Porous tantalum-titanium-niobium-zirconium(Ta-Ti-Nb-Zr)bio-high entropy alloy(bioHEA)scaffolds are fabricated using direct ink writing 3D printing technology in this study.A composite ink is prepared using four metal ...Porous tantalum-titanium-niobium-zirconium(Ta-Ti-Nb-Zr)bio-high entropy alloy(bioHEA)scaffolds are fabricated using direct ink writing 3D printing technology in this study.A composite ink is prepared using four metal powders as raw materials:Ta,Ti,Nb and Zr.Ink extrusion is used to build 3D scaf-folds with interconnected porous structures at room temperature,which are then sintered in a vacuum environment.The interdiffusion of metal elements yields porous bioHEA scaffolds with a body-centered cubic(BCC)structure.The fabricated scaffolds have uniform compositions with a significant alloying ef-fect and good biocompatibility.The scaffolds have a compressive strength of 70.08-149.95 MPa and an elastic modulus of 0.18-0.64 GPa,indicating that the mechanical properties can be controlled over a wide range.The scaffolds have a compressive strength close to that of human cortical bone and thus meet the requirements for porous structure characteristics and biological and mechanical properties of orthopedic implants.展开更多
基金financially supported by the National Natural Science Foundation of China(No.52075421)the Guangdong Ba-sic and Applied Basic Research Foundation(No.2020B1515130002)the Ji Hua Laboratory Project(No.JH-HT20220101).
文摘Porous tantalum-titanium-niobium-zirconium(Ta-Ti-Nb-Zr)bio-high entropy alloy(bioHEA)scaffolds are fabricated using direct ink writing 3D printing technology in this study.A composite ink is prepared using four metal powders as raw materials:Ta,Ti,Nb and Zr.Ink extrusion is used to build 3D scaf-folds with interconnected porous structures at room temperature,which are then sintered in a vacuum environment.The interdiffusion of metal elements yields porous bioHEA scaffolds with a body-centered cubic(BCC)structure.The fabricated scaffolds have uniform compositions with a significant alloying ef-fect and good biocompatibility.The scaffolds have a compressive strength of 70.08-149.95 MPa and an elastic modulus of 0.18-0.64 GPa,indicating that the mechanical properties can be controlled over a wide range.The scaffolds have a compressive strength close to that of human cortical bone and thus meet the requirements for porous structure characteristics and biological and mechanical properties of orthopedic implants.
