The new phosphors Bi2ZnB2O7:Ln3+ (Ln3+=Eu3+,Dy3+) were synthesized by solid-state reaction technique.The obtained phosphors were investigated by means of X-ray powder diffraction (XRD),photoluminescence excitation and...The new phosphors Bi2ZnB2O7:Ln3+ (Ln3+=Eu3+,Dy3+) were synthesized by solid-state reaction technique.The obtained phosphors were investigated by means of X-ray powder diffraction (XRD),photoluminescence excitation and emission spectra with the aim of enhancing the fundamental knowledge about the luminescent properties of Eu3+ and Dy3+ ions in the Bi2ZnB2O7 host lattice.XRD analysis shows that all these compounds are of a single phase of Bi2ZnB2O7.The excitation and emission spectra of Bi2ZnB2O7:Ln3+ (Ln3+=Eu3+,Dy3+) at room temperature show the typical 4f-4f transitions of Eu3+ and Dy3+,respectively.The hypersensitive transitions of 5D0→7F2 (Eu3+) and 4F9/2→6H13/2 (Dy3+) are relatively higher than those of the insensitive transitions in Bi2ZnB2O7.It is conceivable that the Bi2ZnB2O7 structure provides asymmetry sites for activators (Eu3+,Dy3+).The optimum concentrations of Eu3+ and Dy3+ ions in Bi2ZnB2O7 phosphors are both x=0.05.展开更多
The phosphors of （Bi 1-x Smx）2ZnB2O7 （x=0.01, 0.03, 0.05, 0.07, and 0.09） were synthesized by conventional solid state reaction. The purity of all samples was checked by X-ray powder diffraction （XRD）. XRD analy...The phosphors of （Bi 1-x Smx）2ZnB2O7 （x=0.01, 0.03, 0.05, 0.07, and 0.09） were synthesized by conventional solid state reaction. The purity of all samples was checked by X-ray powder diffraction （XRD）. XRD analysis shows that all these compounds are of a single phase of Bi2ZnB2O7, indicating that the Bi 3+ in Bi2ZnB2O7 can be partly replaced by the Sm 3+ without the change of crystal structure. The excitation and emission spectra at room temperature show the typical 4f-4f transitions of Sm 3+ . The dominant excitation line is around 404 nm due to 6H 5/2 →4K 11/2 and the emission spectrum consists of a series of lines at 563, 599, 646, and 704 nm due to 4G 5/2 →6H 5/2 , 6H 7/2 , 6H 9/2 , and 6H 11/2 , respectively. The optimal concentration of Sm 3+ in Bi2ZnB2O7 is about 3mol% （relative to 1mol Bi 3+ ） and the critical distance Rc was calculated as 2.1 nm. The temperature dependence of the emission intensity of Bi 1.94 Sm 0.06 ZnB2O7 was examined in the temperature range between 100 and 450 K. The quenching temperature where the intensity has dropped to half of the initial intensity is 280 K. The lifetime for Sm 3+ in Bi 1.94 Sm 0.06 ZnB2O7 is fitted as a value of 0.29 and 1.03 ms.展开更多
基金Project supported by the Talent Training Funds of Beijing (No. 20051D0501501)the Funding Project for Academic HumanResources Development in Institutions of Higher Learning under the Jurisdiction of Beijing MunicipalityBeijing Natural Science Foundation (No.2073021)
基金supported by the National Natural Science Foundation of China (No.20501023)the Youth Research Fund Project of Guangzhou Research Institute of Non-ferrous Metals
文摘The new phosphors Bi2ZnB2O7:Ln3+ (Ln3+=Eu3+,Dy3+) were synthesized by solid-state reaction technique.The obtained phosphors were investigated by means of X-ray powder diffraction (XRD),photoluminescence excitation and emission spectra with the aim of enhancing the fundamental knowledge about the luminescent properties of Eu3+ and Dy3+ ions in the Bi2ZnB2O7 host lattice.XRD analysis shows that all these compounds are of a single phase of Bi2ZnB2O7.The excitation and emission spectra of Bi2ZnB2O7:Ln3+ (Ln3+=Eu3+,Dy3+) at room temperature show the typical 4f-4f transitions of Eu3+ and Dy3+,respectively.The hypersensitive transitions of 5D0→7F2 (Eu3+) and 4F9/2→6H13/2 (Dy3+) are relatively higher than those of the insensitive transitions in Bi2ZnB2O7.It is conceivable that the Bi2ZnB2O7 structure provides asymmetry sites for activators (Eu3+,Dy3+).The optimum concentrations of Eu3+ and Dy3+ ions in Bi2ZnB2O7 phosphors are both x=0.05.
基金Project supported by the National Natural Science Foundation of China (20501023) and the Guangdong Provincial NaturalScience Foundation (5300527)
文摘The phosphors of （Bi 1-x Smx）2ZnB2O7 （x=0.01, 0.03, 0.05, 0.07, and 0.09） were synthesized by conventional solid state reaction. The purity of all samples was checked by X-ray powder diffraction （XRD）. XRD analysis shows that all these compounds are of a single phase of Bi2ZnB2O7, indicating that the Bi 3+ in Bi2ZnB2O7 can be partly replaced by the Sm 3+ without the change of crystal structure. The excitation and emission spectra at room temperature show the typical 4f-4f transitions of Sm 3+ . The dominant excitation line is around 404 nm due to 6H 5/2 →4K 11/2 and the emission spectrum consists of a series of lines at 563, 599, 646, and 704 nm due to 4G 5/2 →6H 5/2 , 6H 7/2 , 6H 9/2 , and 6H 11/2 , respectively. The optimal concentration of Sm 3+ in Bi2ZnB2O7 is about 3mol% （relative to 1mol Bi 3+ ） and the critical distance Rc was calculated as 2.1 nm. The temperature dependence of the emission intensity of Bi 1.94 Sm 0.06 ZnB2O7 was examined in the temperature range between 100 and 450 K. The quenching temperature where the intensity has dropped to half of the initial intensity is 280 K. The lifetime for Sm 3+ in Bi 1.94 Sm 0.06 ZnB2O7 is fitted as a value of 0.29 and 1.03 ms.
