Maifanite is a nature medicinal stone used in many fields for long time. Theresearch on it showed that there are many trace elements in maifanite. In this paper, 36 traceelements in maifanite were determined by outer ...Maifanite is a nature medicinal stone used in many fields for long time. Theresearch on it showed that there are many trace elements in maifanite. In this paper, 36 traceelements in maifanite were determined by outer cover electrode atomic emission spectrometry, and thedetermination conditions were studied systematically. The results show that the concentrations ofelements, which are beneficial to human health, are higher, and the elements harmful to peoplehealth such as As, Cd, Hg, Cr, and Pb are tiny in maifanite. The precision and the accuracy werealso discussed.展开更多
A method based on the combination of coprecipitation with inductively coupledplasma atomic emission spectrometry (ICP-AES) was developed for the determination of impurities inhigh-purity sodium tungstate. Six elements...A method based on the combination of coprecipitation with inductively coupledplasma atomic emission spectrometry (ICP-AES) was developed for the determination of impurities inhigh-purity sodium tungstate. Six elements (Co, Cu, Fe, Mn, Ni, and Pb) were coprecipitated bylanthanum hydroxide so as to be concentrated and separated from the tungsten matrix. Effects of somefactors on the recoveries of the analytes and on the residual amount of sodium tungstate wereinvestigated, and the optimum conditions for the coprecipitation were proposed. Matrix-matchingcalibration curve method was used for the analysis. It is shown that the elements mentioned abovecan be quantitatively recovered. The detection limits for Co, Cu, Fe, Mn, Ni, and Pb are 0.07, 0.4,0.2, 0.1, 0.6, and 1.3 μg·g^(-1), respectively. The recoveries vary from 92.5% to 108%, and therelative standard deviations (RSDs) are in the range of 3.1%-5.5%.展开更多
The method for the determination of Ni, Ca, Mg, Cu and Pb in wolfram wire by ICP AES was studied. Results showed that perhydrol affects the intensities of elements (Ni, Ca, Mg, Cu, Pb) and this effect can be compensa...The method for the determination of Ni, Ca, Mg, Cu and Pb in wolfram wire by ICP AES was studied. Results showed that perhydrol affects the intensities of elements (Ni, Ca, Mg, Cu, Pb) and this effect can be compensated by internal reference element. It is also showed that the stability of plasma caused by perhydrol matrix was effectively improved. The replicate experiment and recovery experiment revealed perfect precision and accuracy. Results got by two methods were just the same.展开更多
The determination of carbon by means of microwave plasma torch atomic emission spectrometry(MPT-AES) was studied. Aqueous samples were introduced with a pneumatic nebulization system. The detection limit for carbon wa...The determination of carbon by means of microwave plasma torch atomic emission spectrometry(MPT-AES) was studied. Aqueous samples were introduced with a pneumatic nebulization system. The detection limit for carbon was 0. 047μg/mL.The method was applied to the analysis for tap water and results were satisfactory.展开更多
In general, atomic emission spectrometry (AES) is an excellent technique for determination of metal elements. However, its capability of determining nonmetals has not been developed well. The major reasons are the res...In general, atomic emission spectrometry (AES) is an excellent technique for determination of metal elements. However, its capability of determining nonmetals has not been developed well. The major reasons are the resonance lines of most nonmetals lie in the vacuum ultraviolet spectral region and the ionic lines of these elements are difficult to be used because the ionization potentials of the elements are very high. And furthermore only He plasma can efficiently excit those ionic resonance lines. The practical application of HeICP-AES to determining the nonmetals is also difficult because its operating and perchace costs are very high. In contrast to HeICPAES, the costs of He microwave induced plasma (MIP)-AES are relatively low, HeMIP has a high excitation capability which can excite ionic lines of various nonmetals and the nonmetals can be determined by HeMIP-AES with a high sensitivity.展开更多
Although the flow injection(FI) as a sample introduction technique has been extensively applied to atomic spectrometry, such as ICP-AES and AAS, very little has been done so far on coupling FI to microwave plasma syst...Although the flow injection(FI) as a sample introduction technique has been extensively applied to atomic spectrometry, such as ICP-AES and AAS, very little has been done so far on coupling FI to microwave plasma systems. Gehlausen et al. determined aqueous fluorine by coupling flow injection analysis (FIA) with HeMIP展开更多
A Kalman filter was developed for correction of wing interference in ICP-AES.Modeling wing interference theoretically instead of experimentally, the filter can compensate the shift in wavelength position in scans, and...A Kalman filter was developed for correction of wing interference in ICP-AES.Modeling wing interference theoretically instead of experimentally, the filter can compensate the shift in wavelength position in scans, and therefore reduce the effect of the interference on detection limit.展开更多
文摘Maifanite is a nature medicinal stone used in many fields for long time. Theresearch on it showed that there are many trace elements in maifanite. In this paper, 36 traceelements in maifanite were determined by outer cover electrode atomic emission spectrometry, and thedetermination conditions were studied systematically. The results show that the concentrations ofelements, which are beneficial to human health, are higher, and the elements harmful to peoplehealth such as As, Cd, Hg, Cr, and Pb are tiny in maifanite. The precision and the accuracy werealso discussed.
文摘A method based on the combination of coprecipitation with inductively coupledplasma atomic emission spectrometry (ICP-AES) was developed for the determination of impurities inhigh-purity sodium tungstate. Six elements (Co, Cu, Fe, Mn, Ni, and Pb) were coprecipitated bylanthanum hydroxide so as to be concentrated and separated from the tungsten matrix. Effects of somefactors on the recoveries of the analytes and on the residual amount of sodium tungstate wereinvestigated, and the optimum conditions for the coprecipitation were proposed. Matrix-matchingcalibration curve method was used for the analysis. It is shown that the elements mentioned abovecan be quantitatively recovered. The detection limits for Co, Cu, Fe, Mn, Ni, and Pb are 0.07, 0.4,0.2, 0.1, 0.6, and 1.3 μg·g^(-1), respectively. The recoveries vary from 92.5% to 108%, and therelative standard deviations (RSDs) are in the range of 3.1%-5.5%.
文摘The method for the determination of Ni, Ca, Mg, Cu and Pb in wolfram wire by ICP AES was studied. Results showed that perhydrol affects the intensities of elements (Ni, Ca, Mg, Cu, Pb) and this effect can be compensated by internal reference element. It is also showed that the stability of plasma caused by perhydrol matrix was effectively improved. The replicate experiment and recovery experiment revealed perfect precision and accuracy. Results got by two methods were just the same.
文摘The determination of carbon by means of microwave plasma torch atomic emission spectrometry(MPT-AES) was studied. Aqueous samples were introduced with a pneumatic nebulization system. The detection limit for carbon was 0. 047μg/mL.The method was applied to the analysis for tap water and results were satisfactory.
文摘In general, atomic emission spectrometry (AES) is an excellent technique for determination of metal elements. However, its capability of determining nonmetals has not been developed well. The major reasons are the resonance lines of most nonmetals lie in the vacuum ultraviolet spectral region and the ionic lines of these elements are difficult to be used because the ionization potentials of the elements are very high. And furthermore only He plasma can efficiently excit those ionic resonance lines. The practical application of HeICP-AES to determining the nonmetals is also difficult because its operating and perchace costs are very high. In contrast to HeICPAES, the costs of He microwave induced plasma (MIP)-AES are relatively low, HeMIP has a high excitation capability which can excite ionic lines of various nonmetals and the nonmetals can be determined by HeMIP-AES with a high sensitivity.
基金Supported by the National Natural Science Founddation of China
文摘Although the flow injection(FI) as a sample introduction technique has been extensively applied to atomic spectrometry, such as ICP-AES and AAS, very little has been done so far on coupling FI to microwave plasma systems. Gehlausen et al. determined aqueous fluorine by coupling flow injection analysis (FIA) with HeMIP
文摘A Kalman filter was developed for correction of wing interference in ICP-AES.Modeling wing interference theoretically instead of experimentally, the filter can compensate the shift in wavelength position in scans, and therefore reduce the effect of the interference on detection limit.
