The perylene （C20H12） layer effect on the electrical and dielectric properties of Al/p-Si （MS） and Al/perylene/p-Si （MPS） diodes have been investigated and compared in the frequency range of 0.7 kHz-2 MHz. Exper...The perylene （C20H12） layer effect on the electrical and dielectric properties of Al/p-Si （MS） and Al/perylene/p-Si （MPS） diodes have been investigated and compared in the frequency range of 0.7 kHz-2 MHz. Experimental results show that C-V characteristics give an anomalous peak for two structures at low frequencies due to interface states （Nss） and series resistance （Rs）. The increases in C and G/o3 at low frequencies confirm that the charges at interface can easily follow an ac signal and yield excess capacitance and conductance. The frequency-dependent dielectric constant （er） and dielectric loss （e＇） are subtracted using C and G/co data at 1.5 V. The eI and e＂ values are found to be strongly dependent on frequency and voltage, and their large values at low frequencies can be attributed to the excess polarization coming from charges at traps. Plots of ln（o＇ac）-ln（w） for two structures have two linear regions, with slopes of 0.369 and 1.166 for MS, and of 0.077 and 1.061 for MPS, respectively. From the C 2-V characteristics, the doping acceptor atom concentration （NA） and barrier height （,~） for Schottky barrier diodes （SBDs） 1.303 ~ 1015 cm-3, and 1.10 and I. 13 eV, respectively. of MS and MPS types are also obtained to be 1.484 ~ 1015展开更多
As India is a world class producer of sugarcane,sugar beet,other tubers like potato and vegetables with starch,cashew and badam,castor oil and soybean,the quantum of bio resins and bio plastics that can be produced fr...As India is a world class producer of sugarcane,sugar beet,other tubers like potato and vegetables with starch,cashew and badam,castor oil and soybean,the quantum of bio resins and bio plastics that can be produced from these conventional,organic and genetically modified plants is immense.As on date,advanced and state of the art plastics and composites are being used in many applications as there is no incentive for farmers to produce plants and vegetables for the plastics and resins market exclusively.The use of advanced composites in varied applications escalates costs and shifts the material consumption that would deplete the natural resources,through excessive usage at one end and lack of demand for natural resources at the other end as bio derived composites become under-utilized.This review paper attempts to project the actual possibilities of the bio resin and bio plastic market in this country and provides the knowhow for the production of bio-phenolic cashew nut shell resin which are more than a substitute for the synthetically produced epoxies.Their true potentialities in composites product applications involving structural,thermal,electronic,pharmaceutical and petroleum engineering markets is discussed in this paper.A novel working model with an economically feasible option is also provided for those concerned about their safe disposal,recycling,reuse and conversion into useable fuel with virtually no impact to the environment.Cashew Nut Shell Liquid(CNSL)is an abundant natural source for synthesizing phenolic compounds.The excellent monomer,Cardanol is isolated from CNSL for polymer production.These are polymerized with aldehydes and acids at a particular mole fraction in the presence of catalysts like alkalis to convert into rigid resins.Differential Scanning Calorimetric(DSC)and Thermo Gravimetric Analysis(TGA)were studied for the thermal characterization of the synthesized CNSL Resins.Characterization of the synthesized resins was also carried out with respect to the evaluated mechanical properties such as hardness,strength,elastic modulus and fracture toughness.The synthesized CNSL resins yielded many interesting compositions with varied properties increasing the possibilities of various resin formulations which could be used for composites applications in vibrational damping.The electronic packaging applications of nano-composites with high dielectric strength produced with the CNSL matrix are also highlighted.展开更多
文摘The perylene （C20H12） layer effect on the electrical and dielectric properties of Al/p-Si （MS） and Al/perylene/p-Si （MPS） diodes have been investigated and compared in the frequency range of 0.7 kHz-2 MHz. Experimental results show that C-V characteristics give an anomalous peak for two structures at low frequencies due to interface states （Nss） and series resistance （Rs）. The increases in C and G/o3 at low frequencies confirm that the charges at interface can easily follow an ac signal and yield excess capacitance and conductance. The frequency-dependent dielectric constant （er） and dielectric loss （e＇） are subtracted using C and G/co data at 1.5 V. The eI and e＂ values are found to be strongly dependent on frequency and voltage, and their large values at low frequencies can be attributed to the excess polarization coming from charges at traps. Plots of ln（o＇ac）-ln（w） for two structures have two linear regions, with slopes of 0.369 and 1.166 for MS, and of 0.077 and 1.061 for MPS, respectively. From the C 2-V characteristics, the doping acceptor atom concentration （NA） and barrier height （,~） for Schottky barrier diodes （SBDs） 1.303 ~ 1015 cm-3, and 1.10 and I. 13 eV, respectively. of MS and MPS types are also obtained to be 1.484 ~ 1015
文摘As India is a world class producer of sugarcane,sugar beet,other tubers like potato and vegetables with starch,cashew and badam,castor oil and soybean,the quantum of bio resins and bio plastics that can be produced from these conventional,organic and genetically modified plants is immense.As on date,advanced and state of the art plastics and composites are being used in many applications as there is no incentive for farmers to produce plants and vegetables for the plastics and resins market exclusively.The use of advanced composites in varied applications escalates costs and shifts the material consumption that would deplete the natural resources,through excessive usage at one end and lack of demand for natural resources at the other end as bio derived composites become under-utilized.This review paper attempts to project the actual possibilities of the bio resin and bio plastic market in this country and provides the knowhow for the production of bio-phenolic cashew nut shell resin which are more than a substitute for the synthetically produced epoxies.Their true potentialities in composites product applications involving structural,thermal,electronic,pharmaceutical and petroleum engineering markets is discussed in this paper.A novel working model with an economically feasible option is also provided for those concerned about their safe disposal,recycling,reuse and conversion into useable fuel with virtually no impact to the environment.Cashew Nut Shell Liquid(CNSL)is an abundant natural source for synthesizing phenolic compounds.The excellent monomer,Cardanol is isolated from CNSL for polymer production.These are polymerized with aldehydes and acids at a particular mole fraction in the presence of catalysts like alkalis to convert into rigid resins.Differential Scanning Calorimetric(DSC)and Thermo Gravimetric Analysis(TGA)were studied for the thermal characterization of the synthesized CNSL Resins.Characterization of the synthesized resins was also carried out with respect to the evaluated mechanical properties such as hardness,strength,elastic modulus and fracture toughness.The synthesized CNSL resins yielded many interesting compositions with varied properties increasing the possibilities of various resin formulations which could be used for composites applications in vibrational damping.The electronic packaging applications of nano-composites with high dielectric strength produced with the CNSL matrix are also highlighted.
