Two general protocols have been developed for the photoinduced, metal-free direct arylation of unactivated arenes with aryl iodide. Both methods gave good to excellent yields for most substrates. Notably, the C-F bond...Two general protocols have been developed for the photoinduced, metal-free direct arylation of unactivated arenes with aryl iodide. Both methods gave good to excellent yields for most substrates. Notably, the C-F bond in method A and the C-F, C-C1 and C-Br bonds in method B could survive the arylation reaction. These methods offered excellent options for syntheses of biaryls.展开更多
基金Supported by the Natural Science Foundation of Shandong Province(Nos.ZR2018MB009,ZR2016JL012)the International Cooperation Project of Qinghai Province(Nos.2018-HZ-806,2017-HZ-806)the National Natural Science Foundation of China(Nos.21302109,21302110)~~
基金financially supported by the National Basic Research Program of China(2011CB932404,2011CBA00501)the National Natural Science Foundation of China(21332001,21431008,21301173)
文摘Two general protocols have been developed for the photoinduced, metal-free direct arylation of unactivated arenes with aryl iodide. Both methods gave good to excellent yields for most substrates. Notably, the C-F bond in method A and the C-F, C-C1 and C-Br bonds in method B could survive the arylation reaction. These methods offered excellent options for syntheses of biaryls.
