This work presents isotopic data for the non-traditional isotope systems Fe,Cu,and Zn on a set of Chicxulub impactites and target lithologies with the aim of better documenting the dynamic processes taking place durin...This work presents isotopic data for the non-traditional isotope systems Fe,Cu,and Zn on a set of Chicxulub impactites and target lithologies with the aim of better documenting the dynamic processes taking place during hypervelocity impact events,as well as those affecting impact structures during the post-impact phase.The focus lies on material from the recent IODP-ICDP Expedition 364 Hole M0077A drill core obtained from the offshore Chicxulub peak ring.Two ejecta blanket samples from the UNAM 5 and 7 cores were used to compare the crater lithologies with those outside of the impact structure.The datasets of bulk Fe,Cu,and Zn isotope ratios are coupled with petrographic observations and bulk major and trace element compositions to disentangle equilibrium isotope fractionation effects from kinetic processes.The observed Fe and Cu isotopic signatures,with δ^(56/54)Fe ranging from0.95‰to 0.58‰and δ^(65/63)Cu from0.73‰to 0.14‰,mostly reflect felsic,mafic,and carbonate target lithology mixing and secondary sulfide mineral formation,the latter associated to the extensive and long-lived(>105 years)hydrothermal system within Chicxulub structure.On the other hand,the stable Zn isotope ratios provide evidence for volatility-governed isotopic fractionation.The heavier Zn isotopic compositions observed for the uppermost part of the impactite sequence and a metamorphic clast(δ^(66/64)Zn of up to 0.80‰and 0.87‰,respectively)relative to most basement lithologies and impact melt rock units indicate partial vaporization of Zn,comparable to what has been observed for Cretaceous-Paleogene boundary layer sediments around the world,as well as for tektites from various strewn fields.In contrast to previous work,our data indicate that an isotopically light Zn reservoir(δ^(66/64)Zn down to0.49‰),of which the existence has previously been suggested based on mass balance considerations,may reside within the upper impact melt rock(UIM)unit.This observation is restricted to a few UIM samples only and cannot be extended to other target or impact melt rock units.Light isotopic signatures of moderately volatile elements in tektites and microtektites have previously been linked to(back-)condensation under distinct kinetic regimes.Although some of the signatures observed may have been partially overprinted during post-impact processes,our bulk data confirm impact volatilization and condensation of Zn,which may be even more pronounced at the microscale,with variable degrees of mixing between isotopically distinct reservoirs,not only at proximal to distal ejecta sites,but also within the lithologies associated with the Chicxulub impact crater.展开更多
Evidence for a mantle and/or basaltic component in KT boundary distal ejecta is apparently inconsistent with ejection from Chicxulub Crater since it is located on;5km thick continental crust（De Paolo et al.,1983;Mont...Evidence for a mantle and/or basaltic component in KT boundary distal ejecta is apparently inconsistent with ejection from Chicxulub Crater since it is located on;5km thick continental crust（De Paolo et al.,1983;Montanari et al.,1983;Hildebrand and Boynton,1988,1990）.This evidence,along with ejected terrestrial chromites（Olds et al.,2016）suggest the impact sampled terrestrial mafic and/or ultramafic target rocks which are not known to exist in the Chicxulub target area.Possible resolutions to the paradox are:1)the existence of an unmapped/unknown suture in Yucatan Platform basement,2)an additional small unmapped/unknown impact site on oceanic lithosphere,or 3)an additional large impact on oceanic lithosphere or continental margin transitional to oceanic lithosphere.The third hypothesis is elaborated here since:1)Ophiolites nearest to Chicxulub crater are found in Cuba and apparently were obducted in latest Cretaceous/earliest Danian times（García-Casco,2008）,inconsistent with the documented Eocene collision of Cuba with the Bahamas platform;and 2)Cuba hosts the world’s thickest known KT boundary deposits（Iturralde-Vinent,1992;Kiyokawa et al.,2002;Tada et al.,2003）.These and geometric considerations suggest oceanic crust and upper mantle rock,exposed as ophiolite in the Greater Antilles island chain,marks the rim of a roughly 700 km diameter impact basin deformed and dismembered from an originally circular form by at least 50 million years of left-lateral shear displacement along the North American-Caribbeantransform plate boundary.展开更多
基金supported by the Research Foundation Flanders(FWOproject G0A6517N)+8 种基金the Belgian Federal Science Policy Office(BELSPOproject Chicxulub),the Excellence of Science Program(EoS project ET-HoME ID30442502)the VUB Strategic Research Programthe personal PhD fellowship awarded(projects11E6619N,11E6621N)the Fonds de la Recherche Scientifique(FRS-FNRS)for supportthe FWO EoS project ET-HoMEfunding for the acquisition of the MC-ICP-MS instrumentation(ZW15-02–G0H6216N)support from FWO under the form of the aforementioned EoS project and BOF-UGentprovided by IODPICDP Expedition 364,which was jointly funded by the International Ocean Discovery Program and the International Continental Scientific Drilling Program,with contributions and logistical support from the Yucatán State Government and the National Autonomous University of Mexico。
文摘This work presents isotopic data for the non-traditional isotope systems Fe,Cu,and Zn on a set of Chicxulub impactites and target lithologies with the aim of better documenting the dynamic processes taking place during hypervelocity impact events,as well as those affecting impact structures during the post-impact phase.The focus lies on material from the recent IODP-ICDP Expedition 364 Hole M0077A drill core obtained from the offshore Chicxulub peak ring.Two ejecta blanket samples from the UNAM 5 and 7 cores were used to compare the crater lithologies with those outside of the impact structure.The datasets of bulk Fe,Cu,and Zn isotope ratios are coupled with petrographic observations and bulk major and trace element compositions to disentangle equilibrium isotope fractionation effects from kinetic processes.The observed Fe and Cu isotopic signatures,with δ^(56/54)Fe ranging from0.95‰to 0.58‰and δ^(65/63)Cu from0.73‰to 0.14‰,mostly reflect felsic,mafic,and carbonate target lithology mixing and secondary sulfide mineral formation,the latter associated to the extensive and long-lived(>105 years)hydrothermal system within Chicxulub structure.On the other hand,the stable Zn isotope ratios provide evidence for volatility-governed isotopic fractionation.The heavier Zn isotopic compositions observed for the uppermost part of the impactite sequence and a metamorphic clast(δ^(66/64)Zn of up to 0.80‰and 0.87‰,respectively)relative to most basement lithologies and impact melt rock units indicate partial vaporization of Zn,comparable to what has been observed for Cretaceous-Paleogene boundary layer sediments around the world,as well as for tektites from various strewn fields.In contrast to previous work,our data indicate that an isotopically light Zn reservoir(δ^(66/64)Zn down to0.49‰),of which the existence has previously been suggested based on mass balance considerations,may reside within the upper impact melt rock(UIM)unit.This observation is restricted to a few UIM samples only and cannot be extended to other target or impact melt rock units.Light isotopic signatures of moderately volatile elements in tektites and microtektites have previously been linked to(back-)condensation under distinct kinetic regimes.Although some of the signatures observed may have been partially overprinted during post-impact processes,our bulk data confirm impact volatilization and condensation of Zn,which may be even more pronounced at the microscale,with variable degrees of mixing between isotopically distinct reservoirs,not only at proximal to distal ejecta sites,but also within the lithologies associated with the Chicxulub impact crater.
文摘Evidence for a mantle and/or basaltic component in KT boundary distal ejecta is apparently inconsistent with ejection from Chicxulub Crater since it is located on;5km thick continental crust（De Paolo et al.,1983;Montanari et al.,1983;Hildebrand and Boynton,1988,1990）.This evidence,along with ejected terrestrial chromites（Olds et al.,2016）suggest the impact sampled terrestrial mafic and/or ultramafic target rocks which are not known to exist in the Chicxulub target area.Possible resolutions to the paradox are:1)the existence of an unmapped/unknown suture in Yucatan Platform basement,2)an additional small unmapped/unknown impact site on oceanic lithosphere,or 3)an additional large impact on oceanic lithosphere or continental margin transitional to oceanic lithosphere.The third hypothesis is elaborated here since:1)Ophiolites nearest to Chicxulub crater are found in Cuba and apparently were obducted in latest Cretaceous/earliest Danian times（García-Casco,2008）,inconsistent with the documented Eocene collision of Cuba with the Bahamas platform;and 2)Cuba hosts the world’s thickest known KT boundary deposits（Iturralde-Vinent,1992;Kiyokawa et al.,2002;Tada et al.,2003）.These and geometric considerations suggest oceanic crust and upper mantle rock,exposed as ophiolite in the Greater Antilles island chain,marks the rim of a roughly 700 km diameter impact basin deformed and dismembered from an originally circular form by at least 50 million years of left-lateral shear displacement along the North American-Caribbeantransform plate boundary.
