Requirements for the respect of the environment encourage to reduce the impact of human activity on the nature. Civil engineering answers these requirements by the development of ecological construction materials. Thi...Requirements for the respect of the environment encourage to reduce the impact of human activity on the nature. Civil engineering answers these requirements by the development of ecological construction materials. This paper deals with the transformation of clay raw materials which enable the processing of environmentally friendly construction materials: in addition to their biodegradability, the alveolar fired clay materials allow energy saving in home heating thanks to their thermal isolation properties. But their manufacturing is a high energy consumption process, in particular during compaction, drying and firing which contribute to the emission of greenhouse gases. The goal of this paper is to study the rheology of clay pastes in order to develop low energy in manufacturing processes. For this purpose, theoretical and experimental approaches were carried out on six clay varieties. In the theoretical approach, a finite element (FE) simulation model has been developed for pressing a non-rigid material predicting deformations and stresses occurring within the clay structure. Experiments have then been carried out to validate the finite element modelling. In this experimental approach, the clay pastes were transformed with water content respecting the Atterberg limits which determine the plasticity of clays. The samples compaction has been carried out under variable loadings in order to determine the suitable low energy consumption loading.展开更多
To contribute to the valorization of local materials, the physico-chemical and mineralogical characterization of two clay materials MJ and MN collected in the Mayo Tsanaga river which crosses the Makabaye district of ...To contribute to the valorization of local materials, the physico-chemical and mineralogical characterization of two clay materials MJ and MN collected in the Mayo Tsanaga river which crosses the Makabaye district of Maroua (Cameroon) was carried out. For this purpose, various methods of characterization have been used, namely granulometric analysis, Atterberg limits, X-ray fluorescence spectrometry and X-ray diffraction. It is apparent from the granulometry that the clay materials studied titrate 33.77% of clays for MJ against 44.13% for MN. The plasticity indices Ip with values IpMJ = 19.27% and IpMN = 23.4% place the materials in the plastic domain and offer them the possibility to being shaped into objects. The chemical composition of the MJ and MN materials reveals that the silicon oxide SiO2, the aluminumoxide Al2O3 and iron oxide Fe2O3 are their main constituents. The X-ray diffraction of the MJ and MN materials shows that they consist mainly of quartz with associated kaolinite, illite, montmorillonite, perlialite, dickite, nacrite, amesite, albite, brookite and anorthite. In addition to these, 2/1 minerals such as muscovite, nontronite, glauconite, and phlogopite are also identified in the MJ material. The peaks of sanidine, microcline and gismondine are also found in the MN material. The materials being rich in clay minerals 2/1 can be valorized in the adsorption and the absorption of the oils and greases and in the waterproofing of the grounds. The presence of quartz, kaolinite and illite is undoubtedly favorable for the manufacture of ceramic products in terracotta. These products will be obtained at a relatively lower temperature due to illite, feldspars and iron minerals that provide vitrification during firing by forming eutectics. The aluminosilicate amorphous phases contained in the studied materials can be exploited to produce geopolymer cements and concretes.展开更多
The characterization of clay raw materials of three clay deposits from Northern Cameroon was investigated. The three deposits, located in Gaschiga, Sekandé and Boulgou, are locally used as building materials, but...The characterization of clay raw materials of three clay deposits from Northern Cameroon was investigated. The three deposits, located in Gaschiga, Sekandé and Boulgou, are locally used as building materials, but no data are available on these materials and they are relatively unknown. Mineralogical, geochemical and physico-chemical characteristics were studied, using X-ray diffraction, X-ray fluorescence and physico-chemical analyses. Mineralogically, quartz was the most abundant mineral in the studied raw materials. It is associated to abundant quantity of smectite, kaolinite and K-feldspars, and slightly abundant to traces of hematite and amphibole. Geochemically, those clayey soils are more siliceous (SiO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">, 51% - 59%) with significant amount of aluminum (Al</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">3</span></sub><span style="font-family:Verdana;">, 15% - 19%) followed by iron oxides (Fe</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">3</span></sub><span style="font-family:Verdana;">, 3% - 10%). Other oxides (K</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O, MgO, TiO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">, Na</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O, MnO, CaO and P</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">5</span></sub><span style="font-family:Verdana;">) are in relatively lower proportion. High level of silica content explains the sandy nature of these clays. The results of granulometric analysis show that the studied raw material contain sand (39% - 68%) as major grain size followed by clay particles (17% - 38%), silt (1% - 36%) and gravels (0% - 16%). The studied clayey soils were moderately plastic, with plasticity index values ranging from 13% to 30%, and are also characterized by very high liquidity limits of 34% - 63%.展开更多
文摘Requirements for the respect of the environment encourage to reduce the impact of human activity on the nature. Civil engineering answers these requirements by the development of ecological construction materials. This paper deals with the transformation of clay raw materials which enable the processing of environmentally friendly construction materials: in addition to their biodegradability, the alveolar fired clay materials allow energy saving in home heating thanks to their thermal isolation properties. But their manufacturing is a high energy consumption process, in particular during compaction, drying and firing which contribute to the emission of greenhouse gases. The goal of this paper is to study the rheology of clay pastes in order to develop low energy in manufacturing processes. For this purpose, theoretical and experimental approaches were carried out on six clay varieties. In the theoretical approach, a finite element (FE) simulation model has been developed for pressing a non-rigid material predicting deformations and stresses occurring within the clay structure. Experiments have then been carried out to validate the finite element modelling. In this experimental approach, the clay pastes were transformed with water content respecting the Atterberg limits which determine the plasticity of clays. The samples compaction has been carried out under variable loadings in order to determine the suitable low energy consumption loading.
文摘To contribute to the valorization of local materials, the physico-chemical and mineralogical characterization of two clay materials MJ and MN collected in the Mayo Tsanaga river which crosses the Makabaye district of Maroua (Cameroon) was carried out. For this purpose, various methods of characterization have been used, namely granulometric analysis, Atterberg limits, X-ray fluorescence spectrometry and X-ray diffraction. It is apparent from the granulometry that the clay materials studied titrate 33.77% of clays for MJ against 44.13% for MN. The plasticity indices Ip with values IpMJ = 19.27% and IpMN = 23.4% place the materials in the plastic domain and offer them the possibility to being shaped into objects. The chemical composition of the MJ and MN materials reveals that the silicon oxide SiO2, the aluminumoxide Al2O3 and iron oxide Fe2O3 are their main constituents. The X-ray diffraction of the MJ and MN materials shows that they consist mainly of quartz with associated kaolinite, illite, montmorillonite, perlialite, dickite, nacrite, amesite, albite, brookite and anorthite. In addition to these, 2/1 minerals such as muscovite, nontronite, glauconite, and phlogopite are also identified in the MJ material. The peaks of sanidine, microcline and gismondine are also found in the MN material. The materials being rich in clay minerals 2/1 can be valorized in the adsorption and the absorption of the oils and greases and in the waterproofing of the grounds. The presence of quartz, kaolinite and illite is undoubtedly favorable for the manufacture of ceramic products in terracotta. These products will be obtained at a relatively lower temperature due to illite, feldspars and iron minerals that provide vitrification during firing by forming eutectics. The aluminosilicate amorphous phases contained in the studied materials can be exploited to produce geopolymer cements and concretes.
文摘The characterization of clay raw materials of three clay deposits from Northern Cameroon was investigated. The three deposits, located in Gaschiga, Sekandé and Boulgou, are locally used as building materials, but no data are available on these materials and they are relatively unknown. Mineralogical, geochemical and physico-chemical characteristics were studied, using X-ray diffraction, X-ray fluorescence and physico-chemical analyses. Mineralogically, quartz was the most abundant mineral in the studied raw materials. It is associated to abundant quantity of smectite, kaolinite and K-feldspars, and slightly abundant to traces of hematite and amphibole. Geochemically, those clayey soils are more siliceous (SiO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">, 51% - 59%) with significant amount of aluminum (Al</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">3</span></sub><span style="font-family:Verdana;">, 15% - 19%) followed by iron oxides (Fe</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">3</span></sub><span style="font-family:Verdana;">, 3% - 10%). Other oxides (K</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O, MgO, TiO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">, Na</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O, MnO, CaO and P</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">5</span></sub><span style="font-family:Verdana;">) are in relatively lower proportion. High level of silica content explains the sandy nature of these clays. The results of granulometric analysis show that the studied raw material contain sand (39% - 68%) as major grain size followed by clay particles (17% - 38%), silt (1% - 36%) and gravels (0% - 16%). The studied clayey soils were moderately plastic, with plasticity index values ranging from 13% to 30%, and are also characterized by very high liquidity limits of 34% - 63%.
