The ultraviolet(UV)light stability of silicon heterojunction(SHJ)solar cells should be addressed before large-scale production and applications.Introducing downshifting(DS)nanophosphors on top of solar cells that can ...The ultraviolet(UV)light stability of silicon heterojunction(SHJ)solar cells should be addressed before large-scale production and applications.Introducing downshifting(DS)nanophosphors on top of solar cells that can convert UV light to visible light may reduce UV-induced degradation(UVID)without sacrificing the power conversion efficiency(PCE).Herein,a novel composite DS nanomaterial composed of YVO_(4):Eu^(3+),Bi^(3+)nanoparticles(NPs)and AgNPs was synthesized and introduced onto the incident light side of industrial SHJ solar cells to achieve UV shielding.The YVO_(4):Eu^(3+),Bi^(3+)NPs and Ag NPs were synthesized via a sol-gel method and a wet chemical reduction method,respectively.Then,a composite structure of the YVO_(4):Eu^(3+),Bi^(3+)NPs decorated with Ag NPs was synthesized by an ultrasonic method.The emission intensities of the YVO_(4):Eu^(3+),Bi^(3+)nanophosphors were significantly enhanced upon decoration with an appropriate amount of~20 nm Ag NPs due to the localized surface plasmon resonance(LSPR)effect.Upon the introduction of LSPR-enhanced downshifting,the SHJ solar cells exhibited an~0.54%relative decrease in PCE degradation under UV irradiation with a cumulative dose of 45 k W h compared to their counterparts,suggesting excellent potential for application in UV-light stability enhancement of solar cells or modules.展开更多
The mismatch between the AM1.5G spectrum and the photovoltaic (PV) cells absorption is one of the most limiting factors for PV performance.To overcome this constraint through the enhancement of solar energy harvesting...The mismatch between the AM1.5G spectrum and the photovoltaic (PV) cells absorption is one of the most limiting factors for PV performance.To overcome this constraint through the enhancement of solar energy harvesting,luminescent downshifting (LDS) layers are very promising to shape the incident sunlight and,thus,we report here the use of Tb^3+- and Eu^3+-doped organic-inorganic hybrid materials as LDS layers on Si PV cells.Electrical measurements on the PV cell,done before and after the deposition of the LDS layers,confirm the positive effect of the coatings on the cell’s performance in the UV spectral region.The maximum delivered power and the maximum absolute external quantum efficiency increased 14% and 27%,respectively.Moreover,a solar powered car race was organized in which the small vehicle containing the coated PV cells presented a relative increase of 9% in the velocity,when compared to that with the uncoated one.展开更多
To date, the instability of organometal halide perovskite solar cells(PSCs) has become the focus issue that limits the development and long-term application of PSCs. Both the ultraviolet(UV) rays in sunlight and moist...To date, the instability of organometal halide perovskite solar cells(PSCs) has become the focus issue that limits the development and long-term application of PSCs. Both the ultraviolet(UV) rays in sunlight and moisture in air can significantly accelerate the disintegration of the perovskite. Here, we introduced a Zn Se quantum dots layer as downshifting materials, which was spin-coated onto the backside of PSCs.This layer converted the UV rays into visible light to prevent the destruction of PSCs as well as increase the light harvesting of the perovskite layer. Under the UV irradiation in the moisture ambient(40%), the destruction speed of the unencapsulated perovskite films were also delayed evidently. In addition, the power conversion efficiency(PCE) of the PSCs was increased from 16.6% to 17.3% due to the increase of the visible light absorbance of the perovskite.展开更多
For surface gravity waves propagating over a horizontal bottom that consists of a patch of sinusoidal ripples,strong wave reflection occurs under the Bragg resonance condition.The critical wave frequency,at which the ...For surface gravity waves propagating over a horizontal bottom that consists of a patch of sinusoidal ripples,strong wave reflection occurs under the Bragg resonance condition.The critical wave frequency,at which the peak reflection coefficient is obtained,has been observed in both physical experiments and direct numerical simulations to be downshifted from the well-known theoretical prediction.It has long been speculated that the downshift may be attributed to higher-order rippled bottom and free-surface boundary effects,but the intrinsic mechanism remains unclear.By a regular perturbation analysis,we derive the theoretical solution of frequency downshift due to third-order nonlinear effects of both bottom and free-surface boundaries.It is found that the bottom nonlinearity plays the dominant role in frequency downshift while the free-surface nonlinearity actually causes frequency upshift.The frequency downshift/upshift has a quadratic dependence in the bottom/free-surface steepness.Polychromatic bottom leads to a larger frequency downshift relative to the monochromatic bottom.In addition,direct numerical simulations based on the high-order spectral method are conducted to validate the present theory.The theoretical solution of frequency downshift compares well with the numerical simulations and available experimental data.展开更多
基金supported by the National Natural Science Foundation of China (Grant Nos.52202276 and 51821002)the China Postdoctoral Science Foundation (Grant No.2022M712300)+1 种基金the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (Grant No.22KJB480010)a project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)。
文摘The ultraviolet(UV)light stability of silicon heterojunction(SHJ)solar cells should be addressed before large-scale production and applications.Introducing downshifting(DS)nanophosphors on top of solar cells that can convert UV light to visible light may reduce UV-induced degradation(UVID)without sacrificing the power conversion efficiency(PCE).Herein,a novel composite DS nanomaterial composed of YVO_(4):Eu^(3+),Bi^(3+)nanoparticles(NPs)and AgNPs was synthesized and introduced onto the incident light side of industrial SHJ solar cells to achieve UV shielding.The YVO_(4):Eu^(3+),Bi^(3+)NPs and Ag NPs were synthesized via a sol-gel method and a wet chemical reduction method,respectively.Then,a composite structure of the YVO_(4):Eu^(3+),Bi^(3+)NPs decorated with Ag NPs was synthesized by an ultrasonic method.The emission intensities of the YVO_(4):Eu^(3+),Bi^(3+)nanophosphors were significantly enhanced upon decoration with an appropriate amount of~20 nm Ag NPs due to the localized surface plasmon resonance(LSPR)effect.Upon the introduction of LSPR-enhanced downshifting,the SHJ solar cells exhibited an~0.54%relative decrease in PCE degradation under UV irradiation with a cumulative dose of 45 k W h compared to their counterparts,suggesting excellent potential for application in UV-light stability enhancement of solar cells or modules.
文摘The mismatch between the AM1.5G spectrum and the photovoltaic (PV) cells absorption is one of the most limiting factors for PV performance.To overcome this constraint through the enhancement of solar energy harvesting,luminescent downshifting (LDS) layers are very promising to shape the incident sunlight and,thus,we report here the use of Tb^3+- and Eu^3+-doped organic-inorganic hybrid materials as LDS layers on Si PV cells.Electrical measurements on the PV cell,done before and after the deposition of the LDS layers,confirm the positive effect of the coatings on the cell’s performance in the UV spectral region.The maximum delivered power and the maximum absolute external quantum efficiency increased 14% and 27%,respectively.Moreover,a solar powered car race was organized in which the small vehicle containing the coated PV cells presented a relative increase of 9% in the velocity,when compared to that with the uncoated one.
基金supported by the National Science Foundation of China (51774034, 51772026, 51611130063)the Fundamental Research Funds for the Central Universities (FRF-BD-16-012A)111 Project (No. B17003)
文摘To date, the instability of organometal halide perovskite solar cells(PSCs) has become the focus issue that limits the development and long-term application of PSCs. Both the ultraviolet(UV) rays in sunlight and moisture in air can significantly accelerate the disintegration of the perovskite. Here, we introduced a Zn Se quantum dots layer as downshifting materials, which was spin-coated onto the backside of PSCs.This layer converted the UV rays into visible light to prevent the destruction of PSCs as well as increase the light harvesting of the perovskite layer. Under the UV irradiation in the moisture ambient(40%), the destruction speed of the unencapsulated perovskite films were also delayed evidently. In addition, the power conversion efficiency(PCE) of the PSCs was increased from 16.6% to 17.3% due to the increase of the visible light absorbance of the perovskite.
基金financially supported by the National Natural Science Foundation of China (Grant Nos. U1706230 and51379071)the Key Project of NSFC-Shandong Joint Research Funding POW3C (Grant No. U1906230)the National Science Fund for Distinguished Young Scholars (Grant No. 51425901)
文摘For surface gravity waves propagating over a horizontal bottom that consists of a patch of sinusoidal ripples,strong wave reflection occurs under the Bragg resonance condition.The critical wave frequency,at which the peak reflection coefficient is obtained,has been observed in both physical experiments and direct numerical simulations to be downshifted from the well-known theoretical prediction.It has long been speculated that the downshift may be attributed to higher-order rippled bottom and free-surface boundary effects,but the intrinsic mechanism remains unclear.By a regular perturbation analysis,we derive the theoretical solution of frequency downshift due to third-order nonlinear effects of both bottom and free-surface boundaries.It is found that the bottom nonlinearity plays the dominant role in frequency downshift while the free-surface nonlinearity actually causes frequency upshift.The frequency downshift/upshift has a quadratic dependence in the bottom/free-surface steepness.Polychromatic bottom leads to a larger frequency downshift relative to the monochromatic bottom.In addition,direct numerical simulations based on the high-order spectral method are conducted to validate the present theory.The theoretical solution of frequency downshift compares well with the numerical simulations and available experimental data.
