Cenozoic volcanic rocks in the Fildes Peninsula are composed of High-Al basalt, basaltfc andesite, andesite, and dacite belonging to a calc-alkaline volcanic series with low-K and high-Al characteristics. Using a new ...Cenozoic volcanic rocks in the Fildes Peninsula are composed of High-Al basalt, basaltfc andesite, andesite, and dacite belonging to a calc-alkaline volcanic series with low-K and high-Al characteristics. Using a new indicator, the Sr / Ca-Ba / Ca, systematics proposed by Onuma (1980, 1981) and Sr, Ba, Ca concentrations in volcanic lavas and subvolcanic rocks, the authors find that the high-Al basaltic volcanic rocks either in volcanic strata or in subvolcanic intrusives were formed from a primary magma, in different stages through the fractional crystallization of clinopyro-xene(Cpx)and plagioclase (P1) in the process of magmatic evolution, resulting in the formation of basaltic-andesitic, andesitic and dacitic rocks.展开更多
The major elements, trace elements. K-Ar age and Sr-Nd-Pb isotopie systems ofthe Cenozoic volcanic rocks in Daheishan Island and Cishan, Penglai, Shandong Province aremeasured. The volcanic rocks ( olivine-nephelinite...The major elements, trace elements. K-Ar age and Sr-Nd-Pb isotopie systems ofthe Cenozoic volcanic rocks in Daheishan Island and Cishan, Penglai, Shandong Province aremeasured. The volcanic rocks ( olivine-nephelinite and nephcline-basanite ) in Daheishan Islanderupted periodically in an interval of 0.32 Ma, from 8.72 Ma. 8.39 Ma. 8.08 Ma to 7.73 Ma. Thevolcanic rocks arc all rich in light REEs. They are similar to the OIB-type alkali basalt in thetrace elements normalized model by primordial mantle: rich in high field elements such as Nb and Ta,and imcompatible elements such as Cs. Rb, Ba, Th. U. The volcanic rocks show a depletion of K andRb elements. It is suggested by the trace elements that the olivine-nephelinite in Daheishan Islandis originated from deep resources under the continental mantle. ε Nd (0) values of the volcanicrocks in Daheishan Island and Cishan are 5.31～8.51 and 7.33 respectively, suggesting that thevolcanic rocks are from the depleted mantle resources, which have higher Sm/Nd ratios than the CHUR.^(143)Nd /^(144)Nd ratios ot Daheishan Island olivine-nephelinite and Cishan alkali basalts are0.512 910～0.513 074 and 0.513 014 respectively. The ^(87)Sr /^(86)Sr of Daheishan Island volcanicrocks are lower than that of Cishan, 0.703 427 ～0.703 482 and 0.703 895 respectively. The DaheishanIsland olivine-nephelinite has the Pb isotopie values as follows: ^(206)Pb/^(204)Pb= 18.028 9～17.972 8. ^(207)Pb / ^(204)Pb = 15.435 8 ～15.402 2 and ^(208)Pb /^(204)Pb = 38.087 6～37.997 5.lower than those of Cishan basanite. The Cishan basanite has ^(206)Pb/^(204)Pb= 18.240 1. ^(207)Pb/^(204)Pb= 15.564 5 and ^(208)Pb /^(204)Pb = 38.535. The authors suggest that theolivine-nephelinite in Daheishan Island is similar to the E-type MORB or Hawaii OIB, and the alkalibasalts in Cishan similar to the Kerguelen OIB. The dominant mantle components of DM+PREMA andperhaps DM ( Dupal type ) are the dominant mantle components for volcanic rocks in Daheishan Islandand Cishan. The PREMA component plays an important role.展开更多
At present, the main controlling factors of helium accumulation is one of the key scientific problems restricting the exploration and development of helium reservoir. In this paper, based on the calculation results of...At present, the main controlling factors of helium accumulation is one of the key scientific problems restricting the exploration and development of helium reservoir. In this paper, based on the calculation results of He generation rate and the geochemical characteristics of the produced gas, both the similarities and differences between natural gas and He resources in the Bohai Bay, Ordos and the surrounding Songliao Basin are compared and analyzed, discussing the main controlling factors of helium resources in the three main petroliferous basins of the North China Craton. It is found that the three basins of Bohai Bay, Ordos and Songliao have similar characteristics of source rocks, reservoirs and cap rocks, that's why their methane resource characteristics are essentially the same. The calculated ~4He generation per cubic metamorphic crystalline basement in the three basins is roughly equivalent, which is consistent with the measured He resources, and it is believed that the ~4He of radiogenic from the crust is the main factor controlling the overall He accumulation in the three basins;there is almost no contribution of the mantle-derived CH_4, which suggests that the transport and uplift of mantle-derived ~3He carried by the present-day magmatic activities along the deep-large faults is not the main reason for the mantle-derived ~3He mixing in the basins. Combined with the results of regional volcanic and geophysical studies,it is concluded that under the background of the destruction of North China Craton, magma intrusion carried a large amount of mantle-derived material and formed basic volcanic rocks in the Bohai Bay Basin and Songliao Basin, which replenished mantle-derived ~3He for the interior of the basins, and that strong seismic activities in and around the basins also promoted the upward migration of mantle source ~3He. This study suggests that the tectonic zone with dense volcanic rocks in the Cenozoic era and a high incidence of historical strong earthquakes history may be a potential area for helium resource exploration.展开更多
A series of Cenozoic potassium-rich volcanic rocks developed in the Xiaoguli-Keluo-Wudalianchi-Erkeshan districts,northeast China.The source region and potassium-rich mechanism of the potassic rocks remain highly disp...A series of Cenozoic potassium-rich volcanic rocks developed in the Xiaoguli-Keluo-Wudalianchi-Erkeshan districts,northeast China.The source region and potassium-rich mechanism of the potassic rocks remain highly disputed.In this paper,the major elements,trace elements,and Sr-Nd-Pb isotopes of the volcanic rocks in Keluo(KL)and Wudalianchi(WDLC)volcanic districts were analyzed systematically.The results show that the volcanic rocks are characterized by high K2O(4.36wt.%-6.13wt.%),remarkable enrichment in LREEs and LILEs,as well as the strong fractionation of HREEs.The isotopic characteristics with high 87Sr/86Sr(0.704990-0.705272),low 143Nd/144Nd(0.512306-0.512417),low 206Pb/204Pb(16.546-17.135)and 207Pb/204Pb(15.002-15.783)of the volcanic rocks suggest the involvement of EM-I-type mantle.On the basis of the geochemical characteristics,the potassium-rich volcanic magma originated from the new SCLM forming after delamination of the ancient SCLM,with metasomatism of the potassium-rich fluids released from the ancient lower crust during the Late Mesozoic.The proposed genetic model assumes the source which represented by a phlogopite-bearing garnet peridotite(with modal garnet in the range of 2%-10%)experienced very low degrees(i.e.,~0.5)of partial melting.During Cenozoic,the lithosphere in northeast China was affected by the extension and decompression of continental rift,and the metasomatized SCLM underwent low degree partial melting,resulting in the formation of potassium-rich primitive basaltic magma.展开更多
文摘Cenozoic volcanic rocks in the Fildes Peninsula are composed of High-Al basalt, basaltfc andesite, andesite, and dacite belonging to a calc-alkaline volcanic series with low-K and high-Al characteristics. Using a new indicator, the Sr / Ca-Ba / Ca, systematics proposed by Onuma (1980, 1981) and Sr, Ba, Ca concentrations in volcanic lavas and subvolcanic rocks, the authors find that the high-Al basaltic volcanic rocks either in volcanic strata or in subvolcanic intrusives were formed from a primary magma, in different stages through the fractional crystallization of clinopyro-xene(Cpx)and plagioclase (P1) in the process of magmatic evolution, resulting in the formation of basaltic-andesitic, andesitic and dacitic rocks.
基金supported by the National Major Fundamental Research and Development Project(No.G2000046703).
文摘The major elements, trace elements. K-Ar age and Sr-Nd-Pb isotopie systems ofthe Cenozoic volcanic rocks in Daheishan Island and Cishan, Penglai, Shandong Province aremeasured. The volcanic rocks ( olivine-nephelinite and nephcline-basanite ) in Daheishan Islanderupted periodically in an interval of 0.32 Ma, from 8.72 Ma. 8.39 Ma. 8.08 Ma to 7.73 Ma. Thevolcanic rocks arc all rich in light REEs. They are similar to the OIB-type alkali basalt in thetrace elements normalized model by primordial mantle: rich in high field elements such as Nb and Ta,and imcompatible elements such as Cs. Rb, Ba, Th. U. The volcanic rocks show a depletion of K andRb elements. It is suggested by the trace elements that the olivine-nephelinite in Daheishan Islandis originated from deep resources under the continental mantle. ε Nd (0) values of the volcanicrocks in Daheishan Island and Cishan are 5.31～8.51 and 7.33 respectively, suggesting that thevolcanic rocks are from the depleted mantle resources, which have higher Sm/Nd ratios than the CHUR.^(143)Nd /^(144)Nd ratios ot Daheishan Island olivine-nephelinite and Cishan alkali basalts are0.512 910～0.513 074 and 0.513 014 respectively. The ^(87)Sr /^(86)Sr of Daheishan Island volcanicrocks are lower than that of Cishan, 0.703 427 ～0.703 482 and 0.703 895 respectively. The DaheishanIsland olivine-nephelinite has the Pb isotopie values as follows: ^(206)Pb/^(204)Pb= 18.028 9～17.972 8. ^(207)Pb / ^(204)Pb = 15.435 8 ～15.402 2 and ^(208)Pb /^(204)Pb = 38.087 6～37.997 5.lower than those of Cishan basanite. The Cishan basanite has ^(206)Pb/^(204)Pb= 18.240 1. ^(207)Pb/^(204)Pb= 15.564 5 and ^(208)Pb /^(204)Pb = 38.535. The authors suggest that theolivine-nephelinite in Daheishan Island is similar to the E-type MORB or Hawaii OIB, and the alkalibasalts in Cishan similar to the Kerguelen OIB. The dominant mantle components of DM+PREMA andperhaps DM ( Dupal type ) are the dominant mantle components for volcanic rocks in Daheishan Islandand Cishan. The PREMA component plays an important role.
基金The Natural gas formation rules and key technologies for exploration in the western exploration area KT2022A02the Science and Technology Fundamental Resources Investigation Program under contract No. 2023FY101500+2 种基金the National Key Research and Development Program of China under contract No. 2023YFC3012005the Central Public-interest Scientific Institution Basal Researchunder contract No. CEAIEF20230505。
文摘At present, the main controlling factors of helium accumulation is one of the key scientific problems restricting the exploration and development of helium reservoir. In this paper, based on the calculation results of He generation rate and the geochemical characteristics of the produced gas, both the similarities and differences between natural gas and He resources in the Bohai Bay, Ordos and the surrounding Songliao Basin are compared and analyzed, discussing the main controlling factors of helium resources in the three main petroliferous basins of the North China Craton. It is found that the three basins of Bohai Bay, Ordos and Songliao have similar characteristics of source rocks, reservoirs and cap rocks, that's why their methane resource characteristics are essentially the same. The calculated ~4He generation per cubic metamorphic crystalline basement in the three basins is roughly equivalent, which is consistent with the measured He resources, and it is believed that the ~4He of radiogenic from the crust is the main factor controlling the overall He accumulation in the three basins;there is almost no contribution of the mantle-derived CH_4, which suggests that the transport and uplift of mantle-derived ~3He carried by the present-day magmatic activities along the deep-large faults is not the main reason for the mantle-derived ~3He mixing in the basins. Combined with the results of regional volcanic and geophysical studies,it is concluded that under the background of the destruction of North China Craton, magma intrusion carried a large amount of mantle-derived material and formed basic volcanic rocks in the Bohai Bay Basin and Songliao Basin, which replenished mantle-derived ~3He for the interior of the basins, and that strong seismic activities in and around the basins also promoted the upward migration of mantle source ~3He. This study suggests that the tectonic zone with dense volcanic rocks in the Cenozoic era and a high incidence of historical strong earthquakes history may be a potential area for helium resource exploration.
基金supported by the Marine S&T Fund of Shandong Province for Pilot National Laboratory for Marine Science and Technology(Qingdao)(No.2021QNLM020001-1)Natural Science Foundation of Shandong Province(No.ZR2021MD083)+1 种基金National Natural Science Foundation of China(Grant Nos.41302102 and 41772190)Graduate Innovation Project of China University of Petroleum(East China)(No.YCX2021020).
文摘A series of Cenozoic potassium-rich volcanic rocks developed in the Xiaoguli-Keluo-Wudalianchi-Erkeshan districts,northeast China.The source region and potassium-rich mechanism of the potassic rocks remain highly disputed.In this paper,the major elements,trace elements,and Sr-Nd-Pb isotopes of the volcanic rocks in Keluo(KL)and Wudalianchi(WDLC)volcanic districts were analyzed systematically.The results show that the volcanic rocks are characterized by high K2O(4.36wt.%-6.13wt.%),remarkable enrichment in LREEs and LILEs,as well as the strong fractionation of HREEs.The isotopic characteristics with high 87Sr/86Sr(0.704990-0.705272),low 143Nd/144Nd(0.512306-0.512417),low 206Pb/204Pb(16.546-17.135)and 207Pb/204Pb(15.002-15.783)of the volcanic rocks suggest the involvement of EM-I-type mantle.On the basis of the geochemical characteristics,the potassium-rich volcanic magma originated from the new SCLM forming after delamination of the ancient SCLM,with metasomatism of the potassium-rich fluids released from the ancient lower crust during the Late Mesozoic.The proposed genetic model assumes the source which represented by a phlogopite-bearing garnet peridotite(with modal garnet in the range of 2%-10%)experienced very low degrees(i.e.,~0.5)of partial melting.During Cenozoic,the lithosphere in northeast China was affected by the extension and decompression of continental rift,and the metasomatized SCLM underwent low degree partial melting,resulting in the formation of potassium-rich primitive basaltic magma.
