysis, field emission scanning electron microscopy and energy dispersive spectrometry. The results show that with increasing temperature from 380 to 465 ℃, the electric conductivity of normal homogenized sample decreases from 34.9%IACS to 28.7%IACS, the hardness increases from HV 96 to HV 146, and the area fraction of secondary phase reduces from 4.5% to 1.89%. While, DC homogenized sample has a higher hardness, a lower electric conductivity and a smaller area fraction of secondary phases at the same temperature. The DC enhances the homogenization process by promoting the diffusibility of the solute atoms and the mobility of vacancy.展开更多
文摘模拟7B04铝合金表面涂层破损,采用电化学试验研究7B04铝合金在不同环境条件下的自腐蚀与点蚀行为,基于电偶腐蚀数学模型,通过有限元法分析7B04铝合金与TA15钛合金接触后发生点蚀的条件。结果表明:7B04铝合金点蚀电位受Cl^-浓度和pH值的影响,在NaCl质量分数>10%的中性溶液及NaCl质量分数为3.5%的酸性溶液中,自腐蚀状态下7B04铝合金即可发生点蚀;7B04铝合金与TA15钛合金接触后,电位升高,增加了发生点蚀的可能性,在NaCl质量分数为3.5%的中性溶液中,当阴阳极面积比≥40时,7B04铝合金发生点蚀的萌生并进一步扩展;7B04铝合金电位随阴阳极距离的增大而下降,但幅度有限,在10 m的距离内下降不超过2 m V。
文摘通过显微组织观察、拉伸力学性能测试、XRD衍射物相分析以及α(Al)基体点阵常数的测量等方法研究了固溶处理对7B04铝合金组织和性能的影响.结果表明:在410~470℃范围,随固溶温度升高和时间延长,由于粗大的平衡相逐渐回溶,合金的强度逐渐升高;进一步提高固溶温度或延长固溶时间,合金强度逐步降低.7B04铝合金的优选固溶处理制度为470℃×60 min.
基金Project(5157406)supported by the National Natural Science Foundation of China
文摘The effects of the direct current (DC) on the evolutions of hardness and morphology of the secondary phases in 7B04 aluminum alloy homogenized at 380?465 ℃ for 2 h were investigated in detail by electric conductivity measurement, hardness test, X-ray diffraction analysis, field emission scanning electron microscopy and energy dispersive spectrometry. The results show that with increasing temperature from 380 to 465 ℃, the electric conductivity of normal homogenized sample decreases from 34.9%IACS to 28.7%IACS, the hardness increases from HV 96 to HV 146, and the area fraction of secondary phase reduces from 4.5% to 1.89%. While, DC homogenized sample has a higher hardness, a lower electric conductivity and a smaller area fraction of secondary phases at the same temperature. The DC enhances the homogenization process by promoting the diffusibility of the solute atoms and the mobility of vacancy.