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DC铸造铝合金铸锭中含Cr弥散相粒子的析出行为
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作者 周轶然 田妮 +3 位作者 姜旭 张耀中 石旭 赵刚 《轻金属》 北大核心 2021年第12期42-47,共6页
利用透射电镜和电子探针观察、结合能谱及波谱测定分析并借助JmatPro7.0软件计算,对比研究了4种含0.25%Cr的DC铸造铝合金铸锭,及其分别经过470℃×24 h、250℃×168 h+470℃×24 h处理后,合金中含Cr弥散相粒子的析出位置、... 利用透射电镜和电子探针观察、结合能谱及波谱测定分析并借助JmatPro7.0软件计算,对比研究了4种含0.25%Cr的DC铸造铝合金铸锭,及其分别经过470℃×24 h、250℃×168 h+470℃×24 h处理后,合金中含Cr弥散相粒子的析出位置、析出数量、尺寸和分布。结果表明:Al-0.25Cr二元合金中不能析出含Cr弥散相粒子,Al-1.52Mg-0.25Cr、Al-4.3Zn-1.54Mg-0.25Cr和Al-5.54Zn-1.96Mg-1.6Cu-0.25Cr三种合金中能析出Al_(18)Mg_(3)Cr_(2)弥散相粒子。DC铸造Al-1.52Mg-0.25Cr合金铸锭在250℃×168 h预处理过程中无合金相粒子析出,无法提供Al_(18)Mg_(3)Cr_(2)弥散相粒子非均质形核的界面,因而250℃预处理对该合金铸锭中Al_(18)Mg_(3)Cr_(2)弥散相粒子析出无明显促进作用。添加Zn及250℃×168 h预处理分别是促进Al-Mg-Cr合金中形成高密度Al_(18)Mg_(3)Cr_(2)弥散相粒子的内因和外因。DC铸造Al-4.3Zn-1.54Mg-0.25Cr和Al-5.54Zn-1.96Mg-1.6Cu-0.25Cr铸锭经250℃×168 h预处理过程中弥散析出大量MgZn_(2)或T相粒子,这些粒子界面为Al_(18)Mg_(3)Cr_(2)弥散相粒子析出提供了大量形核位置,提高了Al_(18)Mg_(3)Cr_(2)弥散相粒子的形核率,从而使Al_(18)Mg_(3)Cr_(2)弥散相粒子分布更加均匀、尺寸明显细化且数量明显增多。 展开更多
关键词 DC铸造铝合金铸锭 al_(18)mg_(3)cr_(2)弥散 预处理 异质形核
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Mechanism of heterogeneous distribution of Cr-containing dispersoids in DC casting 7475 aluminum alloy 被引量:1
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作者 Yi-ran ZHOU Ni TIAN +5 位作者 Wei LIU Yu ZENG Guang-dong WANG Shi-da HAN Gang ZHAO Gao-wu QIN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2022年第5期1416-1427,共12页
The actual effective partition coefficients of Mg and Cr in a cross-section of a dendrite arm in a direct-chill(DC)-casting ingot of 7475 aluminum alloy are obtained.Meanwhile,by analyzing the microstructure,the mecha... The actual effective partition coefficients of Mg and Cr in a cross-section of a dendrite arm in a direct-chill(DC)-casting ingot of 7475 aluminum alloy are obtained.Meanwhile,by analyzing the microstructure,the mechanism of the heterogeneous distribution of E(Al_(18)Mg_(3)Cr_(2))dispersoids in this DC ingot is revealed.The results show that the actual effective partition coefficients of Mg and Cr are 0.650 and 1.392,respectively,and they describe the heterogeneous distributions of Mg and Cr along the direction of radius of the cross-section of the dendrite arm of the alloy.After homogenization treatment at 470℃ for 24 h,Mg diffuses uniformly,but Cr hardly diffuses.Both the concentrations of Mg and Cr and the sites of heterogeneous nucleation in the alloy are the determinants of the formation of E dispersoids simultaneously.The heat treatment at 250℃ for 72 h provides a large number of the sites of heterogeneous nucleation of the formation of fine E dispersoids that will be formed in the center of the cross-section during the subsequent heat treatment at higher temperature. 展开更多
关键词 7475 aluminum alloy direct-chill-casting ingot al18mg3cr2 dispersoids heterogeneous distribution effective partition coefficient
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