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Improving the sulfidation-flotation of fine cuprite by hydrophobic flocculation pretreatment 被引量:8
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作者 Qian-yu Sun Wan-zhong Yin +3 位作者 Dong Li Ya-feng Fu Ji-wei Xue Jin Yao 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2018年第11期1256-1262,共7页
Hydrophobic flocculation pretreatment was performed to assess its effect on the recovery of fine cuprite in sulfidation-flotation. The results of the micro-flotation experiment showed that cuprite recovery is related ... Hydrophobic flocculation pretreatment was performed to assess its effect on the recovery of fine cuprite in sulfidation-flotation. The results of the micro-flotation experiment showed that cuprite recovery is related to the particle size, and that an excessive content of fine particles(<18 μm) impacted the recovery of coarse particles. When hydrophobic flocculation pretreatment was used, the recovery of fine cuprite in sulfidation-flotation increased from 60.3% to 86.3% under optimum conditions(pH 9.5; sodium oleate concentration, 2 × 10^(-4) mol×L^(-1); stirring time, 6 min; stirring speed, 1600 r×min^(-1)). The laser particle size analysis and optical microscopy results indicate that hydrophobic flocculation pretreatment effectively reduces the content of fine cuprite, and augments the apparent particle size in the pulp. We performed the Derjaguin–Landau–Verwey–Overbeek(DLVO) theory and extended DLVO theory calculations to further support the interpretation of the results. 展开更多
关键词 FINE cuprite sulfidation-flotation hydrophobic flocculation PRETREATMENT extened DLVO theory calculation
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Enhanced sulfidization flotation of cuprite by surface modification with hydrogen peroxide 被引量:9
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作者 Guang HAN Shu-ming WEN +1 位作者 Han WANG Qi-cheng FENG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第11期3564-3578,共15页
Hydrogen peroxide was used as an oxidant to modify the cuprite surface and enhance its sulfidization.Surface-adsorption and infrared spectroscopy measurements indicated that the modification of the cuprite surface wit... Hydrogen peroxide was used as an oxidant to modify the cuprite surface and enhance its sulfidization.Surface-adsorption and infrared spectroscopy measurements indicated that the modification of the cuprite surface with hydrogen peroxide before sulfidization increased the adsorption capacity of xanthate.Zeta potential,scanning electron microscopy-energy dispersive X-ray spectroscopy,X-ray photoelectron spectroscopy,and time-of-flight secondary ion mass spectrometry results showed that the modification with hydrogen peroxide increased the contents of S^(2−)and Sn^(2−)species on the cuprite surface.Microflotation tests showed that the recovery of cuprite increased from 61.74%to 83.30%after the modification of the surface with hydrogen peroxide.These results confirm that the modification of the cuprite surface with hydrogen peroxide enhances the sulfidization of cuprite,which in turn improves its flotation. 展开更多
关键词 cuprite FLOTATION hydrogen peroxide surface modification sulfidization
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Sulfidization regulation of cuprite by pre-oxidation using sodium hypochlorite as an oxidant 被引量:6
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作者 Guang Han Shuming Wen +1 位作者 Han Wang Qicheng Feng 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2021年第6期1117-1128,共12页
The direct sulfidization of cuprite is inefficient because cuprite is a copper-oxide mineral with a strong surface hydrophilicity.In this study,oxidant was used to modify cuprite surfaces to regulate the sulfidization... The direct sulfidization of cuprite is inefficient because cuprite is a copper-oxide mineral with a strong surface hydrophilicity.In this study,oxidant was used to modify cuprite surfaces to regulate the sulfidization of cuprite.Microflotation tests showed that the flotation recovery of pre-oxidized cuprite was nearly25% higher than that of direct sulfidization flotation,which indicates that the cuprite surface activity was enhanced after pre-oxidation by Cu(Ⅰ) species(weak affinity with sulfur ions) transformation to Cu(Ⅱ)species(strong affinity with sulfur ions).Zeta potential,scanning electron microscopy-energy dispersive X-ray spectroscopy,X-ray photoelectron spectroscopy,and time-of-flight secondary ion mass spectrometry results showed that pre-oxidation improved cuprite sulfidization and promoted the formation of copper-sulfide species on the cuprite surfaces.The mineral surface stability and thus,xanthate species adsorption on the cuprite surfaces were improved.The surface-adsorption measurements and infrared spectroscopy showed that a large amount of xanthate species was adsorbed onto the sulfidized cuprite surfaces after pre-oxidation,which enhanced the cuprite hydrophobicity and improved the cuprite flotation. 展开更多
关键词 cuprite PRE-OXIDATION Enhanced sulfidization Xanthate adsorption
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Leaching of cuprite through NH_4OH in basic systems 被引量:1
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作者 A.ARACENA F.PéREZ D.CARVAJAL 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2018年第12期2545-2552,共8页
Cuprite is a difficult oxide to leach under acidic conditions(for the maximum extraction of50%).In this research,the feasibility of leaching cuprite in an ammoniacal medium was studied.The working conditions addressed... Cuprite is a difficult oxide to leach under acidic conditions(for the maximum extraction of50%).In this research,the feasibility of leaching cuprite in an ammoniacal medium was studied.The working conditions addressed here were the liquid/solid ratio(120:1-400:1mL/g),stirring speed(0-950r/min),temperature(10-45℃)and NH4OH concentration(0.05-0.15mol/L).In addition,different ammoniacal reagents(NH4F and(NH4)2SO4)were analyzed.The experiments were performed in a2L reactor with a heating mantle and a condenser.The most important results were that the maximum leaching rate was obtained at pH10.5,0.10mol/L NH4OH,45℃,4h,850r/min and a liquid/solid ratio of400:1,reaching a copper extraction rate of82%.This result was related to the non-precipitation of copper in solution by the formation of copper tetra-amine (Cu(NH2)4^2+).The liquid/solid ratio and stirring speed were essential for increasing the cuprite leaching.The maximum leaching rate was achieved at higher temperatures;however,significant copper leaching rate occurred at temperatures near the freezing point of water(17.9%over4h).Increasing NH4OH concentration and decreasing particle size increased the cuprite leaching rate.The two ammoniacal reagents(NH4F and(NH4)2SO4)had low extraction rate of copper compared with NH4OH.The kinetic model representing cuprite leaching was a chemical reaction on the surface.The order of the reaction with respect to the NH4OH concentration was1.8,and it was inversely proportional to the radius of the ore particles.The calculated activation energy was44.36kJ/mol in the temperature range of10-45℃. 展开更多
关键词 LEACHING cuprite ammonium hydroxide copper tetra-amine reaction kinetics
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Coalescence of the crystallites under hydrothermal conditions (II) —— The morphology and stability energy calculation of cuprite 被引量:3
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作者 陈之战 施尔畏 +3 位作者 元如林 郑燕青 李汶军 赵同荣 《Science China(Technological Sciences)》 SCIE EI CAS 2003年第4期423-431,共9页
Cuprite (Cu2O) particles are synthesized by hydrothermal method. Most crystalline particles have long column morphology. Particles which are regarded as assembling of the crystallites in definite directions are observ... Cuprite (Cu2O) particles are synthesized by hydrothermal method. Most crystalline particles have long column morphology. Particles which are regarded as assembling of the crystallites in definite directions are observed. The typical example is the particles formed by assembling six columns in three perpendicular directions. The cone surfaces are visible at the tops of the columns. The results revealed that the coalescence of the crystallites did happen under hydrothermal conditions in which the crystallite connected with other crystallite on certain structure compatible surfaces to form a crystalline particle with a special morphology. This phenomenon is called the second kind of coalescence. The Cu2O structure unit is determined by its crystal structure. It is concluded that the tetragonal prism and three tetragonal prism-like growth units are the favorable units after stability energy calculation was performed on different kinds of growth units. It is believed that the first kind of coalescence exists commonly. The second kind of coalescence is unlikely to occur for all crystallites under hydrothermal conditions. The occurrence is dependent on the crystal structure. 展开更多
关键词 HYDROTHERMAL method coalescence cuprite STABILITY of growth unit.
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A Different Approach to High-Tc Superconductivity: Indication of Filamentary-Chaotic Conductance and Possible Routes to Room Temperature Superconductivity 被引量:9
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作者 Hans Hermann Otto 《World Journal of Condensed Matter Physics》 CAS 2016年第3期244-260,共18页
The empirical relation of between the transition temperature of optimum doped superconductors T<sub>co</sub> and the mean cationic charge , a physical paradox, can be recast to strongly support fractal the... The empirical relation of between the transition temperature of optimum doped superconductors T<sub>co</sub> and the mean cationic charge , a physical paradox, can be recast to strongly support fractal theories of high-T<sub>c</sub> superconductors, thereby applying the finding that the optimum hole concentration of σ<sub>o</sub> = 0.229 can be linked with the universal fractal constant δ<sub>1</sub> = 8.72109… of the renormalized quadratic Hénon map. The transition temperature obviously increases steeply with a domain structure of ever narrower size, characterized by Fibonacci numbers. However, also conventional BCS superconductors can be scaled with δ<sub>1</sub>, exemplified through the energy gap relation k<sub>B</sub>T<sub>c</sub> ≈ 5Δ<sub>0</sub>/δ<sub>1</sub>, suggesting a revision of the entire theory of superconductivity. A low mean cationic charge allows the development of a frustrated nano-sized fractal structure of possibly ferroelastic nature delivering nano-channels for very fast charge transport, in common for both high-T<sub>c</sub> superconductor and organic-inorganic halide perovskite solar materials. With this backing superconductivity above room temperature can be conceived for synthetic sandwich structures of less than 2+. For instance, composites of tenorite and cuprite respectively tenorite and CuI (CuBr, CuCl) onto AuCu alloys are proposed. This specification is suggested by previously described filamentary superconductivity of “bulk” CuO1﹣x samples. In addition, cesium substitution in the Tl-1223 compound is an option. 展开更多
关键词 SUPERCONDUCTIVITY Fractals Chaos Feigenbaum Numbers Fibonacci Numbers Golden Mean Ferroelastic Domains Mean Cationic Charge Perovskites CUPRATES TENORITE cuprite Cesium Substitution Solar Power Conversion Efficiency
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基于光谱特征参数组合的高光谱数据矿物填图方法 被引量:3
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作者 韦晶 明艳芳 刘福江 《地球科学(中国地质大学学报)》 EI CAS CSCD 北大核心 2015年第8期1432-1440,共9页
受大气环境等因素的影响,高光谱遥感矿物识别难以达到较高的精度.为解决该问题,根据光谱吸收特征参数在大气变化中能保持相对稳定的特点,提出一种基于光谱特征参数组合的高光谱矿物类型识别方法.文中计算了多种光谱特征参数,通过最佳指... 受大气环境等因素的影响,高光谱遥感矿物识别难以达到较高的精度.为解决该问题,根据光谱吸收特征参数在大气变化中能保持相对稳定的特点,提出一种基于光谱特征参数组合的高光谱矿物类型识别方法.文中计算了多种光谱特征参数,通过最佳指数因子(optimum index factor,OIF)优选特征参数组合,选定最佳特征参数组合,利用模式识别方法实现矿物识别.利用机载可见/红外成像光谱仪(airborne visible infrared imaging spectrometer,AVIRIS)高光谱数据,在美国内华达州Cuprite矿区进行了该方法的应用试验研究,并与前人矿物填图结果做了对比.结果表明:吸收波谷位置-吸收面积-吸收右肩位置(P-A-S2)光谱特征参数组合的矿物识别效果最优,整体精度达到74.68%. 展开更多
关键词 光谱吸收特征参数 遥感 矿物填图 机载可见/红外成像光谱仪数据 最佳指数因子 cuprite矿区.
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