The corrosion behavior of bulk metallic glasses(BMGs)(Fe41Co7Cr15Mo14C15B6Y2)100-xCrx(x=0,4,8,12,molar fraction,%)was investigated in1mol/L HCl aqueous solution with electrochemical tests.The electrochemical measureme...The corrosion behavior of bulk metallic glasses(BMGs)(Fe41Co7Cr15Mo14C15B6Y2)100-xCrx(x=0,4,8,12,molar fraction,%)was investigated in1mol/L HCl aqueous solution with electrochemical tests.The electrochemical measurements demonstrate that the passive current density of Fe-based amorphous alloy is reduced by about one order of magnitude,and meanwhile,the stability of passive film can be guaranteed by the Cr/Mo molar ratio.The Mott–Schottky(M–S)curves show that the passive film is the densest when the molar ratio of Cr/Mo is between1.37and1.69.X-ray photoelectron spectroscopy(XPS)analysis was performed to clarify chemical states of elements in the passive films.The results show that the corrosion resistance of the alloy is related to the molar ratio of Cr/Mo.The stability of passive film is determined by the synergistic action of Cr and Mo elements.The main component of the passive film is Cr3+oxide.When the potential is greater than0.5V(vs SCE),Mo6+ions play an important role in keeping the stability of the passive film.The appropriate molar ratio of Cr/Mo can reduce the dissolution rate of the passive film.展开更多
The scarcity of housing increases as population continues to rise all over the world. Despite government efforts at providing houses, yearly demand keeps on exceeding available houses and hence the hike in rent, the c...The scarcity of housing increases as population continues to rise all over the world. Despite government efforts at providing houses, yearly demand keeps on exceeding available houses and hence the hike in rent, the cost of erecting houses and the cost of building materials. This ultimately calls for a decisive solution. This study therefore applied compliance to cost ratio (C-CR) analysis in evaluating the optimum properties of fired ceramic bricks. The optimum mix proportions of waste glass (WG) and wood saw dust (WSD) in fired bricks, that will be suitable for housing constructions were hence determined. Fired clay brick samples which contained varied proportions of WG and WSD were examined for physical, mechanical and thermal properties in line with standard procedures. The results were compared with existing standards and property evaluation index, compliance level and C-CR were applied in analyzing the results obtained. It was observed that with increasing WG content, compliance level increased. Also, cost ratio and experimental cost of each brick sample trended upward. Sample with mix proportion;20 wt% WG, 5 wt% WSD and 75 wt% clay had compliance level of 94% and C-CR index of 7.81, hence chosen as optimum mix proportion for masonry bricks.展开更多
The California bearing ratio (CBR) test is the most widely spread method of determining the bearing strength of the pavement material and is fundamental to pavement design practice in most countries. This test is expe...The California bearing ratio (CBR) test is the most widely spread method of determining the bearing strength of the pavement material and is fundamental to pavement design practice in most countries. This test is expensive, laborious and time consuming, and to overcome this, Quasi static cone penetrometer machine was fabricated and used to measure the consistency limits (liquid limit-LL, Plastic limit-PL and Plasticity index-PI), which were used to develop an empirical equation to determine CBR. Soil samples were collected and unsoaked CBR, PL, LL and PI were determined according to BS 1377 part 9 and BS 1377-2;1990. Quasi static penetration forces at 20 mm depth of penetration were also determined at consistency limits. It was found that the force of 1020 gf and 60 gf was achieved at a depth of 20 mm at PI and LL respectively. The correlation and regression analysis between consistency limits, and the experimental CBR obtained showed coefficient of determination, R<sup>2</sup> = 0.907 between CBR and all the parameters using multiple linear regression analysis (MLRA). The regression equation developed was used together with the relationship developed between the Quasi static Penetration force at consistency limits and the tested consistency limits to come up with the General Empirical Equation. Verification of the formula showed that the correlation can be used accurately to determine the un soaked CBR.展开更多
基金Project(51261021)supported by the National Natural Science Foundation of ChinaProject(KJLD13056)supported by the Science and Technology Landing Plan of Jiangxi Province,China
文摘The corrosion behavior of bulk metallic glasses(BMGs)(Fe41Co7Cr15Mo14C15B6Y2)100-xCrx(x=0,4,8,12,molar fraction,%)was investigated in1mol/L HCl aqueous solution with electrochemical tests.The electrochemical measurements demonstrate that the passive current density of Fe-based amorphous alloy is reduced by about one order of magnitude,and meanwhile,the stability of passive film can be guaranteed by the Cr/Mo molar ratio.The Mott–Schottky(M–S)curves show that the passive film is the densest when the molar ratio of Cr/Mo is between1.37and1.69.X-ray photoelectron spectroscopy(XPS)analysis was performed to clarify chemical states of elements in the passive films.The results show that the corrosion resistance of the alloy is related to the molar ratio of Cr/Mo.The stability of passive film is determined by the synergistic action of Cr and Mo elements.The main component of the passive film is Cr3+oxide.When the potential is greater than0.5V(vs SCE),Mo6+ions play an important role in keeping the stability of the passive film.The appropriate molar ratio of Cr/Mo can reduce the dissolution rate of the passive film.
文摘The scarcity of housing increases as population continues to rise all over the world. Despite government efforts at providing houses, yearly demand keeps on exceeding available houses and hence the hike in rent, the cost of erecting houses and the cost of building materials. This ultimately calls for a decisive solution. This study therefore applied compliance to cost ratio (C-CR) analysis in evaluating the optimum properties of fired ceramic bricks. The optimum mix proportions of waste glass (WG) and wood saw dust (WSD) in fired bricks, that will be suitable for housing constructions were hence determined. Fired clay brick samples which contained varied proportions of WG and WSD were examined for physical, mechanical and thermal properties in line with standard procedures. The results were compared with existing standards and property evaluation index, compliance level and C-CR were applied in analyzing the results obtained. It was observed that with increasing WG content, compliance level increased. Also, cost ratio and experimental cost of each brick sample trended upward. Sample with mix proportion;20 wt% WG, 5 wt% WSD and 75 wt% clay had compliance level of 94% and C-CR index of 7.81, hence chosen as optimum mix proportion for masonry bricks.
文摘The California bearing ratio (CBR) test is the most widely spread method of determining the bearing strength of the pavement material and is fundamental to pavement design practice in most countries. This test is expensive, laborious and time consuming, and to overcome this, Quasi static cone penetrometer machine was fabricated and used to measure the consistency limits (liquid limit-LL, Plastic limit-PL and Plasticity index-PI), which were used to develop an empirical equation to determine CBR. Soil samples were collected and unsoaked CBR, PL, LL and PI were determined according to BS 1377 part 9 and BS 1377-2;1990. Quasi static penetration forces at 20 mm depth of penetration were also determined at consistency limits. It was found that the force of 1020 gf and 60 gf was achieved at a depth of 20 mm at PI and LL respectively. The correlation and regression analysis between consistency limits, and the experimental CBR obtained showed coefficient of determination, R<sup>2</sup> = 0.907 between CBR and all the parameters using multiple linear regression analysis (MLRA). The regression equation developed was used together with the relationship developed between the Quasi static Penetration force at consistency limits and the tested consistency limits to come up with the General Empirical Equation. Verification of the formula showed that the correlation can be used accurately to determine the un soaked CBR.
