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过渡金属元素掺杂对SmCo_(3)合金结构和磁性能影响的第一性原理计算
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作者 严志 方诚 +1 位作者 王芳 许小红 《物理学报》 SCIE EI CAS CSCD 2024年第3期250-257,共8页
在稀土永磁材料中,Sm-Co基合金具有优异的高温磁性能,是目前最有发展前景的永磁材料.然而,这些合金在高温环境的实际应用中,由于其相对较低的饱和磁化强度和结构稳定性而受到限制.本研究采用Fe,Ni,Cu,Zr作为代表的过渡金属元素,通过第... 在稀土永磁材料中,Sm-Co基合金具有优异的高温磁性能,是目前最有发展前景的永磁材料.然而,这些合金在高温环境的实际应用中,由于其相对较低的饱和磁化强度和结构稳定性而受到限制.本研究采用Fe,Ni,Cu,Zr作为代表的过渡金属元素,通过第一性原理计算,研究掺杂元素对SmCo_(3)合金结构稳定性、磁性能和电子结构的影响.计算结果表明,元素Ni,Cu和Fe的掺杂有利于提升SmCo_(3)体系结构稳定性,而元素Zr的掺杂不利于体系结构稳定性.磁性能计算表明,掺杂非磁性元素在一定程度上会降低SmCo_(3)体系的总磁矩,而掺杂磁性元素可以增大SmCo_(3)体系的总磁矩,在SmCo_(3)体系中并不是掺杂所有的磁性元素都可以增大体系总磁矩,并通过电子结构的分析阐明了其微观机制.最后筛选出了过渡元素Fe有利于提升SmCo_(3)的磁性能和结构稳定性,并在其原胞中掺杂原子百分比为0—22.22%范围内,预测了其最佳掺杂原子百分比为18.52%. 展开更多
关键词 Smco_(3)型永磁合金 第一性原理计算 过渡元素掺杂 综合磁性能
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(Nd_(0.9)Dy_(0.1))_(16)Co_(5)Fe_(70)Nb_(2)B_(7) PERMANENT MAGNETIC ALLOY AND BEHAVIOUR OF Nb
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作者 Pan Shuming Pan Feng Ma Ruzhang 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 1996年第1期67-71,共5页
The magnetic properties of (Nd_(0.9)Dy_(0.1))_(16)Co_(5)Fe_(70)Nb_(2)B_(7) permanent magnetic alloy prepared by powder metallurgy are:Br=1.08T,_(1)H_(C)=1620kA/m,(BH)_(max)=208kJ/m^(3).The behaviour of Nb in this allo... The magnetic properties of (Nd_(0.9)Dy_(0.1))_(16)Co_(5)Fe_(70)Nb_(2)B_(7) permanent magnetic alloy prepared by powder metallurgy are:Br=1.08T,_(1)H_(C)=1620kA/m,(BH)_(max)=208kJ/m^(3).The behaviour of Nb in this alloy was studied by joint methods of dynamic observation by high voltage electron microscope(HVEM)and Mossbauer effects.With Nb and Co substituting parts of Fe and adding a little Dy,practical magnetic alloy with excellent properties can be obtained.The thermal stability of it is 80 ℃ higher than that of ternary Nd-Fe-13 magnet.The study shows that adding Nb into Nd-Fe-B can make the intrinsic coercivity appear peak value at about Nb=2%(in mole fraction).Nb mainly enters into Nd-rich and B-rich phases,a little into Nd_(2)Fe_(14)B phase. 展开更多
关键词 (Nd_(0.9)Dy_(0.1))_(16)co_(5)Fe_(70)Nb_(2)B_(7) permanent magnetic alloy magnetic properties
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Correlation of mechanical anisotropy with fine grain strengthening for Sm_(2)Co_(17)-type sintered permanent magnets 被引量:1
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作者 Lei Wang Chao Wang +4 位作者 Qiangfeng Li Youhao Liu Yikun Fang Xiaofei Yi Wei Li 《Journal of Rare Earths》 SCIE EI CAS CSCD 2022年第10期1584-1591,共8页
The as-solution-treated Sm_(2)Co_(17)-type magnets exhibiting a single 1:7 H phase with different average grain sizes(D) were designed.Anisotropy of bending strength(R_(bb))and compressive strength(R_(mc)) of the magn... The as-solution-treated Sm_(2)Co_(17)-type magnets exhibiting a single 1:7 H phase with different average grain sizes(D) were designed.Anisotropy of bending strength(R_(bb))and compressive strength(R_(mc)) of the magnets were investigated.Moreover,the R_(bb) increases from 86 to 173 MPa with D decreasing from~52 to~18 μm for group c//h samples.The Hall-Petch correlation was employed to reveal the effect of grain size on mechanical properties of the magnets,giving deep understanding of the mechanical anisotropy characteristics.The relatively high Hall-Petch coefficient K^(Rbb)(0.79 MPa·m^(1/2)) gives rise to the largest R_(bb)(173 MPa) for group c//h samples.The mechanical anisotropy of the samples is well explained based on crystal structure and grain size features(grain boundaries).Grain refinement is an effective way to enhance the mechanical properties of Sm_(2)Co_(17)-type sintered magnets. 展开更多
关键词 Sm_(2)co_(17)-type permanent magnets Grain refinement Bending strength compressive strength Anisotropy Rare earths
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永磁材料未来十年研究展望 被引量:18
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作者 廖恒成 马立群 袁浩扬 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 1999年第2期65-68,共4页
在未来的10年里,永磁材料的研究与开发将主要呈现3个特点:磁体性能综合化、合金成分多元化和制备工艺高技术化。NdFeB系合金,Sm2Fe17Nx(x=2~3)系合金仍将是研究的热点。除此之外,复合型双相纳米晶永磁合金... 在未来的10年里,永磁材料的研究与开发将主要呈现3个特点:磁体性能综合化、合金成分多元化和制备工艺高技术化。NdFeB系合金,Sm2Fe17Nx(x=2~3)系合金仍将是研究的热点。除此之外,复合型双相纳米晶永磁合金,R3(Fe,T)29Zy(R=RE;T=Cr,V,Ti;Z=C,H,N)3∶29类化合物将吸引越来越多的注意力。本文重点综述了双相纳米晶永磁合金和3∶29类化合物的研究进展,并对今后永磁材料的研究方向作了简略的展望。 展开更多
关键词 永磁材料 NDFEB合金 Sm2Fe17Nx合金 双相纳米晶
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